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921.
V. K. Rybin L. P. Revina L. A. Baratova N. V. Makarov 《Chemistry of Natural Compounds》1992,27(4):518-519
922.
Jürgen Kurths M. Carmen Romano Marco Thiel Grigory V. Osipov Mikhail V. Ivanchenko István Z. Kiss John L. Hudson 《Nonlinear dynamics》2006,44(1-4):135-149
We present two different approaches to detect and quantify phase synchronization in the case of coupled non-phase coherent
oscillators. The first one is based on the general idea of curvature of an arbitrary curve. The second one is based on recurrences
of the trajectory in phase space. We illustrate both methods in the paradigmatic example of the R?ssler system in the funnel
regime. We show that the second method is applicable even in the case of noisy data. Furthermore, we extend the second approach
to the application of chains of coupled systems, which allows us to detect easily clusters of synchronized oscillators. In
order to illustrate the applicability of this approach, we show the results of the algorithm applied to experimental data
from a population of 64 electrochemical oscillators. 相似文献
923.
The mechanisms of liquid-phase phenol ozonation are revised. A new mechanism in which a significant role is played by free-radical reactions is suggested for this process. 相似文献
924.
V. F. Tret’yakov A. G. Zakirova V. A. Matyshak T. N. Burdeinaya V. N. Korchak L. S. Glebov V. V. Lunin 《Kinetics and Catalysis》2006,47(6):873-880
According to X-ray diffraction analysis data, the test catalyst was a Ni-Cr spinel with an impurity of NiO. With the use of in situ IR spectroscopy, it was found that nitrite, nitrate, and acetate surface complexes occurred under the reaction conditions of the selective catalytic reduction of nitrogen oxides by propane in the presence of oxygen on the nickel-chromium catalyst. As the temperature was increased, the nitrite complexes were converted into nitrate species. The molar absorption coefficient of surface nitrate complexes was determined. According to IR-spectroscopic and TPD data, the nitrate complexes were bound relatively weakly to the surface. The temperature region of their existence was 50–200°C. The temperature region of existence of the surface acetate complexes was 200–400°C. The individual adsorption of oxygen was not observed; however, oxygen-containing surface sites (Cr5+=O) participated in the formation of the surface complexes of reactants. 相似文献
925.
V. L. Bratman Yu. K. Kalynov V. N. Manuilov S. V. Samsonov 《Radiophysics and Quantum Electronics》2005,48(10-11):731-736
We develop a thermionic-emission electron-optical system forming a dense beam of electrons moving along helical trajectories round the axis of a gyrotron cavity. The maximum beam current is 4 A and the pitch-factor of electrons is 1.0 for a particle energy of 250 keV and a pulse duration of 10 µs. Using such a beam in a gyrotron operated at the third cyclotron harmonic, we obtain single-mode oscillation with a power of 10 µs in the TE3,8 and TE3,9 modes with frequencies 371 and 414 GHz, respectively. 相似文献
926.
927.
Problems associated with interferences in the analysis of serum for polychlorinated biphenyls 总被引:2,自引:0,他引:2
V W Burse M P Korver P C McClure J S Holler D M Fast S L Head D T Miller D J Buckley J Nassif R J Timperi 《Journal of chromatography. A》1991,566(1):117-125
During a recent survey to determine serum concentrations of polychlorinated biphenyls (PCBs) among people living around New Bedford, MA, U.S.A., an unidentified contaminant precluded the quantification of some early eluting Webb and McCall peaks. Loss of data is estimated to have reduced reported serum levels by 12%. Efforts to identify the contaminant by gas chromatography with an electron-capture detector, a Hall electrolytic condutivity detector, and mass spectrometer were not successful. Researchers ascertained, however, that the contaminant is not a PCB, it does not contain halogens, but it may contain phthalates. Vacutainer tubes and closures for serum storage bottles are suspected sources of contamination. 相似文献
928.
The theoretical proton-40Ca optical potential is constructed based on theα-particle model of the nucleus. With this potential, the differential cross section, analysing power and the spin rotation function for 200 MeV proton-40Ca elastic scattering are calculated. The results are in good agreement with the experimental data. 相似文献
929.
Any system that approximates an infinite lattice by a family of finite clusters (with periodic boundary conditions) passes through an intermediate region with enlarged (hidden) symmetry as the system size is increased. The hidden symmetry allows for extra degeneracies and level crossings and has application to exact-diagonalization studies, Monte Carlo simulations, lattice gauge theories, and renormalization group calculations. 相似文献
930.
We have studied by ESR and ENDOR spectroscopy the free radicals produced in γ-irradiated inclusion compound formed between the ketone 10-nonadecanone and urea. Only one type of long lived radical is formed by the removal of an α-proton from the ketone. The hyperfine (hf) coupling constants of the α- and β-protons of the radicals have been measured by ESR at different temperatures in the range 110–292 K and at different orientations of the crystals. The hf coupling of the γ-protons of the radical and of the urea protons have been studied by ENDOR. The temperature and angular dependences of the coupling constants have been analyzed in terms of the internal and overall motions of the radical inside the hexagonal channels formed by the urea molecules. It has been found that the radical cannot perform complete reorientations around the long molecular axis, but it undergoes restricted rotational diffusion. This process is explained by assuming a coupling between the rotational and translational degrees of freedom of the radical inside the urea channels. 相似文献