Pervasiveness of cluster excitations as seen in the Mössbauer spectra of magnetic materials

Magnetic cluster excitations in various physical systems (e.g., soliton bearing one-dimensional solids, metallic alloys, amorphous materials, small particle aggregates, magnetically ordered substances near T_C, transition metal di-chloride graphite intercalation compounds, etc.) are described. Use of Fe-57 Mössbauer effect spectroscopy as a probe of the spin dynamics for inverse autocorrelation times between 10⁷Hz to 10¹⁰ Hz is emphasized. Particular attention is given to systems which exhibit local or long range magnetic order and whose Mössbauer spectra must therefore be described by more than one autocorrelation (or dwell) time for fluctuations between different allowed hyperfine field directions on a given site.     

Off-shell behaviour of theN-N interaction in a six-quark resonating group model of the deuteron

Two different 6-quark resonating group models of the deuteron are investigated to study the off-shell property of theN-N interaction. In the first model the quarks interact by a central one-gluon-exchange potential plus confinement potential. The meson-exchange contribution to then-p potential is simulated by a central GaussianN-N potential. In the second model the quarks interact by one-gluon-and one-pion-exchange potentials (central and noncentral) plus confinement potential. A small additional -exchange potential between neutron and proton binds the deuteron at the correct energy.Several off-shell variants of the two resonating group models are compared with each other by analyzing their elastic electron scattering cross sections. It is found that the standard renormalized version of the resonating group model yields potentials and wave functions that may be considered physical within the limitations of the model. Unitary off-shell transformations, which modify potentials and wave functions in any sizeable way, lead to a disagreement between the charge distribution predicted by the model via analysis of electron scattering and the charge distribution following from the microscopic quark distribution.Both of the 6-quark models support a soft repulsive core of the tripletn-p potential with a core height of around 900 MeV.     

Nontrivial extensions of a massless representation with definite helicity of the Poincaré group in 3+1 dimensions by the tensor product of two other massless representations with definite helicity

Let U _n (a, ) be a massless, helicity n/2, representation of the Poincaré group in 3+1 dimensions. U _n (a, ) is realized in an adapted nuclear space D _n. We explicitly determine the various classes of cohomology for the extension of U _n (a, ) by U _n1 (a, ) U _n2 (a, ).     

On the origin of additional peaks in the photoelectron spectra of yttrium

Ultraviolet Photoemission analysis of yttrium metal reveals well defined features far below the conduction band. In order to elucidate their origin, we have used X-ray/Ultra violet photoelectron spectroscopy together with inverse photoemission. The comparison of the spectra of clean yttrium and of H exposed yttrium suggests that these structures are most probably due to hydrogen bands, hydrogen being either in a stable surface hydride form or as subsurface H.     

Slowly relaxing tunneling states in neutron-irradiated quartz: A study of the internal friction at audio-frequencies

The internal friction of two neutron-irradiated quartz samples was measured at audio-frequency as a function of temperature. This is an extension of acoustic measurements to much lower frequencies and thus to much longer time scales. A temperature independent behaviour has been observed and is discussed in the framework of the tunnelling model. One of the major assumptions of this model regarding the tunnelling states with long relaxation time could be verified for neutron-irradiated quartz.     

Formation of patchy surface overlayers alkali adsorption and alkali carbon monoxide and oxygen coadsorption on Ru (0001) and Ru(10\overline 1 0)

The retarding-potential and LEED methods are used for obtaining information about the structure and uniformity of alkali (K and CS) and alkali-coadsorbate (CO and O) layers on Ru(0001) and Ru surfaces at 300 K. It was established that for alkali layers on the anisotropic Ru surface and for mixed coadsorbate layer the shape of the retarding potential curves, used for the work function measurements, becomes anomalous which indicates coexistence of patches of different work function on the surface. LEED data on these patchy surfaces showed the formation of a variety of ordered structures depending on the coadsorbate coverages. On the basis of the existing theory a simple mathematical simulation was performed in an attempt to interpret the observed changes in the retarding potential curves. The possible changes of this curves, induced by the formation of patches with varying contribution to the total retarding potential signal and the advantage of the retarding field method for determination the uniformity of surface overlayers are discussed.     

Characterization of reaction products formed during thin-layer chromatographic detection of thiocarbamate herbicides

The reaction between thiocarbamate herbicides and 2,6-dichlorobenzoquinone-N-chloroimine or 2,6-dibromobenzoquinone-N-chloroimine is suitable for the detection of these herbicides on thin-layer plates with high sensitivity. The reactions were followed by infrared, nuclear magnetic resonance and mass spectrometry. We have established the formation of 2,6-dichlorobenzoquinone-S-alkyl sulphenylimines. In the case of the bromo-derivative, halogen exchange and substitution on the quinone ring took place simultaneously leading to the formation of mixed halogenated 2,6-dihalo- and, in addition, 2,3,6-trihalobenzoquinone-S-alkyl sulphenylimines. The final product of the detection reaction, i.e. 2,6-dichlorobenzoquinone-S-alkyl sulphenylimine was reacted with 2,6-dibromobenzoquinone-N-chloroimine where 2,6-dichloro-3-bromobenzoquinone-S-alkyl sulphenylimine formed as a consequence of the looser bromine-carbon linkage on the 2 and 6 positions of the quinone ring.     

Pseudo-cross-conjugated mesomeric betaines. 1. Synthesis of pseudo-cross-conjugated mesomeric betaines from quinoxaline derivatives

A new method for the synthesis of pseudo-cross-conjugated mesomeric betainic heterocyclic compounds with an angular nitrogen atom has been developed consisting in the reaction of 1,4-dielectrophile — -carbethoxy-2-(3-chloro)quinoxalylacetonitrile with azoles. Experimental regularities have been studied and a reaction mechanism has been proposed including the stage of formation of an ylide from a quaternary azolium salt. A pseudo-crossconjugated mesomeric betainic heterocyclic compound containing a thiazole ring compound has been synthesized for the first time.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1528–1533, November, 1992.     

Synthesis of 24-epiteasterone

Starting from ergosterol, the synthesis of the brassinosteroid 24-epiteasterone has been achieved by the use of a new scheme for introducing a 3-hydroxy-6-keto group as the result of the Birch reduction of the corresponding 5-hydroxy-⁷-3,6-dione.Institute of Bioorganic Chemistry, Belorussian Academy of Sciences, Minsk. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 224–227, March–April, 1992.