全文获取类型
收费全文 | 9929篇 |
免费 | 1615篇 |
国内免费 | 1389篇 |
专业分类
化学 | 7517篇 |
晶体学 | 186篇 |
力学 | 487篇 |
综合类 | 90篇 |
数学 | 1075篇 |
物理学 | 3578篇 |
出版年
2024年 | 39篇 |
2023年 | 246篇 |
2022年 | 448篇 |
2021年 | 504篇 |
2020年 | 519篇 |
2019年 | 486篇 |
2018年 | 397篇 |
2017年 | 423篇 |
2016年 | 525篇 |
2015年 | 562篇 |
2014年 | 676篇 |
2013年 | 840篇 |
2012年 | 955篇 |
2011年 | 928篇 |
2010年 | 635篇 |
2009年 | 651篇 |
2008年 | 623篇 |
2007年 | 579篇 |
2006年 | 524篇 |
2005年 | 367篇 |
2004年 | 331篇 |
2003年 | 209篇 |
2002年 | 257篇 |
2001年 | 197篇 |
2000年 | 178篇 |
1999年 | 155篇 |
1998年 | 107篇 |
1997年 | 72篇 |
1996年 | 93篇 |
1995年 | 46篇 |
1994年 | 58篇 |
1993年 | 43篇 |
1992年 | 35篇 |
1991年 | 38篇 |
1990年 | 32篇 |
1989年 | 27篇 |
1988年 | 17篇 |
1987年 | 24篇 |
1986年 | 10篇 |
1985年 | 14篇 |
1984年 | 16篇 |
1983年 | 9篇 |
1982年 | 8篇 |
1981年 | 4篇 |
1977年 | 4篇 |
1975年 | 2篇 |
1974年 | 5篇 |
1971年 | 2篇 |
1959年 | 2篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
61.
62.
Correlations of conserved charges,i.e.,the baryon number,electric charge,and strangeness,are calculated at finite temperature and chemical potentials up to the fourth order.The calculations are done ina 2+1 flavor low energy effective theory,in which the quantum and thermal fluctuations are encoded through the evolution of flow equations within the functional renormalization group approach.Strangeness neutrality and a fixed ratio of the electric charge to the baryon number density are implemented throughout the computation.We find that higher-order correlations incorporate more sensitive critical dynamics than the quadratic ones.In addition,a non-monotonic dependence of the fourth-order correlations between the baryon number and strangeness,i.e.,-χ31BS/χ2Sand χ22BS/χ2S,on the collision energy is also observed. 相似文献
63.
Mid-infrared generation based on a periodically poled LiNbO3 optical parametric oscillator 下载免费PDF全文
We report a nanosecond Nd:YVO_4-pumped optical parametric oscillator (OPO) based on periodically poled LiNbO_3 (PPLN). Tuning is achieved in this experiment by varying the temperature and period of the PPLN. The design of double-pass singly resonant oscillator (DSRO) and confocal cavity enables the OPO threshold to be lowered considerably, resulting in a simple, compact, all-solid-state configuration with the mid-infrared idler powers of up to 466mW at 3.41μm. 相似文献
64.
本文测量了入射能为2–25 keV/u的Ne2+离子穿过不同厚度碳膜诱导的前向、后向 (分别对应出射表面和入射表面) 电子发射产额. 实验中通过改变炮弹离子的能量, 系统的研究了势能沉积、电子能损以及反冲原子对前向、后向电子发射产额的贡献. 结果表明, 离子的势能沉积只对后向电子发射有贡献, 前向、后向电子发射产额分别与Ne2+离子在薄膜出射、入射表面的电子能损近似成正比关系, 其中电子能损很低 (对应于离子能量很低) 的时候, 反冲原子对电子发射的贡献不能忽略.
关键词:
近玻尔速度
电子发射
电子能损
反冲原子 相似文献
65.
