四种多变量校准方法在FTIR多组分分析中的性能比较

本文对四种多变量校准方法－－经典最小二乘法（CLS），偏最小二乘法（PLS），卡尔曼滤波法（KFM）以及人工神经网络法（ANN）－－在多组分浓度分析方面的性能进行了比较。选择五种红外谱图严重混叠的大气有机毒物－－1，3－丁二烯，苯，邻二甲苯，氯苯和丙烯醛－－作为分析对象。分别计算各种方法对该5组分体系的平均预测误差MPE和平均相对误差MRE进行比较。结果表明，偏最小二乘法在处理这类问题中是最稳健的方法。     

系综分布和它的小涨落近似

由“从正则分布出发，在小涨落近似下得出的能量涨落分布公式”求得的能量涨落的二次矩与直接由正则分布求得的二次矩完全相同，但分别由二求得的高次矩并不完全相同。     

粒子鉴别中dE/dx和TOF的权重

在北京谱仪数据分析中,粒子鉴别使用了dE/dx和TOF的信息.在利用dE/dx和TOF联合鉴别粒子时,通常的做法是把两者的χ²值等权重相加(χ²方法).在不同的动量区间,dE/dx和TOF对粒子的鉴别能力不同.本文给出两者联合鉴别时不同动量区间的权重,并构造一个新的线性变量来进行粒子鉴别     

在白噪声分析中的广义维里拉普拉斯

一类广义维里拉普拉斯，把在白噪声分析构架中通常定义的维里拉普拉斯作为特殊情形而包含。     

PHOTOLUMINESCENCE STUDY ON Hg1-xCdxTe THIN FILM IMPLANTED WITH As ION

Photoluminescence spectra of a series of MBE-grown Hg_1-xCd_xTe samples with the same mole fraction of about x≈0.39 have been measured at different temperatures from 5 to 100 K. By aid of the temperature and exciting laser power dependence of photoluminescence peak energy and relative intensity, as well as of the comparison with other measurements, four main structures dominating in the photoluminescence spectra are attributed to band to band, D^oX, A^oX and D^oA^o transitions. A deep donor state level located at about 8.5meV below the bottom of the conduction band has been observed and is determined to be due to the arsenic-occupied mercury vacancies. Two acceptor levels located at about 14.5 meV and about 31.5 meV above the top of the valance band have also been found from the measuements, which are identified as the mercury vacancies and As in anion site, respectively.     

Activity coefficients for NaBr in aqueous ternary solutions with sodium propionate and butyrate from EMF measurements

The activity coefficients of NaBr in the NaBr–NaPropionate–H₂O and NaBr–NaButyrate–H₂O systems were determined from EMF measurements at constant total ionic strength of 0.1 0.5 1.0 1.5 2.0 and 2.5 mol-kg^–1 and at 25° C. The activity coefficients were fitted using Scatchard, Pitzer and Lim equations. Finally the excess Gibbs free energy of these mixtures were also calculated.     

火焰原子吸收光谱法测定磁化杯中铅、镉和铁

本文研究了火焰原子吸收光谱法测定磁化杯陶瓷内胆中Ｐｈ、Ｃｄ和Ｆｅ含量的方法。样品经粉碎，用硝酸－高氯酸混合液进行消解后测定。本法灵敏度高，干扰少，简单，快速，具有良好的精密度和准确度，其相对标准偏差分别为Ｐｂ３．９９％，Ｃｄ１０．７％，Ｆｅ０．９％。回收率Ｐｂ１００．６１％，Ｃｄ１０１．１８％，Ｆｅ１０２．４％。     

煤颗粒燃烧破碎特性及其分数维理论

本文采用激光衍射法和光学显微计算机图像系统及自行开发的软件,测量了三个典型煤在快速加热初期燃烧、等温加热燃烧和火焰燃烧方式的颗粒尺寸,运用分数维理论,建立了煤燃烧颗粒破碎理论,实验和理论研究揭示了煤燃烧中颗粒尺寸变化的本质,理论计算和实验结果符合良好。     

单晶光纤损耗谱测量装置

本文描述了一套用以测量单晶光纤损耗谱的装置。本装置由卤钨灯,单色仪,积分球,AgORbCs光电倍增管以及数据采集,处理和控制系统组成。可测量300～1150nm的光谱范围。利用本装置可获得单晶光纤的吸收光谱,透过率谱,散射光谱以及散射位置谱。     

Dirichlet型空间上的乘子

本文主要根据τ与μ的不同取值分三种情况刻划了Cn中单位球上Dirichlet 型空间上的点乘子空间M(Dτ,Dμ),并通过两个函数的构造表明:当τ≤n时,包含 关系M(Dτ)(?)Dτ和当τ>μ,τ>n-1时,包含关系M(Dτ)(?) M(Dμ)是严格的.