Interfacial strength of joints between fibers and dispersedly filled epoxy matrices

The concentration dependences of adhesive strength are investigated for fiber/dispersedly filled epoxy matrix systems. The measurements were carried out using an improved model of adhesiometer under normal conditions at a constant rate of loading. It is shown that the adhesive strength as a function of filler concentration has a maximum, which is more or less pronounced. The location of the maximum depends on the nature of filler and particle geometry. The increase in the adhesive strength at the maximum reaches 20–30% in comparison with that for the unfilled epoxy matrix. Since the interfacial strength between steel wire and all the mineral powders investigated is zero, the growth in the adhesive strength upon introduction of a finely divided filler in polymer binders is rather un expected. The possible reasons for the phenomenon observed are discussed. __________ Translated from Mekhanika Kompozitnykh Materialov, Vol. 43, No. 1, pp. 3–14, January–February, 2007.     

Adsorption Properties of Thiocontaining Schungite

Chromatography–mass spectrometry and thermodesorption mass spectrometry have been employed to study mineral schungite-III, in which various thiocompounds have been detected and identified. The influence of these compounds on the adsorption activity of schungite with respect to iodine has been investigated. It has been shown that sulfur present in schungite has no effect on the results of determining its adsorption activity and does not interact with iodine; however, it can interact with amino compounds to yield sulfides. Activation energies E_a have been experimentally determined for sulfur, iodine, and dimethyl disulfide desorption from the surfaces of schungite and a model sorbent, graphitized thermal carbon black. The E_a values of these compounds have appeared to be several times lower than the heats of their adsorption on carbon black calculated by the molecular-statistical method.     

Special Features of the Interaction between Asymmetric Dimethylhydrazine and Thiocontaining Schungite

The interaction between asymmetric dimethylhydrazine and thiocontaining mineral schungite-III has been studied. Chromatography–mass spectrometry has been used to identify alkyl polysulfides as the products of desorption of asymmetric dimethylhydrazine from schungite surface. The interaction of asymmetric dimethylhydrazine with crystalline sulfur has been investigated in a model system. Dimethyl polysulfides, CH₃S_nCH₃; (dimethylamino)methyl polysulfides, (CH₃)₂NS_nCH₃; and bis(dimethylamino) polysulfides, (CH₃)₂NS_nN(CH₃)₂, with 2 ≤ n ≤ 4 have been detected. Gas-chromatographic retention indices have been determined for the products of the interaction of asymmetric dimethylhydrazine with sulfur and the schungite material.     

Properties of BaTiO3 and BaTiZrO3 Coatings Deposited by the Detonation Method

Russian Physics Journal -     

Preservation of stability of dynamical systems under homomorphisms

For abstract dynamical systems in the form of systems of motions, we obtain criteria for the preservation of stability properties via an extended notion of a homomorphism of dynamical systems. We obtain corollaries for ordinary differential equations including those with switchings of vector fields. We present examples illustrating the use of these criteria.     

On the self-adjoint nonlinear eigenvalue problem for Hamiltonian systems of ordinary differential equations with singularities

Certain properties of the nonlinear self-adjoint eigenvalue problem for Hamiltonian systems of ordinary differential equations with singularities are examined. Under certain assumptions on the way in which the matrix of the system and the matrix specifying the boundary condition at a regular point depend on the spectral parameter, a numerical method is proposed for determining the number of eigenvalues lying on a prescribed interval of the spectral parameter.     

Nonlinear eigenvalue problem for second-order Hamiltonian systems

The nonlinear self-adjoint eigenvalue problem for a Hamiltonian system of two ordinary differential equations is examined under the assumption that the matrix of the system is a monotone function of the spectral parameter. Certain properties of eigenvalues that were previously established by the authors for Hamitonian systems of arbitrary order are now worked out in detail and made more precise for the above system. In particular, a single second-order ordinary differential equation is analyzed.