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51.
52.
Estefania Fernandez-Bartolome Arturo Gamonal Jos Santos Saeed Khodabakhshi Eider Rodríguez-Snchez E. Carolina Saudo Nazario Martín Jos Snchez Costa 《Chemical science》2021,12(25):8682
Weak forces can play an essential role in chemical reactions. Controlling such subtle forces in reorganization processes by applying thermal or chemical stimuli represents a novel synthetic strategy and one of the main targets in supramolecular chemistry. Actually, to separate the different supramolecular contributions to the stability of the 3D assemblies is still a major challenge. Therefore, a clear differentiation of these contributions would help in understanding the intrinsic nature as well as the chemical reactivity of supramolecular ensembles. In the present work, a controlled reorganization of an hexakis[60]fullerene-based molecular compound purely governed by the weakest van der Waals interactions known, i.e. the dihydrogen interaction – usually called sticky fingers – is illustrated. This pre-reorganization of the hexakis[60]fullerene under mild conditions allows a further selective hydrogenation of the crystalline material via hydrazine vapors exposure. This unique two-step transformation process is monitored by single-crystal to single-crystal diffraction (SCSC) which allows the direct observation of the molecular movements in the lattice and the subsequent solid–gas hydrogenation reaction.Weak forces play an essential role in chemistry. Controlling these supramolecular interactions will contribute to the creation dynamic absorbent materials with a variety of technological applications as chemosensors and environmental remediation. 相似文献
53.
Keypour Hassan Khanmohammadi Hamid Wainwright Kevin P. Jameh-Bozorgi Saeed 《Transition Metal Chemistry》2004,29(5):523-527
The cyclocondensation of 2,6-diformylpyridine with N,N,N,N-tetrakis(2-aminoethyl)ethane-1,2-diamine (pentene) in the presence of MnII forms the [1 + 1] pendant arm Schiff-base macrocyclic complex, [MnL3]2+. The ligand is a 15-membered pentaaza macrocycle having two 2-aminoethyl pendant arms {L3= 6,9-bis(aminoethyl)-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentene}. The complex, investigated by analytical, spectroscopic and magnetic techniques, supports the formation of a highly symmetrical pentagonal bipyramid complex with the MnII ion located within a pentaaza macrocycle and two pendant amines coordinating on opposite sides of a plane defined by the macrocycle and the metal ion. The structure of the complex was also verified by ab initio HF-MO calculations using a standard 3-21G basis set. 相似文献
54.
Three new diamines 1,2-di(p-aminophenyloxy)ethylene, 2-(4-aminophenoxy)methyl-5-aminobenzimidazole and 4,4-(aminopheyloxy) phenyl-4-aminobenzamide were synthesized and polymerized with 3,3′,4,4′-benzophenone tetracarboxylic acid dianhydride (BP), 4,4′-(hexafluoroisopropyledene)diphthalic anhydride (HF) and 3,4,9,10-perylene tetracarboxylic acid dianhydride (PD) either by one step solution polymerization reaction or by two step procedure. The later includes ring opening poly-addition to give poly(amic acid), followed by cyclodehydration to polyimides with the inherent viscosities 0.62-0.97 dl/g. Majority of polymers are found to be soluble in most of the organic solvents such as DMSO, DMF, DMAc, m-cresol even at room temperature and few becomes soluble on heating. The degradation temperature of the resultant polymers falls in the ranges from 240 °C to 550 °C in nitrogen (with only 10% weight loss). Specific heat capacity at 300 °C ranges from 1.1899 to 5.2541 J g−1 k−1. The maximum degradation temperature ranges from 250 to 620 °C. Tg values of the polyimides ranged from 168 to 254 °C. 相似文献
55.
M. Ahmed S. Ahmed M. M. Saeed M. Z. Iqbal 《Journal of Radioanalytical and Nuclear Chemistry》1996,212(4):269-280
Extraction of Pr(III), Ho(III) and Er(III) has been studied in the pH range of 1–10 with N-benzoyl-N-phenylhydroxylamine (BPHA) in benzene. The separation was found to be quantitative in borate media from pH 7 to 10, at an ionic strength of 0.1M (H+, BO3
3–). The stoichiometric composition of the complexes under the optimal conditions of shaking time, pH and reagent concentration was formulated using slope analysis and found to be M(BPHA)3, where M=Pr(III), Ho(III) and Er(III). The effect of various masking agents shows that citrate, ascorbate, EDTA, oxalate, fluoride and phosphate form stable complexes with these rare earths as compared to BPHA. The decontamination factors for different cations with respect to these rare earths under the optimum conditions have been evaluated. 相似文献
56.
