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131.
R. Centore P. Riccio S. Fusco A. Carella A. Quatela S. Schutzmann F. Stella F. De Matteis 《Journal of polymer science. Part A, Polymer chemistry》2007,45(13):2719-2725
We have prepared new polyesters containing quadratic, nonlinear optical (NLO) active chromophores covalently incorporated into the main chain. In these polymers, the sequence of the chromophore units along the main chain is rigorously head to tail. All the polyesters are processable, both in the melt and in solution. For one polyester, a full second‐order NLO characterization has been performed. An out‐of‐resonance d33 coefficient of 21 pm/V at 1368 nm has been measured. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2719–2725, 2007 相似文献
132.
Adam Kiersnowski Jochen S. Gutmann Jacek Pigłowski 《Journal of Polymer Science.Polymer Physics》2007,45(17):2350-2367
ε‐caprolactone was polymerized in the presence of neat montmorillonite or organomontmorillonites to obtain a variety of poly(ε‐caprolactone) (PCL)‐based systems loaded with 10 wt % of the silicates. The materials were thoroughly investigated by different X‐ray scattering techniques to determine factors affecting structure of the systems. For one of the nanocomposites it was found that varying the temperature in the range corresponding to crystallization of PCL causes reversible changes in the interlayer distance of the organoclay. Extensive experimental and literature studies on this phenomenon provided clues indicating that this effect might be a result of two‐dimensional ordering of PCL chains inside the galleries of the silicate. Small angle X‐ray scattering and wide angle X‐ray scattering investigation of filaments oriented above melting point of PCL revealed that polymer lamellae were oriented perpendicularly to particles of unmodified silicate, while in PCL/organoclay systems they were found parallel to clay tactoids. Calorimetric and microscopic studies shown that clay particles are effective nucleating agents. In the nanocomposites, PCL crystallized 20‐fold faster than in the neat polymer. The crystallization rate in nanocomposites was also significantly higher than in microcomposite. Further research provided an insight how the presence of the filler affects crystalline fraction and spherulitic structure of the polymer matrix in the investigated systems. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2350–2367, 2007 相似文献
133.
134.
P. N. Sapozhnikov 《Journal of Mathematical Sciences》1991,53(6):578-582
An analog of a sufficient statistic is proposed in the finite-dimensional linear space of statistics. It is shown that the unbiased estimator of the linear function of a parameter closest to a given function, expressed in terms of a minimal linearly sufficient statistic, is potentially unbiased and optimal.Translated from Statisticheskie Metody Otsenivaniya i Proverki Gipotez, pp. 51–58, 1986. 相似文献
135.
V. I. Bliznikas A. P. Norden B. N. Shapukov A. P. Shirokov 《Journal of Mathematical Sciences》1991,55(6):2091-2100
Biographical information on the eminent Soviet geometer Boris Lukich Laptev (4/23/05–1/15-89) is given as well as a survey of his research in the areas of differential geometry and history of mathematics.Translated from Itogi Nauki i Tekhniki, Seriya Problemy Geometrii, Vol. 21, pp.27–42, 1989. 相似文献
136.
Pál Sohár Gábor Bernáth Géza Stájer Angela E. Szabo 《Magnetic resonance in chemistry : MRC》1989,27(9):872-876
Pentacyclic isoxazolines were obtained by the cycloaddition of benzonitrile oxide to norbornene-azetidinone-fused 3,1-oxazines. The constitutions of two of the isomers obtained, and the configurations and conformations of all products, were determined by means of 1H and 13C NMR spectroscopy and DNOE experiments. 相似文献
137.
We consider three one-dimensional quantum, charged and spinless particles interacting through delta potentials. We derive
sufficient conditions which guarantee the existence of at least one bound state. 相似文献
138.
139.
140.
Gabriel N. Gatica Ernst P. Stephan 《Numerical Methods for Partial Differential Equations》2002,18(1):105-128
This article deals with an expanded mixed finite element formulation, based on the Hu‐Washizu principle, for a nonlinear incompressible material in the plane. We follow our related previous works and introduce both the stress and the strain tensors as further unknowns, which yields a two‐fold saddle point operator equation as the corresponding variational formulation. A slight generalization of the classical Babu?ka‐Brezzi's theory is applied to prove unique solvability of the continuous and discrete formulations, and to derive the corresponding a priori error analysis. An extension of the well‐known PEERS space is used to define an stable associated Galerkin scheme. Finally, we provide an a posteriori error analysis based on the classical Bank‐Weiser approach. © 2002 John Wiley & Sons, Inc. Numer Methods Partial Differential Eq 18: 105–128, 2002 相似文献