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311.
312.
The present study was focused on the thermal degradation of Eulaliopsis binata biomass produced on a salt-affected soil without any fertilizer or pesticide applications. The plant biomass was subjected to thermal degradation experiments at three heating rates, 10, 30 and 50 K min?1. The kinetic analyses were performed through isoconversional models of Kissinger–Akahira–Sunose and Flynn–Wall–Ozawa, followed by the calculation of thermodynamic parameters of activation. The high heating value was calculated as 15.10 MJ mol?1. The activation energy values of the grass were shown to be ranging from 118 through 240 kJ mol?1. Energy difference of enthalpies of activation between the reagent and the activated complex was in accordance with activation energies. Pre-exponential factors indicated the reaction to follow first-order kinetics. Gibbs free energy for the grass was measured to be ranging from 171 to 174 kJ mol?1. Our data have shown that E. binata biomass offers remarkable potential as a low-cost biomass for bioenergy.  相似文献   
313.
A new efficient heterogeneous catalyst was introduced for the epoxidation of styrene. The catalyst was obtained from deposition of gold nanoparticles on the cellulose aerogel. The catalyst was characterized with XRD, TGA, EDX, BET, FAAS and SEM. High yield and excellent selectivity were achieved for the epoxidation of styrene in solvent-free conditions at room temperature using H2O2 as a green oxidant during 1 h. The reaction has some advantages such as solvent-free and mild reaction conditions, low catalyst loading, high yield, excellent selectivity, green oxidant and short reaction duration. In addition, the catalyst is recyclable and applicable for six times without decrease in yield.  相似文献   
314.
The unstable sodium borohydride is stabilized on modified poly(4-vinylpyridinium), and it is used as an efficient and regenerable polymer-supported borohydride reagent for the reduction of a variety of carbonyl compounds, such as aldehydes, ketones, α,β-unsaturated carbonyl compounds, α-diketones and acyloins, in good to excellent yields.  相似文献   
315.
By using a radio‐frequency sputtering method, we synthesized large‐area, uniform, and transparent molybdenum disulfide film electrodes (1, 3, 5, and 7 min) on transparent and conducting fluorine‐doped tin oxide (FTO), as ecofriendly, cost‐effective counter electrodes (CE) for dye‐sensitized solar cells (DSSCs). These CEs were used in place of the routinely used expensive platinum CEs for the catalytic reduction of a triiodide electrolyte. The structure and morphology of the MoS2 was analyzed by using Raman spectroscopy, X‐ray diffraction, and X‐ray photoemission spectroscopy measurements and the DSSC characteristics were investigated. An unbroken film of MoS2 was identified on the FTO crystallites from field‐emission scanning electron microscopy. Cyclic voltammetry, electrochemical impedance spectroscopy, and Tafel curve measurements reveal the promise of MoS2 as a CE with a low charge‐transfer resistance, high electrocatalytic activity, and fast reaction kinetics for the reduction of triiodide to iodide. Finally, an optimized transparent MoS2 CE, obtained after 5 min synthesis time, showed a high power‐conversion efficiency of 6.0 %, which comparable to the performance obtained with a Pt CE (6.6 %) when used in TiO2‐based DSCCs, thus signifying the importance of sputtering time on DSSC performance.  相似文献   
316.
Methanolic extract of Golden rain leaves was fractionated by column chromatography on silica gel and 18 fractions were obtained. Antimicrobial activities of fractions were investigated against Bacillus subtilis, Staphylococcus aureus, Escherichia coli and Pseudomonas aeruginosa as quality control bacteria and fungus Pyricularia grisea which causes Blast disease in rice. Fractions showed more antibacterial activity at 0.04 g/mL concentration only on B. subtilis and S. aureus as gram positive bacteria. Also, three fractions indicated excellent antifungal effect on fungus P. grisea. Moreover, in the present study, fractions that showed very good effect on microorganisms were used for gas chromatography-mass spectrometry analysis to identify different phytochemicals.  相似文献   
317.
The charged current lepton production induced by neutrinos in 56Fe nuclei has been studied. The calculations have been done for the quasielastic as well as the inelastic reactions assuming Δ-dominance and take into account the effect of Pauli blocking, Fermi motion and the renormalization of weak transition strengths in the nuclear medium. The quasielastic production cross-sections for lepton production are found to be strongly reduced due to nuclear effects, while there is about 10% reduction in the inelastic cross-sections in the absence of the final-state interactions of the pions. The numerical results for the momentum and angular distributions of the leptons averaged over the various atmospheric-neutrino spectra at the Soudan and Gran Sasso sites have been presented. The effect of nuclear-model dependence and the atmospheric-flux dependence on the relative yield of μ to e has been studied and discussed.  相似文献   
318.
Albumin which is the most abundant drug carrier protein in plasma controls the distribution aspect of drug pharmacokinetics. The aim of this study has been to elucidate the concurrent binding behavior of indomethacin/ibuprofen/heme to HSA under the effect of aspirin-mediated protein acetylation and also to explore the esterase-like catalytic property of the unmodified/modified proteins, as binary or ternary systems, by using various spectroscopic and molecular docking techniques. We found that aspirin-based modification of HSA affects the protein conformation as well as ligand binding at sites I–III. Decrease in pNPA-mediated esterase activity of HSA in different reversible inhibition modes, upon the protein–ligand interactions, was also documented, an issue that may receive considerable attention for computational prodrug design in near future.  相似文献   
319.
The unsteady stagnation point flow impinging obliquely on a flat plate in presence of a uniform applied magnetic field due to an oscillating stream has been studied. The governing partial differential equations are transformed into dimensionless form and the stream function is expressed in terms of Hiemenz and tangential components. The dimensionless partial differential equations are solved numerically by using well-known implicit finite difference scheme named as Keller-box method. The obtained results are compared with those available in the literature. It is observed that the results are in excellent agreement with the previous studies. The effects of pertinent parameters involved in the problem namely magnetic parameter, Prandtl number and impinging angle on flow and heat transfer characteristics are illustrated through graphs. It is observed that the influence of magnetic field strength increases the fluid velocity and by the increase of obliqueness parameter, the skin friction increases.  相似文献   
320.
Ethylene polymerization was carried out by using a group of new dizirconium(IV) tetrapyrrole complexes as catalysts and MAO as co-catalyst under 1 atmosphere pressure of ethylene gas at 25 and 40°C. The highest value of catalyst activity was obtained at 40°C by using bizirconium complexes including one calix[4]pyrrole between two zirconium centers and two terminal chlorines, while zirconium(IV) complexes with coordinated THF, almost have not catalytic activity. The maximum catalytic activity mounted to 830 kg/mol·bar·h by Zr2(Cy4 Pyr 4)Cl4. The results show that the structure of the coordination sphere of zirconium(IV) has great influence on the rate of polymerization, molar masses of forming polymer, and its molecular mass distribution.  相似文献   
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