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101.
T. K. Kar U. K. Pahari K. S. Chaudhuri 《Journal of Applied Mathematics and Computing》2005,19(1-2):311-326
The paper deals with the problem of selective harvesting in a prey-predator model with predator self limitation. Criteria for local stability and global stability for both the exploited and unexploited system are derived. The effort has been considered as a dynamic variable and taxation as a control instrument to protect the fish populations from over exploitation. Finally, the optimal taxation policy is discussed with the help of control theory. 相似文献
102.
Mateusz Pucilowski Mehdi Jangi Hesameddin Fatehi Kar Mun Pang Xue-Song Bai 《Proceedings of the Combustion Institute》2021,38(4):5597-5604
In this paper, the flame-wall interaction of reacting diesel spray under engine like conditions is investigated using large eddy simulations. The aim of this study is to understand the influence of the distance between the wall and the spray nozzle on the air entrainment rate, which is a key variable in formation/oxidation process of soot. Three experimental cases are investigated, a free jet case and two wall impingement cases with a distance from nozzle to wall of 30 mm and 50 mm, which are considered as characteristic wall impingement distances for light- and heavy-duty bores in diesel engines, respectively. The optical soot measurements imply a positive influence of wall on the rate of soot oxidation. Numerical simulations are employed to elucidate importance of different mechanisms for the air entrainment, i.e., air entrainment prior to flame lift-off position, enhanced mixing due to the wall impingement and enhanced mixing by the entrainment wave. The results show that oxidation process after the end of injection is driven by a different mixing mechanism depending on the distance to the wall. The 30 mm case resulted in a “mixing boost”, where the dominant mixing mechanism is the wall impingement vortex mixing, which gives rise to the fastest soot decay among the cases. The mixing in the 50 mm case is governed by a late wall impingement vortex mixing, giving rise to a low, but a constant air entrainment rate, i.e., a “mixing plateau”. The free jet case resulted in mixing governed by the entrainment wave mechanism. Both wall impingement cases have faster soot oxidation rate compared with the free jet case, but due to a different underlying mixing process. LES is shown to be able to replicate the line-of-sight measurements of natural OH* chemiluminescence and distribution of soot region from the optical soot diagnostics. 相似文献
103.
The connection between bulk glass properties and network topology is now well established. However, there has been little attention paid to the impact of network topology on the surface properties of glass. In this work, we report the impact of the network topology on both the transport properties (such as cationic inward diffusion) and the mechanical properties (such as hardness) of borate glasses with modified surfaces. We choose soda lime borate systems as the object of this study because of their interesting topological features, e.g., boron anomaly. An inward diffusion mechanism is employed to modify the glass surface compositions and hence the surface topology. We show that accurate quantitative predictions of the hardness of the modified surfaces can be made using topological constraint theory with temperature-dependent constraints. Experimental results reveal that Ca(2+) diffusion is most intense in glasses with lowest BO(4) fraction, whereas Na(+) diffusion is only significant when nonbridging oxygens start to form. These phenomena are interpreted in terms of the atomic packing and the local electrostatic environments of the cations. 相似文献
104.
Here, we predict that the ferromagnetically coupled cobalt-benzene-cobalt system will act as the smallest molecular spin filter with unprecedented spin injection coefficient. To validate our in-silico observation, we have performed state-of-the-art nonequilibrium Green's function calculations and analyzed the density of states of cobalt at the relativistic and nonrelativistic level of theory. Remarkably, we found that unpaired 3d electrons of cobalt are not participating in the spin transport process like other transition metal containing multidecker complexes. Instead, an admixture of the outer-sphere 4s and 4p orbitals of cobalt along with the 2p orbital of carbon of the benzene moiety is contributing to the singly occupied highest molecular orbital in the majority spin channel that creates a path for coherent spin transport leading to the extremely high spin injection coefficient of the system. The absence of the 3d electrons of cobalt in the spin transport process has been carefully examined, and it was found that the nodal structure of the 3d orbital of cobalt is not at all suitable for bonding in the cobalt-benzene-cobalt system. The whole study indicates that the underlying mechanism of the spin filter action in cobalt-benzene-cobalt is completely distinctive from the other known materials. 相似文献
105.
Ab initio and density functional theory calculations are used to monitor the process wherein a OH· radical is allowed to approach the various CH groups of a Leu dipeptide, with its CH(2)CH(CH(3))(2) side chain. After forming an encounter complex, the OH· abstracts the pertinent H atom, and the resulting HOH is then dissociated from the complex. The energy barriers for H· abstraction from the β, γ, and δ CH groups are all less than 8 kcal/mol, but a significantly higher barrier is computed for the C(α)H removal. This higher barrier is the result of the strong H-bonds formed in the encounter complex between the OH· and the NH and C═O groups of the peptide units that surround the C(α) atom. This low-energy complex represents a kinetic trap which raises the energy needed to surmount the ensuing H· transfer barrier. 相似文献
106.
Gautam Prasanna Kar Anirban Karmakar Jubaraj B. Baruah 《Journal of chemical crystallography》2010,40(8):702-706
Abstract
Crystal structures of two bis-phenols namely bis-(3,5-dimethyl-2-hydroxyphenyl)(3-amino phenyl)methane 1 and bis-(3,5-dimethyl-4-hydroxyphenyl)(3-aminophenyl) methane 2 are determined. The compound 1 crystallises in monoclinic P21/c with a = 12.2579(16) ?, b = 16.0906(19) ?, c = 10.6664(13) ?, β = 115.417(7)°, V = 1900.2(4) ?3 whereas 2 crystallizes in monoclinic C2/c, a = 9.2538(2) ?, b = 18.6579(4) ?, c = 23.2725(5) ?, β = 98.796(2)°, V = 3970.89(15) ?3. The crystal lattice of both the compounds shows presence of N–H···π interactions but no O–H···π interactions. 相似文献107.
The interaction of dislocations with copper-enriched precipitates in the matrix of body-centered cubic iron has been investigated
by the molecular dynamics method. It has been shown that dislocations stimulate the development of a phase instability of
body-centered cubic copper precipitates in a specific range of their sizes. This process is accompanied by the pinning of
dislocations by precipitates and makes a significant contribution to strengthening. The results obtained provide an adequate
explanation for the observed dependence of the strengthening in the Fe-Cu system on the precipitate size. 相似文献
108.
109.
110.
An SIR epidemic model with time delay, information variable and saturated incidence rate, where the susceptibles are assumed to satisfy the logistic equation and the incidence term, is of saturated form with the susceptibles. This model exhibits two bifurcations, one is transcritical bifurcation and the other is Hopf bifurcation. The local and global stability of endemic equilibrium is also discussed. Finally, numerical simulations are carried out to explain the mathematical conclusions. 相似文献