Bulk flow parameters in turbulent wall boundary layers near separation

Experiments were conducted in a turbulent boundary layer near separation along a flat plate. The pressure gradient in flow direction was varied such that three significant boundary layer configurations could be maintained. The flow in the test section thus had simultaneously a region of favourable pressure gradient, a region of strong adverse pressure gradient with boundary layer separation and a region of reattached boundary layer. Specially designed fine probes facilitated the measurements of skin friction and velocity distribution very close to the wall. Bulk flow parameters such as skin friction coefficient C _f, Reynold's number Re_δ2 and shape factors H and G, which are significant characteristics of wall boundary layers were evaluated. The dependence of these parameters on the Reynolds number and along the test section was explored and the values were compared with other empirical and analytical formulae known in the literature.     

Electrodeposition of nanocrystalline Ni–Cu alloy from environmentally friendly lactate bath

A new environmentally friendly electroplating bath for Ni–Cu alloy deposition was developed. Lactic acid was used as a complexing agent. The influence of bath composition, current density, pH and temperature on cathodic polarization, cathodic current efficiency and alloy composition was studied. Different proportions of the two metals were obtained by using different deposition parameters, but at all [Ni²⁺] / [Cu²⁺] ratios studied, preferential deposition of Cu occurred and regular co‐deposition took place. The Ni content of the deposit increased with Ni²⁺ content and current density and decreased with temperature. The surface morphology of the deposited Ni–Cu alloy was investigated using scanning electron microscopy. The crystal structure was examined using the X‐ray diffraction technique. The results showed that the deposits consisted of a single solid solution phase with a face‐centered cubic structure. The crystallite size lies in the range of 12 to 25 nm for as‐plated alloys. Copyright © 2014 John Wiley & Sons, Ltd.     

Modeling the effects of capillary pressure with the presence of full tensor permeability and discrete fracture models using the mimetic finite difference method

Capillary dominated flow or imbibition—whether spontaneous or forced—is an important physical phenomena in understanding the behavior of naturally fractured water-driven reservoirs (NFR’s). When the water flows through the fractures, it imbibes into the matrix and pushes the oil out of the pores due to the difference in the capillary pressure. In this paper, we focus on modeling and quantifying the oil recovered from NFR’s through the imbibition processes using a novel fully implicit mimetic finite difference (MFD) approach coupled with discrete fracture/discrete matrix (DFDM) technique. The investigation is carried out in the light of different wetting states of the porous media (i.e., varying capillary pressure curves) and a full tensor representation of the permeability. The produced results proved the MFD to be robust in preserving the physics of the problem, and accurately mapping the flow path in the investigated domains. The wetting state of the rock affects greatly the oil recovery factors along with the orientation of the fractures and the principal direction of the permeability tensor. We can conclude that our novel MFD method can handle the fluid flow problems in discrete-fractured reservoirs. Future works will be focused on the extension of MFD method to more complex multi-physics simulations.

     

Morphological and optical properties changes in nanocrystalline Si (nc-Si) deposited on porous aluminum nanostructures by plasma enhanced chemical vapor deposition for Solar energy applications

Photoluminescence (PL) spectroscopy was used to determine the electrical band gap of nanocrystalline silicon (nc-Si) deposited by plasma enhancement chemical vapor deposition (PECVD) on porous alumina structure by fitting the experimental spectra using a model based on the quantum confinement of electrons in Si nanocrystallites having spherical and cylindrical forms. This model permits to correlate the PL spectra to the microstructure of the porous aluminum silicon layer (PASL) structure. The microstructure of aluminum surface layer and nc-Si films was systematically studied by atomic force microscopy (AFM), transmission electron microscopy (TEM), Raman spectroscopy and X-ray diffraction (XRD). It was found that the structure of the nanocrystalline silicon layer (NSL) is dependent of the porosity (void) of the porous alumina layer (PAL) substrate. This structure was performed in two steps, namely the PAL substrate was prepared using sulfuric acid solution attack on an Al foil and then the silicon was deposited by plasma enhanced chemical vapor deposition (PECVD) on it. The optical constants (n and k as a function of wavelength) of the deposited films were obtained using variable angle spectroscopic ellipsometry (SE) in the UV-vis-NIR regions. The SE spectrum of the porous aluminum silicon layer (PASL) was modeled as a mixture of void, crystalline silicon and aluminum using the Cauchy model approximation. The specific surface area (SSA) was estimated and was found to decrease linearly when porosity increases. Based on this full characterization, it is demonstrated that the optical characteristics of the films are directly correlated to their micro-structural properties.     

