软x射线近贴显微技术

软x射线近贴显微技术不但可使活的生物样品成象,分辨率高于光学显微镜,而且人为的样品准备程序在该技术中都可避免。本文描述了用高功率激光打靶产生的等离子体作为软x射线源而进行的近贴显微研究,并得到了分辨率好于1μm的结果。     

岩盐型ZnO纳米微粒的光电子发射结构

报道了岩盐型氧化锌纳米微粒的X射线光电子发射结构,发现其中3d电子的强烈成键作用,还存在着3d-4sp杂化和离域电子弛豫态的贡献,表现出与纤锌矿型明显的差异. 关键词：     

北京同步辐射装置3B1B生物光谱实验站

本文介绍北京同步辐射装置（ＢＳＲＦ）３Ｂ１Ｂ光束线、生物光谱实验站和圆二色谱仪的基本情况。报道北京正负电子对撞机（ＢＥＰＣ）同步辐射专用光期间，我们在站测量了１１种手征性生物和药物样品的圆二色（ＣＤ）谱，首次在国内利用同步辐射光获取了Ｄ－苯丙氨酸等样品的ＣＤ谱和Ｄ－及Ｌ－亮氨酸对称的ＣＤ曲线。     

HBTMPTP与伯胺N1923对稀土元素(Ⅲ)的协同萃取

研究了二（2，4，4-三甲基戊基）单硫代膦酸（HBTMPTP，HL）和伯胺N1923的正己烷溶液从硫酸介质中对稀土元素（Ⅲ）的协同萃取．并以La（Ⅲ）为例，用斜率法、恒摩尔法和饱和法确定了协萃配合物的组成为（RNH3）3L2La（SO4）2，计算了协萃配合物的生成常数及热力学函数，观测了协萃配合物的IR谱．     

Electronic Structure and Magnetic Properties of SmCo7-xZrx

The electronic structure and magnetism of SmCo_7-xZr_x alloy are investigated using the spin-polarized MS-X. method. The results show that a few of electrons are transferred to the Sm(5d⁰) orbital due to orbital hybridization between Sm and Co atoms. The exchange interactions between 3d and 5d electrons are more important than the polarization effects of the conductive electrons, thus it is the main reason resulting in the long-range ferromagnetic order in SmCo_7-xZr_x. The Curie temperature of SmCo_7-xZr_x is generally lower than that of corresponding pure Co, which may be explained by the weaker average coupling strength between Co lattices due to some negative couplings mainly occurring of 2e site. The calculated results for the Sm₅Co₃₂Zr₂ cluster may lead to a better understanding of why SmCo_7-xZr_x is stable phase. Since the spin-up DOS peak of d electrons at E_F arises and the bonding of electrons at E_F strengthens with increasing Zr concentration, which results in the internal energy of the system decrease, the stable ferromagnetic order forms in SmCo_7-xZr_x.     

A Two-Dimensional Photonic Crystal Slab Mirror with Silicon on Insulator for Wavelength 1.3μm

A concrete two-dimensional photonic crystal slab with triangular lattice used as a mirror for the light at wavelength 1.3μm with a silicon-on-insulator （SOI） substrate is designed by the three-dimensional plane wave expansion method. For TE-like modes, the bandgap in the Г-K direction is from 1087nm to 1559nm. The central wavelength in the bandgap is about 1.3μm, hence the incident light at wavelength 1.3μm will be strongly reflected. Experimentally, such a photonic crystal slab is fabricated on an SOI substrate by the combination of EBL and ICP etching. The measurement of its transmission characteristics shows the bandgap edge in a longer wavelength is about 1540 nm. The little discrepancy between the experimental data and the theoretical values is mainly due to the size discrepancy of the fabricated air holes.     

HL—1装置SiC涂层辐照实验的表面分析

本文应用表面分析技术研究HL-1装置中SiC涂层的等离子体辐照性能。结果表明,SiC材料应用于孔栏和壁涂层有利于减少杂质和提高等离子体品质。     

Cyclic BSEC of block size 3

Balanced sampling plans excluding contiguous units (or BSEC) were first introduced by Hedayat, Rao and Stufken in 1988. In this note, we discuss constructions of these designs having cyclic automorphisms. We use Langford sequences to construct all possible cyclic BSEC (or CBSEC) with block size 3 and λ = 1,2, which establishes the necessary and sufficient conditions for such designs. Some constructions of the balanced sampling plan avoiding adjacent units, a generalization of BSEC, are also given for fixed λ.     

Behaviors of the positive temperature coefficient of resistance of poly(styrene‐co‐n‐butylacrylate) filled with Ni‐plated core‐shell polymeric particles

Conductive composite films of poly(styrene‐co‐n‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007     

Isolation and Structure Elucidation of Nortriterpenoids from Schisandra rubriflora

Seven new highly oxygenated nortriterpenoids, rubriflorins D–J ( 1 – 7 ), were isolated from the leaves and stems of Schisandra rubriflora, and their structures were elucidated on the basis of extensive analysis of spectroscopic data. These new compounds feature the opening of ring A compared with related known nortriterpenoids isolated from the genus Schisandra and showed weak activity against HIV‐1.