Chu I Liu F Soares A Kumari P Nomeir AA 《Rapid communications in mass spectrometry : RCM》2002,16(15):1501-1505
Rapid, generic gradient liquid chromatography/tandem mass spectrometry (LC/MS/MS) assays, designed to accelerate sample analyses, have been developed to keep pace with the productivity of advanced synthetic procedures. In this study, LC/MS/MS was combined with an in vitro, cell-based, blood-brain barrier (BBB) model to evaluate the potential of new chemical entities (NCEs) to cross the BBB. This in vitro assay provides the permeability of discovery compounds across a monolayer of a primary culture of bovine brain microvessel endothelial cells in a fraction of the time that is required for in vivo studies (brain/plasma concentrations), using only 2 mg of the compound. The results are consistent with in vivo brain/plasma concentration ratio data. 相似文献
57.
One‐pot synthesis of 1‐ and 5‐substituted 1H‐tetrazoles using 1,4‐dihydroxyanthraquinone–copper(II) supported on superparamagnetic Fe3O4@SiO2 magnetic porous nanospheres as a recyclable catalyst
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An effective one‐pot, convenient process for the synthesis of 1‐ and 5‐substituted 1H‐tetrazoles from nitriles and amines is described using1,4‐dihydroxyanthraquinone–copper(II) supported on Fe3O4@SiO2 magnetic porous nanospheres as a novel recyclable catalyst. The application of this catalyst allows the synthesis of a variety of tetrazoles in good to excellent yields. The preparation of the magnetic nanocatalyst with core–shell structure is presented by using nano‐Fe3O4 as the core, tetraethoxysilane as the silica source and poly(vinyl alcohol) as the surfactant, and then Fe3O4@SiO2 was coated with 1,4‐dihydroxyanthraquinone–copper(II) nanoparticles. The new catalyst was characterized using Fourier transform infrared spectroscopy, X‐ray diffraction, transmission electron microscopy, field emission scanning electron microscopy, dynamic light scattering, thermogravimetric analysis, vibration sample magnetometry, X‐ray photoelectron spectroscopy, nitrogen adsorption–desorption isotherm analysis and inductively coupled plasma analysis. This new procedure offers several advantages such as short reaction times, excellent yields, operational simplicity, practicability and applicability to various substrates and absence of any tedious workup or purification. In addition, the excellent catalytic performance, thermal stability and separation of the catalyst make it a good heterogeneous system and a useful alternative to other heterogeneous catalysts. Also, the catalyst could be magnetically separated and reused six times without significant loss of catalytic activity. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
58.
Glass doped with silver ions was fabricated using a dry technique and then irradiated at the scanning speed of 14 mm?s?1 using a nanosecond pulsed Nd:YVO4 laser operating at 355?nm. This led to the spatially selective, one-step precipitation of silver particles and fabrication of a homogeneously structured optical composite material: glass?Csilver composite. The optical and structural properties of such composite material can be designed at will, which could have potential impact on light/plasmon wave and sensing technologies, optoelectronics, and surface enhanced Raman spectroscopy. 相似文献
59.
60.
Soap-free emulsion polymerization (SFEP) of methyl methacrylate, butyl acrylate was conducted in water/methanol media with sodium salts of four different acidic comonomers, namely styrene sulfonic acid (NaSS), 2-acrylamide-2-methyl-1-propane sulfonic acid (NaAmps), acrylic acid (NaAA), and itaconic acid (Na2ita). It was found that the introduction of methanol as co-solvent (35 wt%) to the medium greatly decreases the amount of water-soluble polyelectrolyte in the cases NaAA and Na2ita while it does not make difference for NaSS and NaAmps. Having employed the concept of conductance dependency to the ion mobility, the onset concentration in which soluble chains were formed was detected. The addition of sulfonic-based comonomers (NaSS and NaAmps), first decreased particle size and then led to predomination of solution polymerization over SFEP. On the contrary, the incorporation of carboxylic-based comonomers (NaAA and Na2ita) led to increase in particle size. Moreover, the particle size results were in good qualitative agreement with the classical Smith–Ewart theory. 相似文献