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61.
An efficient diketene ring-opening synthesis of polyhydroquinoline derivatives using SBA-15 sulfonic acid modified mesoporous substrates a green and reusable catalyst in a single-pot four-component coupling reaction of diketene,alcohol,enamine,and aldehydes is reported.Dihydropyridine derivatives based on neat adduct of diketene,alcohols and aldehydes using SBA-15/SO3H nanoreactor as catalyst via a four-component reactions are also synthesized.The advantages of the present method include the use of a small amount catalyst,simple procedure with an easy filterable work-up,waste-free,green and direct synthetic method with an excellent yield of products with efficient use of catalyst and a short reaction time. 相似文献
62.
Seyyed Javad Sabounchei Mohsen Ahmadi Zahra Nasri Esmaeil Shams Sadegh Salehzadeh Yasin Gholiee Roya Karamian Mostafa Asadbegy Sepideh Samiee 《Comptes Rendus Chimie》2013,16(2):159-175
The non-symmetric phosphorus ylides and their Pd(II) complexes have been synthesized as potential antioxidant and antibacterial compounds and their structures were elucidated using a variety of physicochemical techniques. The reaction of 1 equiv non-symmetric phosphorus ylides, Ph2PCH2PPh2C(H)C(O)PhX (X = Br (Y1), Cl (Y2), NO2 (Y3), OCH3 (Y4)) with [Pd(dppe)Cl2] (M1), followed by treatment with 2 equiv AgOTf led to monomeric chelate complexes, [(dppe)Pd(Ph2PCH2PPh2C(H)C(O)PhX)] (OSO2CF3)2 (X = Br (C1), Cl (C2), NO2 (C3), OCH3 (C4)), which contain a five-membered P,P chelate ring in one side and a five-membered P,C chelate ring in the other side. Palladium ion complexes were synthesized and investigated by cyclic voltammetry, FT-IR, UV–visible, multinuclear (1H, 31P and 19F) NMR, thermal analysis and ESI-mass spectroscopic studies. Some complexes and ligands have been studied by powder XRD and single crystal X-ray diffraction techniques. FT-IR and 31P NMR studies revealed that the ylides Y are coordinated to the metal ions via the terminal phosphorus (Pc) of the ylides and methene group (CH). The proposed coordination geometry around the Pd atom in these complexes is defined as slightly distorted square planar by UV-Visible and DFT studies. Thermal stability of all complexes was also shown by TG/DTG methods. Furthermore, the electrochemical behavior of the complexes was investigated by cyclic voltammetry. The results indicate that all complexes are successfully synthesized from the initial ligands. All complexes were analyzed for their antioxidant properties by DPPH free radical scavenging assay. In addition, the antibacterial effects of the hexane-solved complexes were investigated by disc diffusion method against four Gram positive and negative bacteria. All complexes represented antibacterial activity against bacteria tested especially on Gram positive ones. A theoretical study on the structure, 1H and 31P NMR chemical shifts and the interaction energy between the Pd2+ ion and ligands dppe and ylide Y is also reported. 相似文献
63.
Motallebi Hasankola Seyed Sadegh Shafaghat Rouzbeh Jahanian Omid Nikzadfar Kamyar 《Journal of Thermal Analysis and Calorimetry》2020,139(4):2509-2516
Journal of Thermal Analysis and Calorimetry - Nowadays, due to the environmental problems caused by pollution and high fossil fuels prices, the study on the internal combustion engines have... 相似文献
64.
Maryam Shanehsaz Afshin Mohsenifar Sadegh Hasannia Nazanin Pirooznia Yasaman Samaei Mojtaba Shamsipur 《Mikrochimica acta》2013,180(3-4):195-202
We report on a method for the sensitive determination of Helicobacter that is based on fluorescence resonance energy transfer using two oligonucleotide probes labeled with CdTe quantum dots (QDs) and 5-carboxytetramethylrhodamine (Tamra) respectively. QDs labeled with an amino-modified first oligonucleotide, and a Tamra-labeled second oligonucleotide were added to the DNA targets upon which hybridization occurred. The resulting assembly brings the Tamra fluorophore (the acceptor) and the QDs (the donor) into close proximity and causes fluorescence resonance energy transfer (FRET) to occur upon photoexcitation of the donor. In the absence of target DNA, on the other hand, the probes are not ligated, and no emission by the Tamra fluorophore is produced due to the lack of FRET. The feasibility of the method was demonstrated by the detection of a synthetic 210-mer nucleotide derived from Helicobacter on a nanomolar level. This homogeneous DNA detection scheme is simple, rapid and efficient, does not require excessive washing and separation steps, and is likely to be useful for the construction of a nanobiosensor for Helicobacter species. Graphical Abstract
We report a method for the sensitive determination of Helicobacter that is based on fluorescence resonance energy transfer using two oligonucleotide probes labeled with CdTe quantum dots and 5-carboxytetramethylrhodamine respectively. 相似文献
65.
Hamid Yeganeh Moslem Mansour Lakouraj Sadegh Jamshidi 《Journal of polymer science. Part A, Polymer chemistry》2005,43(14):2985-2996
Biodegradable polyurethane elastomers with the potential for applications in medical implants were synthesized from the reaction of epoxy‐terminated polyurethane prepolymers (EUPs) with 1,6‐hexamethylenediamine as a curing agent. EUPs were themselves prepared from the reaction of glycidol and isocyanate‐terminated polyurethanes made from different molecular weights of poly(ε‐caprolactone) (CAPA) and 1,6‐hexamethylene diisocyanate. All materials were characterized by spectroscopic methods. The curing conditions were optimized by gel content measurements. The curing kinetic and kinetic parameters were determined from differential scanning calorimetry measurements. The effects of changing the crosslink density and crystallinity of elastomers via the alteration of the CAPA polyol molecular weight on the physical, mechanical, and degradation properties of the final elastomeric polymers were examined fully. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2985‐2996, 2005 相似文献
66.
