Facile formation of water-insoluble cyclodextrin/Nafion composite films on solid surfaces

The water-insoluble poly-beta-cyclodextrin (poly-CD)/Nafion composite film was easily prepared by casting a mixed solution of poly-CD and Nafion onto substrate plates. FT-IR measurements showed that the 50/50 wt% poly-CD/Nafion composite film remained stable on the glass and quartz substrates after immersion in water for more than 3 h, while a pure poly-CD film was almost completely dissolved by immersion within 1 h. The film stability was also evaluated from the amount of p-nitrophenol (p-NP) inclusion in the film, which was determined from the decrease in UV-vis absorbance of the p-NP solution into which the film was immersed. The composition dependence of the inclusion amount showed that the film was stable up to 50 wt% CD, but became less stable with further increase in the CD concentration in the film. From the isotherms for the inclusion of p-NP and 1-naphthoate (1-Naph) into the film, the inclusion (stability) constants were determined to be 3.7x10(3) M(-1) and 1.9x10(2) M(-1), respectively. These results show that the selective inclusion of CD is retained after preparation of the composite film.     

The role of the doubly excited configurations in the π-electronic structure of the croconate anion

The electronic structure of the croconate anion is investigated by the semi-empirical VESCF method with CI including up to the doubly excited configurations. The effect of the doubly excited configuration is quite large in the lowest singlet state which turns out to be a ground state, while the calculation including only singly excited configurations produces a triplet ground state. The calculated first transition energy (¹ A₁ ¹ E₁) is in fair agreement with the observed value. The interpretation of the transition moment in case that the doubly excited configurations are included is also discussed.

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Zusammenfassung Die Elektronenstruktur des Croconat-Anions wurde mit der halbempirischen VESCF-Methode mit Konfigurationswechselwirkung, die bis zu zweifach angeregte Konfigurationen einschloß, untersucht. Der Einfluß der zweifach angeregten Konfigurationen ist im niedrigsten Singulettzustand, der sich als Grundzustand herausstellt, sehr stark. Schließt die Rechnung hingegen nur einfach angeregte Konfigurationen ein, so erhält man einen Tripletgrundzustand. Die berechnete erste Übergangsenergie (¹ A₁ ¹ E₁ stimmt gut mit dem beobachteten Wert überein. Ebenso wird die Interpretation des Übergangsmomentes für den Fall, daß auch zweifach angeregte Konfigurationen berücksichtigt werden, diskutiert.

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Resumé La structure électronique de l'anion croconique est étudieé par la méthode VESCF semi-empirique avec IC, configurations diexcitées comprises. L'effet des configurations diexcitées est très important sur l'état singulet le plus has qui est un état fundamental, alors que si l'on ne tient compte que des configurations monoexcitées on obtient un état fundamental triplet. La premiére énergie de transition calculée (¹ A₁ ¹ E₁ est en bon accord avec la valeur observee. Le moment de transition est interprété dans les cas où l'on tient compte des configurations diexcitées.

     

Search for enhancements in the nucleon-nucleon mass distributions in the dp breakup reaction in the momentum range 2.0–3.7 GeV/c

We have investigated the dp → ppn non-spectator breakup reaction obtained from the KEK l m liquid hydrogen bubble chamber exposed to a beam of deuterons at ten momenta in the range 2.0–3.7 GeV/c. The pn and pp effective mass distributions in the two momentum regions 2.0–2.9 GeV/c and 3.0–3.7 GeV/c show no structure.     

Boundary feedback stabilization of coupled sine-Gordon equations

^** Email: koba{at}cntl.kyutech.ac.jp^*** Email: sakamoto{at}cntl.kyutech.ac.jp This paper is concerned with global stabilization of the systemgoverned by coupled sine-Gordon equations without damping. Astabilizer is constructed by boundary velocity feedback. Theclosed-loop system is shown to be well posed by the non-linearsemigroup approach. Moreover, using a multiplier method, globalexponential stabilization of the closed-loop system is proved.     

Regiocontrolled intramolecular cyclizations of carboxylic acids to carbon-carbon triple bonds promoted by acid or base catalyst

We systematically investigated, for the first time, the relationship between regioselectivity and acid/base effects in the cyclization reactions between carboxylic acids and carbon-carbon triple bonds. We found novel acid- and base-promoted cyclizations to selectively give isocoumarin or pyran-2(2H)-one and phthalide or furan-2(5H)-one skeletons, respectively, and established a catalytic version of regioselective heterocyclic ring synthesis. Density functional theory calculations and application to a short route to thunberginol A were also described. [reaction: see text].     

Eventually positive solutions of first order nonlinear differential equations with a deviating argument

The following first order nonlinear differential equation with a deviating argument $ x'(t) + p(t)[x(\tau (t))]^\alpha = 0 $ is considered, where α > 0, α ≠ 1, p ∈ C[t ₀; ∞), p(t) > 0 for t ≧ t ₀, τ ∈ C[t ₀; ∞), lim _t→∞ τ(t) = ∞, τ(t) < t for t ≧ t ₀. Every eventually positive solution x(t) satisfying lim _t→∞ x(t) ≧ 0. The structure of solutions x(t) satisfying lim _t→∞ x(t) > 0 is well known. In this paper we study the existence, nonexistence and asymptotic behavior of eventually positive solutions x(t) satisfying lim _t→∞ x(t) = 0.