A new phenanthropyran and a new biphenanthrene from the rhizomes of Dioscorea septemloba and their antioxidant activities

Abstract

A new phenanthropyran, dioscorone B (1), and a new phenanthrene (2), together with seven known compounds (3–9), were isolated from the 75% ethanol extract of Dioscorea septemloba rhizomes. The chemical structures of these compounds were elucidated by comprehensive spectroscopic methods including NMR, HRESIMS, IR, and UV spectra. Compounds 1–5 were first isolated from genus Dioscorea. The proton and carbon chemical shifts of compounds 1–9 were unambiguously assigned based on the 1D-NMR and 2D-NMR data. Compounds 1–5 and 8–9 were first tested for their antioxidant activities. Compounds 1 and 2 showed excellent activities with IC₅₀ values of 0.07?±?0.10?μM and 0.13?±?0.09?μM, respectively.     

Preparation, characterization, and the molecular structure of 2,4,6-trinitro-mesitylene

We reported in this study the synthesis, culture of crystal, and single-crystal X-ray crystallography of the 2,4,6-trinitro-trimethylbenzene (TNTM) compound. We found the crystal belongs to the Triclinic system with space group P-1. The compound was also characterized by FT-IR,¹H NMR, and MS spectroscopy techniques. Density functional theory (DFT) B3LYP was employed to optimize structure and calculate frequencies of TNTM. The calculated geometrical parameters are close to the corresponding experimental ones. The thermal decomposition of TNTM was investigated by DSC and TG–DTG methods at heating rate 10°C/min. The results indicate that TNTM has high heat-resistant ability.1

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A-B效应的动力学机制及其实验验证方案

主要讨论了A-B效应所产生的动力学机制，指出运动电子所产生的磁场和外磁场的相互叠加是产生A-B效应的动力学原因。如果能够屏蔽掉运动电子所产生的磁场使之不能和外磁场相互叠加，那么A-B效应也将随之消失。为了验证这一结论，提出了一种新的实验方案，该方案可以对A-B效应的动力学机制做出明确的判断。 关键词： A-B效应 超导电性 迈斯纳效应 介观物理     

熔锥型全波耦合器

从耦合模方程出发，分析了全光纤非对称熔融拉锥型耦合器的带宽特性，提出和论证了全波(O+E+S+C+L band)耦合器的制作方案，并且在工艺上实现了全波耦合，其带宽达到了390nm(1260—1650)，分束比1∶99；附加损耗01dB. 关键词： 全波耦合器 熔融拉锥 带宽 预拉伸     

Solvothermal Synthesis and Crystal Structure of a 1D Helical-chain Cobalt（II） Complex Containing （Quinolin-8-yloxy）acetate

The cobalt(II) complex with (quinolin-8-yloxy)acetate, [CoCl(C11H8NO3)]n (1), has been prepared via the solvothermal method and characterized by IR, elemental analysis, UV- Vis diffuse-reflection spectra and single-crystal X-ray diffraction analysis. Complex 1 is a novel carboxylate-bridged one-dimensional helical cobalt(II) polymer, and the Co(II) centre exhibits an approximately square pyramidal CoClNO3 coordination geometry. It crystallizes in monoclinic, space group P21/n, with a = 9.1594(10), b = 6.8864(7), c = 17.290(2) , β = 102.629(3)o, C11H8ClCoNO3, Mr = 296.56, V = 1064.2(2) 3, Z = 4, Dc = 1.851 g/cm3, F(000) = 596, μ = 1.856 mm-1, the final R = 0.0308 and wR = 0.0807. Interestingly, the chain complexes are assembled to form two-dimensional networks through intermolecular face-to-face π-π stacking interactions with the centroid-to-centroid distance of 3.559(1)  and the dihedral angle of 8.4(1)° between the aromatic rings.     

微波消解-火焰原子吸收光谱法测定环境土壤中的总铬

应用微波消解-火焰原子吸收光谱法测定环境土壤中总铬的含量.土壤样品经HNO3+HzO2微波消解体系消解后,采用氯化铵作为基体改进剂,用原子吸收分光光度计在波长357.9nm,富燃烧性(还原性)火焰中测定土壤中的铬.铬含量在0-2.00mg/L范围与吸光度呈良好的线性关系,线性相关系数r=0.9993,最低检出限为5.0...     

Theoretical investigation of electron paramagnetic resonance parameters and lattice distortion in α-Al2O3 crystal doped with V3+ ions

The electron paramagnetic resonance parameters D, g _∥ and g _⊥ for V³⁺ ions in α-Al₂O₃ crystals are calculated on the basis of the complete diagonalization method and the superposition model. In the calculation, the contributions of the variation of the cation–ligand bond lengths and bond angles are taken into consideration. The calculated results agree well with the experimental data. Our investigation shows that the local structure around the V³⁺ ions possesses a compressed trigonal distortion above the O^2?-triangle and an elongated trigonal distortion in the lower one.     

统一非对称光波导横向耦合模理论分析

光波导横向耦合模理论包含正交耦合模理论和非正交耦合模理论两大类, 为了追求形式上的完美, 两类理论没有统一的解析解, 并且都没有对非匹配耦合系统中耦合功率的非对称性进行深入研究. 本文一方面由Helmholtz方程出发推导出了一种新型的非正交耦合模方程, 并对两类理论中的耦合模方程进行了统一处理和求解, 得到了一种统一的解析解; 另一方面根据所得到的统一的解析解对非匹配耦合系统中耦合功率的非对称性进行了详细研究, 计算结果表明非匹配耦合系统中的最大互耦合功率和最小自耦合功率均可用统一的解析解进行近似计算. 关键词： 光波导 耦合模理论 耦合器 最大耦合功率     

钯和铂金属在石墨烯表面不同生长机理第一性原理研究

本文采用密度泛函计算方法,研究了钯和铂金属在石墨烯表面不同的生长机理.几何结构和电子结构分析表明,钯金属的d2z轨道电子通过石墨烯的π电子为中介,转移电子至钯金属的dxz+dyz轨道,并保持石墨烯的π电子不变.该电荷转移机理增强了钯金属与石墨烯衬底之间的相互作用,是钯在石墨烯表面生长的主要原因.反之,铂金属不存在该生长机理,而铂原子的自发团聚是铂金属无法在石墨烯表面生长的另一主要原因.     

Y型分子筛固载(1S,2S)-DPEN-Ru(TPP)2催化苯乙酮不对称加氢

采用自由配体法将(1S,2S)-DPEN(1,2-diphenyl-1,2-ethylene-diamine)-Ru(TPP)2(TPP=三苯基膦,triphenylphosphine)配合物封装于NaY沸石分子筛超笼中,制备了(1S,2S)-DPEN-Ru(TPP)2/Y主客体材料(1S,2S)-DPEN=1,2-二苯基-1,2-乙二胺).采用等离子体发射光谱ICP、粉末X射线衍射(XRD)、紫外光谱(UV-Vis)、氮吸附等物理化学手段对所制备材料进行了表征.结果表明,(1S,2S)-DPEN-Ru(TPP)2配合物封装于Y型分子筛超笼中保持了原有的物理化学性能;作为苯乙酮不对称加氢催化剂,在优化条件下,苯乙酮的转化率可达100%,(R)-苯乙醇的对映体过量值(ee值)可达61.0%.该催化剂具有良好的稳定性和重复使用性.