催化光度法测定痕量钒——钒(Ⅴ)-溴甲酚紫-过氧化氢体系

催化光度法测定钒已有报道[1～3],在0.45 mol·L-1磷酸介质及加热条件下,过氧化氢氧化溴甲酚紫褪色反应非常缓慢,而痕量钒对此反应具有较高的催化活性,且在一定浓度范围内,钒量与褪色反应程度呈线性关系,据此可建立测定痕量钒的方法.方法的检出限为1.9×10-6g·L-1,测定范围为0.003～1.8 mg·L-1.方法操作简便,重现性好,用于钢样中痕量钒的测定,结果满意.     

Least-cost Testing Sequence

If items have to pass each of a series of different tests to be accepted, the cost of testing can be minimized by doing the tests in a certain sequence. A simple rule for finding the least-cost sequence is proved and illustrated.     

One-pot synthesis of new-phase AgInSe2 nanorods

AgInSe2 nanorods with a previously unknown orthorhombic phase isostructural to AgInS2 have been prepared by the thermolysis of [(PPh3)2AgIn(SeC{O}Ph)4] in a mixture of oleylamine (OA) and dodecanethiol (DT) at 185 degrees C. A systematic study indicates that the ratio of surfactants is crucial for obtaining both monodispersed nanorods and the new orthorhombic phase AgInSe2. The AgInSe2 nanorods have been characterized by TEM, XRPD, EDX, and XPS.     

酶促开环聚合合成双亲性H型嵌段共聚物及其自组装

通过固定化酶Novozyme435（NV435）催化聚乙二醇（PEG）开环聚合己内酯（CL）得到端基带有羟基的ABA型三嵌段聚合物,用2,2-二氯代乙酰氯将聚合物的端羟基功能化形成H型大分子引发剂,在CuCl／HMTETA体系中引发4-乙烯基吡啶（4VP）进行原子转移自由基聚合反应（ATRP）,得到了具有两亲性的H型五嵌段聚合物（PVP）2-b—PCL-b．PEG-PCL-（PVP）2,用红外光谱（FT IR）,核磁共振（^1H NMR）,凝胶渗透色谱（GPC）对其结构与分子量及其分子量分布进行了表征,结果表明：H型五嵌段聚合物分子量46121g／mol,分子量分布1．30．并利用动态光散射（DLS）和原子力显微镜（AFM）对聚合物在水溶液中的自组装行为进行了研究,H型嵌段聚合物的胶束呈球形结构,平均直径为70nm左右．     

TDDFT Study on the Electronic Excitations and First Hyperpolarizabilities of Mixed-metal Carbonyl Clusters W2Ir2（μ-L）（CO）8（η^5-C5H4Me）2（L = dppe/dppf）

Mixed-metal carbonyl clusters of W2Ir2（CO）10（η^5-C5H4Me）2 1 and W2Ir2（μ-L）（CO）8（η^5-C5H4Me）2 （L = dppe 2, dppf 3） have been studied by TDDFT method focusing on their electronic and nonlinear optical properties. These three clusters exhibit the first static hyperpolarizabilities of medium magnitude （βtot-10×10^-30 esu）. The origin of β is discussed by the new proposed orbital-pair decomposition scheme by Barandes et al. The result suggests that the β values of the two clusters are mainly originated from d-d electron transition within the metal skeleton, and d-p （π＊） electron transition from metals to carbonyls and phenyl. The additional coordination by the electron donor group, ferrocene, makes cluster 3 own much larger β values, and the relatively longer range charge transfer from d orbitals of ferrocene to d orbirals of Ir and W is responsible for the enhanced β values.     

燃烧法制备纳米CdFe2O4及表征

以Fe（NO3）3.9H2O和Cd（NO3）2.4H2O为原料,以柠檬酸为还原剂,采用燃烧法制备了CdFe2O4纳米粉体,用X射线粉末衍射仪（XRD）、透射电子显微镜（TEM）、红外光谱（IR）和振动样品磁强计（VSM）等手段对样品进行了表征,结果表明,样品为尖晶石型铁酸镉纳米粉体,其粒径大约为20—50nm,且具有超顺磁性。     

A Queueing Model for Spare Coal Faces

Determining the best provision of spare coal faces to allow for unexpected closures of faces can be considered as a problem in queueing theory. A machine-interference type of model is examined with random input, exponential service time and a fixed maximum number of spares. Steady state results are derived for the probability of a given number of faces being out of action, for the average number of spare faces held and for the average loss of working time. Numerical values of the average loss of working time have been computed as a guide to management and examples are given. No practical applications have yet been made.     

Charge fluctuations in Au+Au collisions at RHIC energy

A hadron and string cascade model, JPCIAE, together with the corresponding Monte Carlo event generator, has been employed in this paper to investigate further the charge fluctuations in Au+Au collisions at Snn = 130 GeV. The default JPCIAE calculations are in good agreement with PHENIX and STAR data. We found that the thermal predictions for the π gas, the resonance π gas and quark matter deviate, respectively, from the corresponding dynamical simulations from the JPCIAE model. The discrepancies were also found between the π charge fluctuations and the charge fluctuations of all species of hadrons. However the charge fluctuations for "π from ρ and ω decay" and for all the hadrons from resonance decay are close to each other, indicating the correlation between positively and negatively charged hadrons is not sensitive to the species of hadrons. This work shows further that it is questionable to use the charge fluctuations as a signature of QGP.     

Layered Black Phosphorus: Strongly Anisotropic Magnetic,Electronic, and Electron‐Transfer Properties

Layered elemental materials, such as black phosphorus, exhibit unique properties originating from their highly anisotropic layered structure. The results presented herein demonstrate an anomalous anisotropy for the electrical, magnetic, and electrochemical properties of black phosphorus. It is shown that heterogeneous electron transfer from black phosphorus to outer‐ and inner‐sphere molecular probes is highly anisotropic. The electron‐transfer rates differ at the basal and edge planes. These unusual properties were interpreted by means of calculations, manifesting the metallic character of the edge planes as compared to the semiconducting properties of the basal plane. This indicates that black phosphorus belongs to a group of materials known as topological insulators. Consequently, these effects render the magnetic properties highly anisotropic, as both diamagnetic and paramagnetic behavior can be observed depending on the orientation in the magnetic field.