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排序方式: 共有201条查询结果,搜索用时 31 毫秒
101.
102.
H Machner M Betigeri J Bojowald A Budzanowski A Chatterjee J Ernst L Freindl D Frekers W Garske K Grewer A Hamacher J Ilieva L Jarczyk K Kilian S Kliczewski W Klimala D Kolev T Kutsarova J Lieb H Machner A Magiera H Nann L Pentchev HS Plendl D Protić B Razen P Von Rossen BJ Roy R Siudak J Smyrski RV Srikantiah A Strzałkowski R Tsenov K Zwoll 《Pramana》2001,57(2-3):399-416
Total and differential cross sections for the reactions p + d → 3He + m
0 with m=π, η and p + d → 3H+π+ were measured with the GEM detector at COSY for beam momenta between threshold and the maximum of the corresponding baryon
resonance. For both reactions a strong forward-backward asymmetry was found. The data were compared with model calculations.
The aspect of isospin symmetry breaking is studied.
Representing the GEM Collaboration 相似文献
103.
Allison M. Mills Michael Ruck 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(8):i71-i72
Tricerium(III) diiron(II,III) heptasulfide, Ce3Fe1.94S7, crystallizes in the polar hexagonal space group P63 and adopts the Ce6Al3.33S14 structure type. The Fe atoms occupy both tetrahedral and octahedral sites. Isolated FeS4 tetrahedra, all pointing in the same direction, are stacked along the threefold rotation axes. Chains of face‐sharing FeS6 octahedra propagate along the 63 axis. Vacancies resulting from the partial oxidation of Fe2+ to Fe3+ occur exclusively in the octahedral Fe sites. The Ce atoms are coordinated by [7+1] S atoms, which form bicapped trigonal prisms. 相似文献
104.
Nitsche F Goltz T Klauss HH Isaeva A Müller U Schnelle W Simon P Doert T Ruck M 《Inorganic chemistry》2012,51(13):7370-7376
Room-temperature precipitation from aqueous solutions yields the hitherto unknown metastable stoichiometric iron selenide (ms-FeSe) with tetragonal anti-PbO type structure. Samples with improved crystallinity are obtained by diffusion-controlled precipitation or hydrothermal recrystallization. The relations of ms-FeSe to superconducting β-FeSe(1-x) and other neighbor phases of the iron-selenium system are established by high-temperature X-ray diffraction, DSC/TG/MS (differential scanning calorimetry/thermogravimetry/mass spectroscopy), (57)Fe M?ssbauer spectroscopy, magnetization measurements, and transmission electron microscopy. Above 300 °C, ms-FeSe decomposes irreversibly to β-FeSe(1-x) and Fe(7)Se(8). The structural parameters of ms-FeSe (P4/nmm, a = 377.90(1) pm, c = 551.11(3) pm, Z = 2), obtained by Rietveld refinement, differ significantly from literature data for β-FeSe(1-x). The M?ssbauer spectrum rules out interstitial iron atoms or additional phases. Magnetization data suggest canted antiferromagnetism below T(N) = 50 K. Stoichiometric non-superconducting ms-FeSe can be regarded as the true "parent" compound for the "11" iron-chalcogenide superconductors and may serve as starting point for new chemical modifications. 相似文献
105.
The reaction of an electron‐rich transition metal M (M = Ru, Rh, Ir), tellurium and TeX4 (X = Cl, Br, I) resulted in black crystals of five ternary coordination polymers with the general composition [MIII(Te6)]X3 (M = Rh, Ir) and of the molecular cluster compound [RuII2(Te6)](TeIIBr3)4(TeIIBr2)2. X‐ray diffraction on single‐crystals revealed that the compounds [M(Te6)]X3 crystallize isostructurally in the trigonal space group type R$\bar{3}$ c. In their crystal structures linear, positively charged [MIII(Te6)] chains form the motif of a hexagonal rod packing. In the chain, each of the formally uncharged Te6 molecules with chair conformation acts as a bis‐tridentate bridging ligand to two M atoms. The octahedrally coordinated M atoms are spiro atoms in the chain of trans vertices sharing heterocubane fragments. Including the isolated halide ions, which provide charge balance, the entire arrangement resembles a cut‐out of the α‐polonium structure type.In the monoclinic compound Ru2Te12Br16 (space group P21/n), the ruthenium atoms of the hetero‐cubane core of the molecular cluster [Ru2(Te6)](TeBr3)4(TeBr2)2 are saturated by terminal bromidotellurate(II) groups. Again, the Te6 ring is formally uncharged. With the tellurium atoms acting as electron‐pair donors the 18 electron rule is fulfilled for the M atoms in all compounds. 相似文献
106.
