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131.
132.
基于Hill动力学与Michaelis-Menten方程,建立理论模型研究发状分裂相关增强子1(hairy and enhancer of split 1,Hes1)调控蛋白激酶B (Protein Kinase B,AKT)-鼠双微体2 (Murine Double Minute2,MDM2)-抗癌基因p53(p53)-第10号染色体缺失的磷酸酶及张力蛋白同源的基因(Phosphatase and tensin homolog deleted on chromosome ten,PTEN)通路的一种物理机制.研究发现,Hes1通过与PTEN结合抑制PTEN表达,并调控AKT信号.表明了Hes1蛋白的合成,以及Hes1与PTEN相互作用调控AKTMDM2-p53-PTEN通路信号,将会有效地控制细胞结果 . Hes1作为AKT-MDM2-p53-PTEN信号通路中上游调节的重要因素,还可以在一定程度上通过影响p53蛋白功能,改变p53对肿瘤的抑制性.理论结果可用于预测Notch通路信号异常诱导的致癌性,并进一步揭示了Notch信号通路影响细胞AKT-MDM2-p53-PTEN通路的激活... 相似文献
133.
134.
Alexandre P. Felgueiras Fbio M. S. Rodrigues Rui M. B. Carrilho Pedro F. Cruz Vitor H. Rodrigues Tams Kgl Lszl Kollr Mariette M. Pereira 《Molecules (Basel, Switzerland)》2022,27(6)
Four stereoisomeric monoether derivatives, based on axially chiral (R)- or (S)-BINOL bearing a chiral (+)- or (−)-neomenthyloxy group were synthesised and fully characterised by NMR spectroscopy and X-ray crystallography. The respective tris-monophosphites were thereof prepared and fully characterised. The coordination ability of the new bulky phosphites with Rh(CO)2(acac), was attested by 31P NMR, which presented a doublet in the range of δ = 120 ppm, with a 1J(103Rh-31P) coupling constant of 290 Hz. The new tris-binaphthyl phosphite ligands were further characterised by DFT computational methods, which allowed us to calculate an electronic (CEP) parameter of 2083.2 cm−1 and an extremely large cone angle of 345°, decreasing to 265° upon coordination with a metal atom. Furthermore, the monophosphites were applied as ligands in rhodium-catalysed hydroformylation of styrene, leading to complete conversions in 4 h, 100% chemoselectivity for aldehydes and up to 98% iso-regioselectivity. The Rh(I)/phosphite catalytic system was also highly active and selective in the hydroformylation of disubstituted olefins, including (E)-prop-1-en-1-ylbenzene and prop-1-en-2-ylbenzene. 相似文献
135.
建立了一台基于新研制的高重复频率皮秒扫描相机的双光子激发荧光寿命显微成像系统,重点介绍所研制的高重复频率皮秒扫描相机。为了在高时间分辨力的同时扩大时间测量范围,实现大面积两维空间高时间分辨取样测量,从而提高采样速率和更有效地发挥扫描相机的作用,设计和研制了一种大面积、高时间分辨力扫描变像管和一种重复频率高达1MHz的斜坡电压扫描电路。基于上述关键部件所研制的扫描相机具有重复频率高、扫描速度可调、时间分辨力高、工作面积大、非线性低、触发晃动小等优点。用钛宝石飞秒激光器作为激光脉冲源,通过脉冲提取器将76MHz的高重复频率降低为1MHz,采用可调延时器和标准具对扫描相机的时间分辨力、扫描速度和非线性进行标定。该系统的时间分辨力达到6.5ps,非线性为2.60%,可测量的时间范围从十几皮秒到几十纳秒。测量了若丹明6G和香豆素314两种标准荧光染料的荧光寿命,取得了与参考文献一致的实验结果。 相似文献
136.
137.
A new simple optical system based on optical beam deflection combining the holophote corner cube was developed in order to study the dynamics of laser-induced shock waves in air. In this method, we adopt a He-Ne laser beam as the detection beam. The He-Ne laser beam, reflected by corner cube, intersects the propagating shock wave at two successive positions. The measurement of the shock wave velocity benefits from the double peak signals induced by the same acting laser pulse, which is calculated from the time interval between the corresponding oscilloscope signals and the distance of the two He-Ne laser beams. By virtue of this setup, we are also able to determine the pressure of the generated shock waves. It is shown that this method is simple with a fairly good precision and is much easier than the conventional methods used for this task. 相似文献
138.
Rui Zheng 《Journal of Molecular Spectroscopy》2011,265(2):102-105
The rovibrational spectrum of the N2-N2O van der Waals complex has been recorded in the N2O ν1 region (∼1285 cm−1) using a tunable diode laser spectrometer to probe a pulsed supersonic slit jet. The observed transitions together with the data observed previously in the N2O ν3 region are analyzed using a Watson S-reduced asymmetric rotor Hamiltonian. The rotational and centrifugal distortion constants for the ground and excited vibrational states are accurately determined. The band-origin of the spectrum is determined to be 1285.73964(14) cm−1. A restricted two-dimensional intermolecular potential energy surface for a planar structure of N2-N2O has been calculated at the CCSD(T) level of theory with the aug-cc-pVDZ basis sets and a set of mid-bond functions. With the intermolecular distance fixed at the ground state value R = 3.6926 Å, the potential has a global minimum with a well depth of 326.64 cm−1 at θN2 = 11.0° and θN2O = 84.3° and has a saddle point with a barrier height of 204.61 cm−1 at θN2 = 97.4° and θN2O = 92.2°, where θN2(θN2O) is the enclosed angle between the N-N axis (N-N-O axis) and the intermolecular axis. 相似文献
139.
140.
臧宏亮 叶沿林 李智焕 王建松 楼建玲 李奇特 葛愉成 杨晓菲 李晶 蒋伟 冯俊 刘强 杨彪 陈志强 刘洋 吴鸿毅 牛晨阳 李晨光 王春光 王翔 刘威 高见 余翰舟 马军兵 马朋 白真 杨彦云 金仕纶 卢飞 《中国物理C(英文版)》2018,42(7):074003-074003
An experiment for p(~(14)C,~(14)C~*→~(10)Be+α)p inelastic excitation and decay was performed in inverse kinematics at a beam energy of 25.3 Me V/u.A series of~(14)C excited states,including a new one at 18.3(1)Me V,were observed which decay to various states of the final nucleus of~(10)Be.A specially designed telescope system,installed around zero degrees,played an essential role in detecting the resonant states near theα-separation threshold.A state at 14.1(1)Me V is clearly identified,being consistent with the predicted band-head of the molecular rotational band characterized by theπ-bond linear chain configuration.Further clarification of the properties of this exotic state is suggested by using appropriate reaction tools. 相似文献