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排序方式: 共有278条查询结果,搜索用时 15 毫秒
91.
92.
Chemical Preparation of Graphene Materials Results in Extensive Unintentional Doping with Heteroatoms and Metals
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Dr. Chun Kiang Chua Dr. Adriano Ambrosi Prof. Zdeněk Sofer Dr. Anna Macková Dr. Vladimír Havránek Dr. Ivo Tomandl Prof. Martin Pumera 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(48):15760-15767
Chemical synthesis of graphene relies on the usage of various chemical reagents. The initial synthesis step, in which graphite is oxidized to graphite oxide, is achieved by a combination of chemical oxidants and acids. A subsequent chemical reduction step eliminates/reduces most oxygen functionalities to yield graphene. We demonstrate here that these chemical treatments significantly contaminate graphene with heteroatoms/metals, depending on the procedures followed. Contaminations with heteroatoms (N, B, Cl, S) or metals (Mn, Al) were present at relatively high concentrations (up to 3 at %), with their chemical states dependent on the procedures. Such unintentional contaminations (unwanted doping) during chemical synthesis are rarely anticipated and reported, although the heteroatoms/metals may alter the electronic and catalytic properties of graphene. In fact, the levels of unintentionally introduced contaminants on graphene are often higher than typical levels found on intentionally doped graphene. Our findings are important for scientists applying chemical methods to prepare graphene. 相似文献
93.
Template-based nanoscale epitaxy has been explored to realize high-quality GaN on Si(1 1 1) substrates. We have employed polystyrene-based nanosphere lithography to form the nano-hole array patterns on GaN/Si(1 1 1) template and then, subsequent regrowth of GaN is carried out by metalorganic chemical vapor deposition (MOCVD). During the initial growth stage of GaN on such nanopatterned substrates, we have observed formation of nanoislands with hexagonal pyramid shape due to selective area epitaxy. With further epitaxial regrowth, these nanoislands coalesce and form continuous GaN film. The overgrown GaN on patterned and non-patterned regions is characterized by high-resolution X-ray diffraction (HRXRD) and high-spatial resolution optical spectroscopic methods. Micro-photoluminescence (PL), micro-Raman scattering and scanning electron microscopy (SEM) have been used to assess the microstructural and optical properties of GaN. Combined PL and Raman data analyses show improved optical quality when compared to GaN simultaneously grown on non-patterned bulk Si(1 1 1). Such thicker GaN templates would be useful to achieve III-nitride-based opto- and electronic devices integrated on Si substrates. 相似文献
94.
We give a simple proof of the Uncertainty Principle for finite nonabelian groups, which generalizes directly to compact groups. 相似文献
95.
Functionalization of Hydrogenated Graphene: Transition‐Metal‐Catalyzed Cross‐Coupling Reactions of Allylic C−H Bonds
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Dr. Chun Kiang Chua Prof. Zdeněk Sofer Prof. Martin Pumera 《Angewandte Chemie (International ed. in English)》2016,55(36):10751-10754
The chemical functionalization of hydrogenated graphene can modify its physical properties and lead to better processability. Herein, we describe the chemical functionalization of hydrogenated graphene through a dehydrogenative cross‐coupling reaction between an allylic C?H bond and the α‐C?H bond of tetrahydrothiophen‐3‐one using Cu(OTf)2 as the catalyst and DDQ as the oxidant. The chemical functionalization was confirmed by X‐ray photoelectron spectroscopy and Fourier transform infrared spectroscopy and visualized by scanning electron microscopy. The functionalized hydrogenated graphene material demonstrated improved dispersion stability in water, bringing new quality to the elusive hydrogenated graphene (graphane) materials. Hydrogenated graphene provides broad possibilities for chemical modifications owing to its reactivity. 相似文献
96.
A novel organocatalytic asymmetric tandem Michael-Henry reaction catalyzed by 9-amino-9-deoxyepiquinine (VI) has been developed. The reaction was efficiently catalyzed by catalyst VI to give highly functionalized cyclohexanes with four stereogenic carbons including two quaternary stereocenters in excellent enantioselectivities (97 to >99% ee) and high diastereoselectivities (93:7-99:1 dr). Thus, the first organocatalytic asymmetric Henry reaction of common ketones as acceptors is shown. 相似文献
97.
Dr. Chun Kiang Chua Prof. Martin Pumera 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(36):12550-12562
The rise in global demand for crucial chemical compounds has driven immense research in the fundamental science of catalysis. Graphene and its derivatives (chemically modified graphene, CMGs) have recently emerged as a new class of heterogeneous catalyst that promises economically viable and greener routes to these compounds. Although CMGs possess unique catalytic properties, the actual active sites are often points of discussion. Current minimal understanding on the possible effects of metallic impurities on the electrocatalytic performances of these CMGs calls forth the need to raise awareness on possible metallic impurities misrepresenting the actual chemical catalytic performances of the CMGs. This Minireview highlights the latest advances in the application of CMGs as catalysts, with an emphasis on the possible effects of metallic impurities on CMG catalysis. 相似文献
98.
Prof. D. Scott Bohle Dr. Zhijie Chua Maya Singer Hobbs Dr. Inna Perepichka Alexander Waked 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(39):13739-13747
The remarkably stable catenated hexa‐nitrogen chain in bis(benzotriazene‐4‐one) is structurally, theoretically, and spectroscopically characterized to illustrate the durability of the central N?N bond in this hexaazo chain. The reactions of this species illustrate the potential of these nitrogen catenates for the preparation of other condensed heterocycles, such as bispyrazolones, by thermal nitrogen exclusion or by trapping the single ring‐opened Dimroth intermediates. In these latter reactions, 2‐naphtholate anion condenses with bis(benzotriazene‐4‐one) to trap and retain a zwitterionic diazonium intermediate as an isolated diazo product, whereas transition metals ring effect ring‐extrusion of dinitrogen from the Dimroth intermediate to generate chelating σ‐aryls. The catenated nitrogen species can be stabilized by incorporating strong formal sp2?sp2 N?N σ bonds with orthogonal orientations. Extending these stabilization and activation principles may allow these types of nitrogen catenates to be useful synthons for other polyaza species. 相似文献
99.
Paul B. Huleatt Jacelyn LauSheena Chua Yun Lei TanHung Anh Duong Christina L.L. Chai 《Tetrahedron letters》2011,52(12):1339-1342
A concise, efficient and simple route to a series of bromoindole building blocks is described. The synthetic routes are highlighted by purification-free preparation of o-nitrocinnamate intermediates and clean, modified Cadogan indole syntheses. The scope of this indole synthesis has been explored and expanded through the use of a range of solvents and easily removable phosphine reagents. 相似文献
100.
We have developed a robust approach for the synthesis of 3,4-fused isoquinolin-1(2H)-one analogs. A benzonitrile or a nicotinonitrile bearing an ortho-substituent, such as -OH, -SH, or -NHR (R = alkyl or aryl) can be deprotonated by KOtBu and then reacted with methyl 2-(bromomethyl)benzoate (8) to form its corresponding O-, S-, or N-alkylation product. The product thus formed is then treated with KOtBu again to initiate a cascade process that will lead to the formation of its corresponding 3,4-fused isoquinolin-1(2H)-one. This multistep synthesis as well as the final product purification is achieved in a one-pot manner. 相似文献