Black crystals of [Rh(Te6)]Br3 (I), [Rh(Te6)]I3 (II), [Ir(Te6)]Cl3 (III), [Ir(Te6)]Br3 (IV), and [Ir(Te6)]I3 (V) are prepared from stoichiometric mixtures of Rh or Ir, Te, and TeX4 (X: Cl, Br, I; evacuated silica tube, 300—350 °C, 7 d). 相似文献
107.
Matthias F. Groh Dr. Anna Isaeva Prof. Dr. Michael Ruck 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(35):10886-10891
Two polymorphs of the new cluster compound [Ru2Bi14Br4](AlCl4)4 have been synthesized from Bi24Ru3Br20 in the Lewis acidic ionic liquid [BMIM]Cl/AlCl3 ([BMIM]+: 1‐n‐butyl‐3‐methylimidazolium) at 140 °C. A large fragment of the precursor’s structure, namely the [(Bi8)Ru(Bi4Br4)Ru(Bi5)]5+ cluster, dissolved as a whole and transformed into a closely related symmetrical [(Bi5)Ru(Bi4Br4)Ru(Bi5)]4+ cluster through structural conversion of a coordinating Bi82+ to a Bi5+ polycation, while the remainder was left intact. Both modifications have monoclinic unit cells that comprise two formula units (α form: P21/n, a=982.8(2), b=1793.2(4), c=1472.0(3) pm, β=109.05(3)°; β form: P21/n, a=1163.8(2), b=1442.7(3), c=1500.7(3), β=97.73(3)°). The [Ru2Bi14Br4]4+ cluster can be regarded as a binuclear inorganic complex of two ruthenium(I) cations that are coordinated by terminal Bi5+ square pyramids and a central Bi4Br4 ring. The presence of a covalent Ru? Ru bond was established by molecular quantum chemical calculations utilizing real‐space bonding indicator ELI‐D. Structural similarity of the new and parent cluster suggests a structural reorganization or an exchange of the bismuth polycations as mechanisms of cluster formation. In this top‐down approach a complex‐structured unit formed at high temperature was made available for low‐temperature use. 相似文献
108.
Synthesen,Eigenschaften und Kristallstrukturen der Cluster‐Salze Bi6[PtBi6Cl12] und Bi2/3[PtBi6Cl12]
Syntheses, Properties and Crystal Structures of the Cluster Salts Bi6[PtBi6Cl12] and Bi2/3[PtBi6Cl12] Melting reactions of Bi with Pt and BiCl3 yield shiny black, air insensitive crystals of the subchlorides Bi6[PtBi6Cl12] and Bi2/3[PtBi6Cl12]. Despite the substantial difference in the bismuth content the two compounds have almost the same pseudo‐cubic unit cell and follow the structural principle of a CsCl type cluster salt. Bi6[PtBi6Cl12] consists of cuboctahedral [PtBi6Cl12]2? clusters and Bi62+ polycations (a = 9.052(2) Å, α = 89.88(2)°, space group P 1, multiple twins). In the electron precise cluster anion, the Pt atom (18 electron count) centers an octahedron of Bi atoms whose edges are bridged by chlorine atoms. The Bi62+ cation, a nido cluster with 16 skeletal electrons, has the shape of a distorted octahedron with an opened edge. In Bi2/3[PtBi6Cl12] the anion charge is compensated by weakly coordinating Bi3+ cations which are distributed statistically over two crystallographic positions (a = 9.048(2) Å, α = 90.44(3)°, space group ). Bi6[PtBi6Cl12] is a semiconductor with a band gap of about 0.1 eV. The compound is diamagnetic at room temperature though a small paramagnetic contribution appears towards lower temperature. 相似文献
109.
110.
Pierre F. Poudeu Poudeu Michael Ruck 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(5):i41-i43
The silver bismuth tridecasulfide Ag3.5Bi7.5S13 crystallizes in the monoclinic space group C2/m. Its structure is built up of two alternating kinds of layered modules parallel to (001). In the module denoted A, octahedra around the metal positions (M = Ag/Bi, M2 and an S atom on 2/m, other atoms on m) alternate with paired monocapped trigonal prisms around Bi. The NaCl‐type module B is composed of parallel eight‐membered chains of edge‐sharing octahedra running diagonally across it. Ag3.5Bi7.5S13 is the member with N = 8 of the pavonite homologous series NP of ternary compounds with the general formula [Bi2S3]2·[AgBiS2](N−1)/2. 相似文献