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61.
A novel fiber-based scheme for generating quadrature entanglement between a specific pair of frequency bands is proposed. The scheme is based on use of a nonlinear fiber, a spectral pulse shaper, and an adaptive feedback loop. It is numerically predicted that at least -5 dB of the quadrature entanglement will be created by preparation of an appropriate initial phase spectrum. Optimal control of the four-wave mixing terms of the Kerr Hamiltonian is crucial for improvement of the entanglement. 相似文献
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Mitsuru Yoshioka Ikuo Kikkawa Teruji Tsuji Yasuhiro Nishitani Sachio Mori Kyo Okada Masayuki Murakami Fumihiko Matsubara Masaaki Yamaguchi Wataru Nagata 《Tetrahedron letters》1979,20(44):4287-4290
A intermediate was obtained by novel reductive cleavage of , prepared from in steps including a new ester to ketone conversion. Regioselective bromination of followed by substitution and known conversions gave 1-oxacephems . 相似文献
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In the alpha-glycosylation study of the unusual, 2-deoxy amino sugar of kedarcidin, polystyrene-supported DBU (PDBU) was found to be invaluable to the clean preparation of the highly labile Schmidt donor of l-kedarosamine. By further recognition that the C4-alcohol should be left free for favorable acceptor reactivity, we could for the first time successfully assemble the C13-O-alpha-glycoside of the ansamacrolide substructure of the kedarcidin chromophore. [reaction: see text] 相似文献
68.
The goal of this paper is to study well-posedness to strictly hyperbolic Cauchyproblems with non-Lipschitz coefficients with low regularity with respect to timeand smooth dependence with respect to space variables. The non-Lipschitz conditionis described by the behaviour of the time-derivative of coefficients. This leads to a classification of oscillations, which has a strong influence on the loss of derivatives. To study well-posednesswe propose a refined regularizing technique. Two steps of diagonalizationprocedure basing on suitable zones of the phase spaceand corresponding nonstandard symbol classes allow to applya transformation corresponding to the effect of loss of derivatives.Finally, the application of sharp Gårding's inequality allows to derive a suitable energy estimate. From this estimatewe conclude a result about C
well-posedness of the Cauchy problem. 相似文献
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Collapse of a poly(N-isopropylacrylamide)(PNIPAM) chain upon heating and phase diagrams of aqueous PNIPAM solutions with very flat LCST phase separation line are theoretically studied on the basis of cooperative dehydration(simultaneous dissociation of bound water molecules in a group of correlated sequence),and compared with the experimental observation of temperature-induced coil-globule transition by light scattering methods.The transition becomes sharper with the cooperativity parameterσof hydration.Reentrant coil-globule-coil transition in mixed solvent of water and methanol is also studied from the viewpoint of competitive hydrogen bonds between polymer-water and polymer-methanol. The downward shift of the cloud-point curves(LCST cononsolvency) with the mole fraction of methanol due to the competition is calculated and compared with the experimental data.Aqueous solutions of hydophobically-modified PNIPAM carrying short alkyl chains at both chain ends(telechelic PNIPAM) are theoretically and experimentally studied.The LCST of these solutions is found to shift downward along the sol-gel transition curve as a result of end-chain association (association-induced phase separation),and separate from the coil-globule transition line.Associated structures in the solution,such as flower micelles,mesoglobules and higher fractal assembly,are studied by USANS with theoretical modeling of the scattering function. 相似文献