Kinematic and electrooptical anharmonicity in the semiempirical intensity theory of IR and raman spectra of polyatomic molecules

Saratov State University, 83 Astrakhanskaya Str., Saratov, 410601, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 62, No. 6, pp. 49–57, November–December, 1995.     

Asymptotic Expansions for the Distribution of the Maximum of Gaussian Random Fields

Some asymptotic results are proved for the distribution of the maximum of a centered Gaussian random field with unit variance on a compact subset S of ^N . They are obtained by a Rice method and the evaluation of some moments of the number of local maxima of the Gaussian field above an high level inside S and on the border S. Depending on the geometry of the border we give up to N+1 terms of the expansion sometimes with exponentially small remainder. Application to waves maximum is shown.     

Perturbations in the Spectra of the Rydberg Series of a Silver Atom

The main series of a silver atom with n = 5–70 are investigated. Perturbations of the np ² P _1/2,3/2 states with n = 10 and 17 caused by interaction with the selfionization 4d5s5p ⁴ P _1/2,3/2 states are detected. Energies of the selfionization states are determined.     

Composition of the essential oil ofSalvia garedzhii. Terpenoids and sesquiterpene hydrocarbons

The composition of the terpenoid and sesquiterpene hydrocarbon fraction ofSalvia garedzhii has been studied by chromato-mass spectrometry. A total of 19 compounds have been identified and a provisional assignment of another 6 components has been made.