Hassan Keypour Reza Azadbakht Sadegh Salehzadeh Hamid Khanmohammadi Hamidreza Khavasi Harry Adams 《Polyhedron》2008
Two new asymmetric tripodal tetraamine ligands, 2-((bis(2-aminoethyl)amino)methyl)benzenamine (L2) and 2-(((2-aminoethyl)(3-aminopropyl)amino)methyl)benzenamine (L3) were synthesized and characterized. [1+1] Macrocyclic Schiff-base complexes containing 1,2-diphenoxyethane head units and a 2-aminobenzyl pendant arm, were synthesized as [MnL4(MeOH)](ClO4)2 (1), [MnL5(MeOH)](ClO4)2 (2), [CdL4(H2O)](NO3)2 (3) and [CdL5(H2O)](NO3)2 (4) from the metal ion templated cyclocondensation reactions of 2-[2-(2-formylphenoxy)ethoxy]benzaldehyde with the (L2) or (L3) tripodal tetraamine ligands. The crystal structure determination of (1) and (4) showed that the complex cations that had formed consisted of pentagonal bipyramidally coordinated Mn(II) and Cd(II) ions, centrally located in a N3O2 macrocycle, with one 2-aminobenzyl pendant arm. Supporting ab initio HF-MO calculations have been undertaken using the standard 3-21G∗ and 6-31G∗ basis sets. 相似文献
67.
Mohammad Sadegh Amiri Vahideh Mohammadzadeh Mohammad Ehsan Taghavizadeh Yazdi Mahmood Barani Abbas Rahdar George Z. Kyzas 《Molecules (Basel, Switzerland)》2021,26(6)
Gums are carbohydrate biomolecules that have the potential to bind water and form gels. Gums are regularly linked with proteins and minerals in their construction. Gums have several forms, such as mucilage gums, seed gums, exudate gums, etc. Plant gums are one of the most important gums because of their bioavailability. Plant-derived gums have been used by humans since ancient times for numerous applications. The main features that make them appropriate for use in different applications are high stabilization, viscosity, adhesive property, emulsification action, and surface-active activity. In many pharmaceutical formulations, plant-based gums and mucilages are the key ingredients due to their bioavailability, widespread accessibility, non-toxicity, and reasonable prices. These compete with many polymeric materials for use as different pharmaceuticals in today’s time and have created a significant achievement from being an excipient to innovative drug carriers. In particular, scientists and pharmacy industries around the world have been drawn to uncover the secret potential of plant-based gums and mucilages through a deeper understanding of their physicochemical characteristics and the development of safety profile information. This innovative unique class of drug products, useful in advanced drug delivery applications, gene therapy, and biosynthesis, has been developed by modification of plant-based gums and mucilages. In this review, both fundamental and novel medicinal aspects of plant-based gums and mucilages, along with their capacity for pharmacology and nanomedicine, were demonstrated. 相似文献
68.
Research on Chemical Intermediates - In this research, high purity magnesium hydroxide (Mg(OH)2) nanoparticles were successfully synthesized by the wet chemical precipitation method from an impure... 相似文献
69.
Hadi Beiginejad Davood Nematollahi Sadegh Khazalpour 《Journal of the Iranian Chemical Society》2017,14(4):873-882
Electrochemical oxidations of 4-methylcatechol (1), 4-tert-butylcatechol (5) and catechol (7) in the presence of different nucleophiles have been investigated both experimentally and theoretically. Experimental results have been obtained by means of cyclic voltammetry and controlled-potential coulometry. Also the theoretical results were calculated at DFT (B3LYP) level of theory and 6–311+G (p, d) basis set. The calculated results indicate that oxidation potential of catechols (1, 5, 7) and their substituted species are directly dependent on the ?G tot, and continuance of reactions during electrolysis is dependent on ?G tot of produced species on the surface of electrode. The current study indicates that theoretical studies along with empirical research can be useful in displaying electrochemical reaction mechanisms. 相似文献
70.
Maziar Dehghan Mohammad Sadegh Valipour Seyfollah Saedodin 《Transport in Porous Media》2014,102(2):139-152
This study focuses analytically on the local thermal non-equilibrium (LTNE) effects in the developed region of forced convection in a saturated porous medium bounded by isothermal parallel-plates. The flow in the channel is described by the Brinkman–Forchheimer-extended Darcy equation and the LTNE effects are accounted by utilizing the two-equation model. Profiles describing the velocity field obtained by perturbation techniques are used to find the temperature distributions by the successive approximation method. A fundamental relation for the temperature difference between the fluid and solid phases (the LTNE intensity) is established based on a perturbation analysis. It is found that the LTNE intensity ( $\Delta \textit{NE}$ ) is proportional to the product of the normalized velocity and the dimensionless temperature at LTE condition. Also, it depends on the conductivity ratio, Da number, and the porosity of the medium. The intensity of LTNE condition ( $\Delta \textit{NE}$ ) is maximum at the middle of the channel and decreases smoothly to zero by moving to the wall. Finally, the established relation for the intensity of LTNE condition is simple and fundamental for estimating the importance of LTNE condition and validation of numerical simulation results. 相似文献