Mott gap excitations in twin-free YBa2Cu3O7-delta (Tc=93 K) studied by resonant inelastic x-ray scattering

Mott gap excitations in the optimally doped high-T(c) superconductor YBa(2)Cu(3)O(7-delta) (T(c)=93 K) have been studied by the resonant inelastic x-ray scattering method. Anisotropic spectra in the ab plane are observed in a twin-free crystal. The excitation from the one-dimensional CuO chain is enhanced at 2 eV near the zone boundary of the b* direction, while the excitation from the CuO2 plane is broad at 1.5-4 eV and almost independent of the momentum transfer. Theoretical calculations based on the one-dimensional and two-dimensional Hubbard model reproduces the observed spectra when different values of the on-site Coulomb energy are assumed. The Mott gap of the CuO chain site is found to be much smaller than that of the CuO2 plane site.     

X-ray fluorescence spectroscopy of inorganic solids—V: The relation between the X-ray energy shifts and the basicity of oxide glasses

X-ray fluorescence spectroscopy was applied to oxide glasses. Potassium K_α and K_β lines were found to shift depending upon the rest components and the composition. These data combined with the previous data of Si K_α and Al K_α line shifts are discussed as to their relations to bond nature and bulk basicity in vitreous solids.     

Noise control by barriers—Part 2: Noise reduction by an absorptive barrier

This paper presents a method of estimating the excess attenuation of a noise by an absorptive barrier covered with sound-absorbing materials. The approximate theory of diffraction by the absorptive barrier is derived from rigorous theory for a hard barrier. A single chart, which may be very convenient for the rapid estimation of the effect of absorption (the increase of the excess attenuation caused by the absorbing treatment of the barrier) in the practice of noise control, is presented. The validity of the method developed in this paper is confirmed by comparing estimated with measured values.     

Strahleninduzierte Polymerisation von Harnstoff-Kanal-Komplexen. 3. Mitt. Strahleninduzierte Polymerisation des Acrylnitril-Harnstoff-Kanalkomplexes im gefrorenen Zustand

Ohne Zusammenfassung     

A study of 3He-4He tunneling motion in solid 3He-4He mixtures by means of T1ϱ measurements

³He spin relaxation time in the rotating frame (T_1?) has been measured for 2% ³He in ⁴He solid samples of different molar volume at exchange plateau region (0.5 K). From the data, the characteristic frequency by which a ³He atom exchanges its position with a neighboring ⁴He atom is determined.     

Low energy electronic states and triplet pairing in layered cobaltate

The structure of the low-energy electronic states in layered cobaltates is considered starting from the Mott insulating limit. We argue that the coherent part of the wave functions and the Fermi-surface topology at low doping are strongly influenced by spin-orbit coupling of the correlated electrons on the t(2g) level. An effective t-J model based on mixed spin-orbital states is radically different from that for the cuprates, and supports unconventional, pseudospin-triplet pairing.     

Three-dimensional observation of an helical hot structure during a sawtooth crash in the WT-3 tokamak

Sawtooth crashes in an Ohmically heated plasma in the WT-3 tokamak have been observed by using soft x-ray computer tomography at three different poloidal cross sections around the torus. Initially, collapsing proceeds slowly with keeping the helical structure of an m = 1/n = 1 hot core around the torus. It accelerates as the helical hot structure is strongly deformed and fades away in the manner that the hot core at the high field side becomes obscure and disappears, while that at the low field side is deformed into a thin crescent aligned along the inversion circle, which survives even at the completion of the crash.     

Benzenthiolate bridged binuclear group 12 metal complexes with TTF fused dithiolate ligand,a new synthetic approach using cluster-cracking reaction

Novel binuclear dithiolate complexes (Me4N)2[M2-(SPh)2(S2TTF(SMe)2)2] (M = Cd and Zn) have been synthesized by a new cluster-cracking method.