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881.
882.
Ş. Hakan Üngören Mustafa Saçmacı Cengiz Arıcı Ertan Şahin Taner Arslan Fatma Kandemirli 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2877-2890
Novel alkyl substituted 3-(4-benzoyl-1,5-diphenyl-2,3-dihydro-1H-pyrazol-3-yl)-3-oxo-2-(triphenylphosphoranylidene) propanoates (3) were synthesized from 4-benzoyl-1,5-diphenyl-1H-pyrazole-3-carbonylchloride (1) and alkyl (triphenylphosphoranylidene) acetates (2a–b). The synthesized compounds were characterized by elemental analysis, spectroscopic studies (3a–b), and single crystal X-ray diffraction (3a). The mechanism of the reaction between (1) and (2a) was studied by AM1, and the geometrical parameters of the studied molecules were also carried out in B3LYP methods with the standard 6–31G (d,p) basis set. NBO analysis were studied for 1 and 2a B3LYP methods with the standard 6–31G (d,p) basis set. 相似文献
883.
Abdallah Harizi Noureddine Saïd Zine Mighri Hédi Zantour 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2623-2632
A variety of 5-aryl-3-[(1-dialcoxyphosphonyl)methyl]-1,2,4-triazoles 3 has been synthesized efficiently by treatment of trialkylphosphites with 5-aryl-3-chlorométhyl-1,2,4-triazoles 2 . Compound 2 has been prepared by action of N-chloroacylimidates 1 with hydrazines. The structure of triazoles 2 and 3 have been unequivocally confirmed by means of IR, 1 H, 13 C, 31 P NMR spectroscopy and mass spectra. 相似文献
884.
Firuze Diyar Altındağ Begüm Nurpelin Sağlık Ulviye Acar Çevik İlhan Işıkdağ Hülya Karaca Gençer 《Phosphorus, sulfur, and silicon and the related elements》2013,188(9):887-894
AbstractA series of 2-(substituteddithiocarbamoyl)-N-[4-((1H-imidazol-1-yl)methyl)phenyl]acetamide derivatives was designed and synthesized to combat the increasing incidence of drug-resistant fungal infections. All synthesized compounds were characterized by IR, 1H-NMR, 13C-NMR, and HRMS spectra and elemental analyses. Antifungal activity tests were performed against four different fungal strains. Molecular docking studies were performed to investigate the mode of action towards the fungal lanosterol 14α-demethylase, a cytochrome P450-dependent enzyme. ADME studies were carried out and a connection between activities and physicochemical properties of the target compounds was determined. Most of the final compounds exhibited significant activity against Candida albicans and Candida krusei with MIC50 value 12.5?μg/mL. The results of in vitro anti-Candida activity, a docking study and ADME prediction revealed that the newly synthesized compounds have potential anti-Candida activity and evidenced the most active derivative, 5b (2-Pyrrolidinthiocarbonylthio-N-[4-((1H-imidazol-1-yl)methyl)phenyl]acetamide), which can be further optimized as a lead compound. 相似文献
885.
Mohamed Saïdi 《manuscripta mathematica》2014,145(1-2):163-174
We prove a local-global principle for torsors under the prosolvable geometric fundamental group of a hyperbolic curve over a number field. 相似文献
886.
The set of Dyck paths of length 2n inherits a lattice structure from a bijection with the set of noncrossing partitions with the usual partial order. In this paper, we study the joint distribution of two statistics for Dyck paths: area (the area under the path) and rank (the rank in the lattice). While area for Dyck paths has been studied, pairing it with this rank function seems new, and we get an interesting (q, t)-refinement of the Catalan numbers. We present two decompositions of the corresponding generating function: One refines an identity of Carlitz and Riordan; the other refines the notion of γ-nonnegativity, and is based on a decomposition of the lattice of noncrossing partitions due to Simion and Ullman. Further, Biane’s correspondence and a result of Stump allow us to conclude that the joint distribution of area and rank for Dyck paths equals the joint distribution of length and reflection length for the permutations lying below the n-cycle (12· · ·n) in the absolute order on the symmetric group. 相似文献
887.
In the present paper we investigate some uniqueness and Ulam’s type stability concepts of fixed point equations due to Rus, for the Darboux problem of partial differential and integro-differential equations involving the Caputo fractional derivative. Our results are obtained by using weakly Picard operators theory. 相似文献
888.
We derive in this paper some new existence and uniqueness results for a nonlinear multi-orders impulsive differential equation subject to fractional multi-point fractional integral boundary conditions. The obtained results are based on the Banach’s contraction theorem as well as Schauder fixed point theorem. Finally, two illustrative examples are given. 相似文献
889.
A simple and useful tandem addition–cyclization reaction of primary amines on a prepared α-functionalized propylvinyl ketone 3 in methanol at reflux is a promising route for the synthesis of a new family of 1-alkyl-4-propionylpyrrolidin-2-ones 4.
[Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.] 相似文献
890.
[1,3]-Dipolar cycloadditions of N-aryl sydnones to benzothiophene 1,1-dioxide, 1-cyclopropylprop-2-yn-1-ol and 1-(prop-2-ynyl)indole gave fused pyrazole derivatives when carried out in refluxing toluene. While the first two dipolarophiles gave single regioisomers, this indolic derivative gave mixtures, the ratios of which appeared to be controlled by the phenyl substituents. Their structures were identified in the usual manner, supported by single crystal X-ray diffraction measurements. 相似文献