A new insight to the role of bubble properties on inertial effect in particle–bubble interaction

In this study the impact of bubble surface characterization (mobility or immobility), its diameter and velocity is investigated on inertial forces in particle–bubble collision efficiency (E_C). Three models including Sutherland (E_C-SU), Schulze (E_C-SC), and generalized Sutherland Equation (E_C-GSE) were taken into account with regard to their differences from the inertial point of view in the particle size range of 1–100?µm. Bubble diameters of 0.08, 0.12, and 0.15?cm and bubble velocities of 10, 20 and 30?cm/s were selected to study the flotation of chalcopyrite. Weber and Paddock collision model (E_C-W&P) was taken for evaluation of the effect of bubble surface mobility on E_C. It was found that when the bubble diameter is 0.12?cm, reducing bubble velocity from 30 to 20?cm/s, the inertia force can be ignored for wider range of particle size. Corresponding particle size in cross-sectional point between GSE and Schulze collision models was introduced for better evaluation of the positive and negative particle inertial effects. The best agreement between them was taken for bubble diameter of 0.12?cm and velocity of 20?cm/s. It was concluded that the influence of bubble velocity is more effective than bubble diameter regarding its role on particle inertial forces in particle–bubble interaction.     

Silicon Nano-Particles with High Resistance to Harsh Ambient Conditions

Silicon nanoparticles which have an average size of 1?nm are synthesized using electrochemical methods and their stability under high temperature and humidity conditions have been investigated. These types of Silicon nanoparticles exhibit strong blue emission (centered around 420?nm) upon excitation with ultraviolet illumination. Standard heating procedures showed that, these nanoparticles in a liquid suspension (de-ionized water) are stable to heating and they retain characteristic emissions even at elevated temperatures. Thin solid films of such Silicon nanocrystals also show good stability under plasma and oxidizing environments at high temperatures.     

Quantum dot semiconductor laser with optoelectronic feedback

The optoelectronic feedback (OEF) in quantum dot semiconductor lasers (QD SLs) is studied theoretically where a model includes wetting layer ground state and excited state for QDs are included separating electrons and holes in their dynamics. Both positive and negative OEF are studied. The time series of photon density, the phase portraits of carriers in the states are studied. The parameters affecting OEF are examined where an excitability is seen. The QD SL is found to be more sensitive to the changes in time delay compared with other SLs and a complicated routs are seen in the behavior of QD SL.     

Synthesis and properties of isoviagra. A 2‐methyl‐2H‐pyrazolo[4,3‐d]pyrirnidin‐7‐one isomer of viagra®

The synthesis and spectral properties (ir, ms, nmr) of a substituted 2‐methyl‐2H‐pyrazolo[4,3‐d]‐pyrimidin‐7‐one ( 3 ), an isomer of Viagra^®, are described. The key synthon, 4‐amino‐1‐methyl‐5‐propyl‐3‐pyrazolecarboxamide ( 7 ), is prepared via the reaction of ethyl 2,4‐dioxoheptanoate with methylhydrazine, followed by cyclization, nitration, amidation, and nitro group reduction. Interaction of 7 with 2‐ethoxyben‐zoyl chloride yielded the respective bis‐amide ( 8 ) which was cyclized in polyphosphoric acid to the corresponding pyrazolo[4,3‐d]pyrimidin‐7‐one derivative 9 . Chlorosulfonylation of 9 , and subsequent treatment with 1‐methylpiperazine furnished iso Viagra ( 3 ).     

DFT calculations of quadrupolar solid-state NMR properties: Some examples in solid-state inorganic chemistry

This article presents results of first-principles calculations of quadrupolar parameters measured by solid-state nuclear magnetic measurement (NMR) spectroscopy. Different computational methods based on density functional theory were used to calculate the quadrupolar parameters. Through a series of illustrations from different areas of solid state inorganic chemistry, it is shown how quadrupolar solid-state NMR properties can be tackled by a theoretical approach and can yield structural information.     

Global robust stability analysis of neural networks with discrete time delays

Global robust convergence properties of continuous-time neural networks with discrete delays are studied. By using a Lyapunov functional, we derive a delay independent stability condition for the existence uniqueness and global robust asymptotic stability of the equilibrium point. The condition is in terms of the network parameters only and can be easily verified. It is also shown that the obtained result improves and generalizes a previously published result.     

On the propagation of thermoelastic waves in temperature rate-dependent materials

The one-dimensional propagation of thermoelastic waves in isotropic homogeneous half spaces within the theory of Green and Lindsay [1] is studied. Padé-extended ray methods are employed to obtain the desired information. Comparisons between the predictions of the Green and Lindsay theory and the theory of Lord and Shulman [2] are made. Our ray series solutions show that for discontinuous thermal disturbances the displacement according to the Green and Lindsay theory is also discontinuous. This violates the fundamental continuum hypothesis that matter is impenetrable. For a simple numerical example we show also that a compressive behaviour in the displacement may be associated with a tensile behaviour in the stress and vice versa. This prediction of the Green and Lindsay theory is also unrealistic from the physical point of view.