Fractional quasi AKNS‐technique for nonlinear space–time fractional evolution equations

This paper aims to formulate the fractional quasi‐inverse scattering method. Also, we give a positive answer to the following question: can the Ablowitz‐Kaup‐Newell‐Segur (AKNS) method be applied to the space–time fractional nonlinear differential equations? Besides, we derive the Bäcklund transformations for the fractional systems under study. Also, we construct the fractional quasi‐conservation laws for the considered fractional equations from the defined fractional quasi AKNS‐like system. The nonlinear fractional differential equations to be studied are the space–time fractional versions of the Kortweg‐de Vries equation, modified Kortweg‐de Vries equation, the sine‐Gordon equation, the sinh‐Gordon equation, the Liouville equation, the cosh‐Gordon equation, the short pulse equation, and the nonlinear Schrödinger equation.     

Facile Preparation and Analytical Utility of ZnO/Date Palm Fiber Nanocomposites in Lead Removal from Environmental Water Samples

This study reports a facile approach for preparing low-cost, eco-friendly nanocomposites of ZnO nanoparticles (NPs) and date palm tree fiber (DPF) as a biomass sorbent. The hypothesis of this research work is the formation of an outstanding adsorbent based on the date palm fiber and ZnO nanoparticles. ZnO NP/DPF nanocomposites were synthesized by mixing the synthesized ZnO NPs and DPF in different mass ratios and evaluating their efficacy in adsorbing Pb²⁺ from aqueous solutions. The structure and surface morphology of the developed ZnO NP/DPF nanocomposite were critically characterized by XRD, FESEM, and TEM techniques. Compared to ZnO NPs, the ZnO NP/DPF nanocomposites displayed significantly enhanced Pb²⁺ uptake. Pb²⁺ adsorption was confirmed via various isotherm and kinetic models and thermodynamics. The computed Langmuir sorption capacity (qm) was found to be 88.76 mg/g (R² > 0.998), and the pseudo-second-order R² > 0.999 model was most appropriate for describing Pb²⁺ adsorption. Impregnating the biomass with ZnO NPs enhanced the spontaneity of the process, and the value (−56.55 kJ/mol) of ΔH displayed the exothermic characteristics of Pb²⁺ retention. Only the loaded ZnO NP/DPF achieved the removal of a high percentage (84.92%) of Pb²⁺ from the environmental water sample (seawater). This finding suggests the use of ZnO NP/DPF nanocomposites for removing heavy metals from environmental water samples to purify the samples.     

On a class of solvable Pauli-Schrödinger hamiltonians

To every scalar potential for which the bound state problem of the Schrödinger equation can be (at least partially) solved it is possible to associate a new potential containing Pauli matrices and for which the associated Pauli-Schrödinger equation can also be solved to the same extent. The new system can be regarded as a finite break of the supersymmetry that the original system and its supersymmetric partner have.     

Improving surface quality of polyethylene terephthalate film for large area flexible electronic applications

Lamination is a method utilized to protect flexible electroluminescence device against environmental hazards, such as dust, moisture, and water vapor. The materials are typically joined together using adhesive or cohesion of the materials during the lamination process. Polyethylene terephthalate (PET) is commonly used as the substrate film where electroluminescence patterns are printed. However, PET film has a relatively low surface energy and high contact angle, which would cause relatively weak laminating strength. This paper discusses the use of atmospheric plasma as a surface treatment method to modify PET and laminating films’ interface to improve bonding and laminating quality. Experimental results revealed that atmospheric plasma process reduced the contact angle of both PET and laminating films. Functional groups favoring hydrophilicity were found on the films’ interface after the atmospheric plasma treatment. These effects consequently increased surface energies of both films and favored bonding between the films. The treated films thus had increased laminating strength by approximately six times without compromising the transparency quality.