首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   506639篇
  免费   4118篇
  国内免费   1660篇
化学   254285篇
晶体学   8486篇
力学   24048篇
综合类   8篇
数学   60752篇
物理学   164838篇
  2021年   4529篇
  2020年   5083篇
  2019年   5691篇
  2018年   6995篇
  2017年   7121篇
  2016年   10163篇
  2015年   5841篇
  2014年   9731篇
  2013年   23397篇
  2012年   17624篇
  2011年   21505篇
  2010年   15663篇
  2009年   15563篇
  2008年   19456篇
  2007年   19406篇
  2006年   18079篇
  2005年   15978篇
  2004年   14865篇
  2003年   13149篇
  2002年   13108篇
  2001年   15341篇
  2000年   11586篇
  1999年   9098篇
  1998年   7616篇
  1997年   7382篇
  1996年   7010篇
  1995年   6224篇
  1994年   6127篇
  1993年   6086篇
  1992年   6563篇
  1991年   6852篇
  1990年   6515篇
  1989年   6372篇
  1988年   6194篇
  1987年   6217篇
  1986年   5818篇
  1985年   7672篇
  1984年   7902篇
  1983年   6428篇
  1982年   6678篇
  1981年   6399篇
  1980年   6204篇
  1979年   6572篇
  1978年   6609篇
  1977年   6589篇
  1976年   6669篇
  1975年   6193篇
  1974年   6166篇
  1973年   6258篇
  1972年   4423篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
271.
The Ni(II) ion catalyzed thermal decomposition of peroxomonosulfate (PMS) was studied in the pH range 3.42–5.89. The rate is first order in [PMS] and Ni(II) ion concentrations. At pH greater than or equal to 5.23, the reaction becomes zero order in [PMS] and this changeover in the order of the reaction occurs at a higher concentration of nickel ions. The first‐order kinetics in PMS can be explained as a rate‐limiting step and is the transformation of nickel peroxomonosulfate into nickel peroxide. This peroxide intermediate reacts rapidly with another PMS to give oxygen and Ni(II). The formation of nickel peroxide is associated with a small negative or nearly zero entropy of activation. The zero‐order kinetics in [PMS] can be explained by the fact that the hydrolysis of aquated nickel(II) ions into hydroxocompounds is the rate‐limiting step. The turnover number is 2 at pH 3.42 and increases with pH. © 2007 Wiley Periodicals, Inc. Int J Chem Kinet 39: 320–237, 2007  相似文献   
272.
The spectra of the intensity fluctuations of light scattered by large (erythrocytes of whole blood) and small (vesicles of surgical bile) particles in natural conditions were studied. It is shown that photon correlation spectroscopy can be used in analysis of variations in the size of biological particles in normal and pathological conditions and as an express method of noninvasive diagnostics of diseases.  相似文献   
273.
The kinetics of oxidation of Fe2+ by [Co(C3H2O4)3]3? in acidic solutions at 605 nm showed a simple first-order dependence in each reactant concentration. The second-order rate constant dependence on [H+] is in accordance with eqn (i) k2 = k′2 + k3[H+] (i) where k′2 and k3 have values of 73.4 ± 14.0 M ?1 s?1 and 353 ± 41 M?2 s?1, respectively, at 1.0 M ionic strength (NaClO4) and 25°C. At 310 nm the formation and decomposition of an intermediate, believed to be [FeC3H2O4]+, was observed. The increase in the rate of oxidation with increasing [H+] was interpreted in terms of a “one-ended” dissociation mechanism which facilitates chelation of Fe2+ by the carbonyl oxygens of malonate in the transition state.  相似文献   
274.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 55, No. 4, pp. 613–618, October, 1991.  相似文献   
275.
We consider strongly parabolic, Hilbert submanifolds in Riemannian Hilbert manifolds. We prove that their properties are analogous to the known properties in the finite-dimensional case. The main geometric result consists of Theorem 3: a complete, Riemannian, Hilbert submanifold of nonpositive extrinsic curvature and finite codimension in a Hilbert sphere is a great sphere.Translated from Ukrainskii Geometricheskii Sbornik, No. 33, pp. 91–100, 1990.The author expresses his thanks to Professor A. A. Borisenko for posing the problem and guiding the work.  相似文献   
276.
Modifications are introduced into the large-particle method to make it possible to use the method in arbitrary nonrectangular computing nets in the study of the flow of an ideal compressible gas over mobile thin permeable membranes. A problem in the aeroelasticity of a parachute is stated. An example is given of the solution of a problem in the stationary formulation for an axially symmetric parachute in the wake of a cylindrical leading body for supersonic flow.Translated fromDinamicheskie Sistemy, No. 6, 1987, pp. 16–22  相似文献   
277.
278.
Asymptotic high-freqeuncy estimates are obtained for the amplitudes of specular and non-specular reflections with extraction of the contribution of sound reradiation into the surrounding medium by Rayleigh type surface elastic waves. The conditions are found that govern the magnification of scattering in the opposite direction. The theoretical explanation of the book reflection effect /1/ for bounded sound beam incidence on the plane interface of a fluid-elastic solid is given by many authors in different situations (/12/, say). As for non-specular reflection of a plane sound wave by bounded elastic bodies (plates, cylinders, rods, and shells enclosed in a screen), studied most thoroughly in /3–9/, this effect is a consequence of satisfying the space-time resonance conditions between the incident acoustic wave and the normal surface waves excited in an elastic solid under total internal reflection.  相似文献   
279.
Summary The pH versus fluorescence intensity profiles of a series of new pH-indicators are reported. They are characterized by two pKa-values in the 3.7–4.9 and 6.9–7.9 range, respectively. The strong change in fluorescence intensity with pH allows the determination of pH's over a much wider range (typically 2–9) than with one-step indicators. They are therefore considered to be of potential utility for measurement of pH over the neutral and slightly acidity range which occurs, for instance, in bioliquids such as urine.
Eine neue Gruppe fluorescierender pH-Indicatoren für einen erweiterten pH-Bereich
Zusammenfassung Die Fluorescenzintensitätsprofile als Funktion des pH-Wertes einer Reihe von neuen pH-Indicatoren werden untersucht. Sie sind charakterisiert durch zwei pKa-Werte im Bereich 3,7–4,9 bzw. 6,9–7,9. Die gefundene starke Änderung der Fluorescenzintensität mit dem pH-Wert erlaubt eine pH-Bestimmung über einen viel weiteren Bereich (typischerweise 2 – 9) als mit einstufigen Indicatoren. Aus diesem Grund werden sie als potentiell nützlich angesehen zur Messung von pH-Werten im neutralen und schwach sauren Bereich, wie er z.B. in biologischen Flüssigkeiten, etwa im Urin, gegeben ist.
  相似文献   
280.
Results of an experimental observation of the voltage oscillations associated with a discrete tunneling of holes in porous silicon at room temperature are presented. The noise characteristics of diode structures with a porous silicon interlayer formed on heavily boron-doped silicon single crystals are studied. Peaks of excessive noise are observed at frequencies of ~1 MHz, at which single-electron oscillations should be expected. The peak noise power is found to increase with current according to the ~2.5 power law and, at a current density of 0.15 A/cm2, to exceed the noise power of the receiver by three to four orders of magnitude. The complex shape of the noise spectrum and its extension to the higher frequency region with increasing current are explained by the three-dimensionality of the system of nanometer-sized silicon grains embedded in insulating silicon dioxide of porous silicon.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号