Structures and stability of N13 cluster

Quantum chemical studies for the nine N₁₃ isomers with low spin were carried out at the UHF/6-31G*, UB3LYP/6-31G* and UMP2/6-311G* levels of theory. The most stable N₁₃ isomer is structure 1 with C_2v symmetry, which contains two separated pentazole rings connected by three nitrogen atoms. The results show that structures 1, 2, 3, 4 and 5 which are composed of the pentazole ring are more stable than the open chain structure 6 and structures 8 and 9 which contain the four- and six-membered rings. This suggests that the pentazole ring is a fundamental stable structural unit, which is applicable not only for the even-numbered nitrogen clusters, but also for the large odd-numbered clusters.     

Morlet小波在确定局部周期中的应用

本文通过引入改进的Morlet小波变换核函数,得到了等幅值的Morlet小波变换(MMWT)和功率谱(MMPS).理论及实验均表明,MMPS不但能够准确的确定信号的局部周期,而且使相同振幅(强度)的谐波产生了相同大小的MMPS,弥补了MPS的不足.对于MMWT还给出了相应的Morlet小波变换尺度与频率转化公式.     

集值映射的广义重心选择

给出了广义重心选择的一些结论.对任意r∈R+我们给出了具有紧凸像的映射F的一个选择.并且如果F的像不是凸集我们同样给出了一个选择.     

关于算子方程λA2+μA*2=αA*A+βAA*

本文主要是给出Hilbert空间上满足方程 λA²+μA^*2=αA^*A+βAA^* (λ,μ,α,β都是复数)的有界线性算子A的全部形式,并给出它的应用。     

主动成像系统距离选通实验方案设计

 距离选通技术是克服大气后向散射，提高主动成像系统信噪比的有效方法。分析了距离选通的技术要求，分别使用电源调制和机械调制的方法获得了适合用于主动成像系统脉冲光源,并进行了距离选通实验，机械调制方法适用于大功率连续半导体激光器。使用氙灯泵浦YAG激光器实现了对675 m和1 509 m距离目标的主动成像，详细分析了几种方案的利弊并提出了改进方法。     

非负整数格上元素的性质及其在刻画@-Fuzzy关系方程解集中的作用

首先讨论了非负整数格上元素的性质. 从而完全地刻画了非负整数格上@-Fuzzy关系方程(其中@表示inf-α合成)的解集.     

富氧条件下生物质基活性炭负载钾催化剂高选择性还原氮氧化物

研究了富氧环境中生物质基活性炭负载钾催化剂选择性还原氮氧化物的性能。结果表明,与煤基（褐煤）活性炭负载钾催化剂相比,生物质基（木屑）活性炭负载钾催化剂表现出高选择性还原NO能力,在2 h恒温稳态实验过程中能够保持80%的NO还原效率,而C-O₂反应活性仅为18%。X射线衍射、比表面积、X射线光电子能谱以及程序升温脱附实验表征结果显示,生物质基活性炭负载钾催化剂优异的选择性还原NO性能应归因于炭表面钾物种的高度分散性,这与催化剂的高比表面积以及大量的表面氧基团有关。另外,生物质基炭材料还原NO反应产物中具有较高的CO₂选择性。     

一维聚合物{[Co(N3)2(dps)2]·0.5H2O}n的合成，结构和磁性质

A coordination polymer {[Co(N₃)₂(dps)₂]·0.5H₂O}_n (1) (dps=dipyridin-4-ylsulfane) with one dimensional chains has been synthesized and the structure and magnetic properties were characterized. Complex 1 crystallizes belongs to monoclinic system and has space group P2₁/c. The Co^Ⅱ ion is six-coordinated and located at a compressed octahedral environment due to the Jahn-Teller effect. The ligand of dps bridges between Co^Ⅱ ions producing the infinite chains of Co…Co along a direction and, interestingly, four pyridyl groups of dps ligands form a propeller-shaped coordination geometry around Co^Ⅱ ion with the same spiral within the chain. These 1D chains are further linked through the hydrogen bonds to generate a 3D supermolecular network. Magnetic studies indicated that complex 1 shows very weak antiferromagnetic coupling between Co^Ⅱ ions in low temperature. CCDC: 769596.     

槲皮素在悬汞电极上的伏安行为研究

应用循环扫描伏安法考察槲皮素在悬汞电极上的电化学行为,并用线性扫描伏安法测定其含量。在0.1mol/LNa2CO3-NaHCO3(pH9.51)缓冲溶液中,槲皮素在-1.33V(vs.Ag/AgCl)处出现灵敏的还原峰,峰电流与其浓度在2.0×10-6～2.0×10-5mol/L(r=0.9989)范围内呈良好的线性关系。该方法可直接用于罗布麻叶中槲皮素的含量测定。     

齐次Morrey-Herz空间中高阶交换子的中心BMO估计

建立了具有粗糙核的Hardy—Littlewood极大算子高阶交换子及其相应的分数次极大算子高阶交换子在齐次Morrey-Herz空间上的中心BMO估计,并由此得到了由一类次线性算子所生成的高阶交换子在齐次Morrey—Herz空间上的相应结果.