研究得到了偏离束腰入射的复宗量Laguerre-Gauss光束在强非局域非线性介质中传输的解析表达式,并且得到了其二阶矩束宽的解析解.通过例子研究了偏离束腰入射的复宗量Laguerre-Gauss光束在强非局域非线性介质中传输性质.结果表明:非(0, m)模的复宗量Laguerre-Gauss光束的光束形状随着传输而发生改变,并以Δz=πzc为周期做周期性演化.而(0,m)模复宗量Laguerre-Gauss光束在演化过程中则形状保持不变,仅改变光束宽度;不论功率多大,在偏离束腰入射条件下总是表现为呼吸子;只有当其为束腰入射,并且入射功率等于临界功率时才能形成孤子. 相似文献
66.
The adsorptive denitrogenation from fuels over three metal-organic frameworks(MIL-96(Al),MIL-53(Al)and MIL-101(Cr))was studied by batch adsorption experiments.Four nitrogen-containing compounds(NCCs)pyridine,pyrrole,quinoline and indole were used as model NCCs in fuels to study the adsorption mechanism.The physicochemical properties of the adsorbents were characterized by XRD,N2physical adsorption,FT-IR spectrum and Hammett indicator method.The metal-organic frameworks(MOFs),especially the MIL-101(Cr)containing Lewis acid sites as well as high specific surface area,can adsorb large quantities of NCCs from fuels.In addition,the adsorptive capacity over MIL-101(Cr)will be different for NCCs with different basicity.The stronger basicity of the NCC is,the more it can be absorbed over MIL-101(Cr).Furthermore,pore size and shape also affect the adsorption capacity for a given adsorbate,which can be proved by the adsorption over MIL-53(Al)and MIL-96(Al).The pseudo-second-order kinetic model and Langmuir equation can be used to describe kinetics and thermodynamics of the adsorption process,respectively.Finally,the regeneration of the used adsorbent has been conducted successfully by just washing it with ethanol. 相似文献
67.
Rui M. Novais Frank Simon Petra Pötschke Tobias Villmow José A. Covas Maria C. Paiva 《Journal of polymer science. Part A, Polymer chemistry》2013,51(17):3740-3750
This work reports the study of the effect of chemical functionalization of carbon nanotubes on their dispersion in poly(lactic acid). The nanotubes were functionalized by the 1,3‐dipolar cycloaddition reaction, generating pyrrolidine groups at the nanotube surface. Further reaction of the pyrrolidine groups with poly(lactic acid) was studied in solution and in the polymer melt. The former involved refluxing the nanotubes in a dimethylformamide/polymer solution; the latter was carried out by direct melt mixing in a microcompounder. The carbon nanotubes collected after each process were characterized by thermogravimetry and by X‐ray photoelectron spectroscopy, showing evidence of polymer bonded to the nanotube surface only when the reaction was carried out in the polymer melt. The composites with polymer modified nanotubes present smaller average agglomerate area and a narrower agglomerate area distribution. In addition, they show improved tensile properties at low CNT concentration and present lower electrical resistivity. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3740–3750 相似文献
68.
Abstract Dibutylstannylene acetals, particularly those derived from terminal diols, were found to be oxidized regiospeeifically to α-hydroxyketones in good to excellent yield by N-bromosuccinimide. One of the products, 3-deoxy-l,2-O-isopropylidene-α-D-erythro hexofuranos-5-ulose (8), exists to about 20% in solution as a mixture of dimers. One of the dimers can be obtained as a solid and its structure was determined tentatively by a combination of NMR experiments and MM3 molecular mechanics calculations. 相似文献
69.
ABSTRACT Convenient regio- and stereoselective syntheses of rhamnose-containing oligosaccharides via sugar-sugar orthoester formation and rearrangement are described. 1→3 Linked rhamno di- and trisaccharides were synthesized effectively using unprotected rhamnose residue as the glycosyl acceptor by this methodology. 相似文献
70.
近年来, 磁性纳米管的物理性质和相关应用得到了人们的广泛关注. 利用有效场理论研究了纳米管上双模随机晶场中Blume-Capel模型的磁化强度和相变性质, 得到了系统的磁化强度与温度和随机晶场的关系及其相图. 结果表明: 系统在稀释晶场、交错晶场和同向晶场中会表现出不同的磁学性质和相变行为; 稀释晶场和交错晶场会抑制系统的磁化强度, 导致其基态饱和值小于1, 而同向晶场则不会; 随着随机晶场参量的变化, 系统存在多个相变温度, 并呈现出三临界现象和重入现象. 相似文献