Facile Assembly of Dispersed ZrMCM‐41 Nanoparticles Promoted in‐situ by Zirconium Salt

Mesoporous ZrMCM‐41 nanoparticles were synthesized by a usual way where tetraethyl‐orthosilicate (TEOS) and zirconium nitrate were used as the inorganic precursors. The obtained nanoscale ZrMCM‐41 was characterized by X‐ray diffraction, N₂ physis‐sorption, scanning electron microscopy and transmission electron microscopy. Characterization results revealed that zirconium salt added in the synthesis had a crucial effect on the assembly of nanoscale ZrMCM‐41 with relatively uniform particle size, which was rarely observed in reported studies for ZrMCM‐41 synthesized using the similar method. Meanwhile, the possible mechanism behind the synthesis was discussed based on the character of hydrolysis and condensation of TEOS and the mild acidic environment induced by the hydrolysable zirconium salt under aqueous conditions. Thus obtained nanoscale ZrMCM‐41 with developed pore structures may be advantageous to general applications in catalysis or adsorption host‐guest chemistry in terms of efficient mass transport of guest molecules.     

Synthesis and Characterization of New Schiff Base and Polyoxa-azaCryptands and Their Rare Earth Cryptates with [1 1] Condensation and Reduction Methods

IntroductionWithspecialandnovelstructures,macropolycyclicmoleculespreselltamultitudeofnewproperties'andopenupvastvistasforapplicationsinmanyfields"',suchassupramoleculardevices,luminescentlabels,fluorescentprobesinbiologicalandmedicalapplications,magneticresonanceimagingandcatalyticcleavageofRNA,and.-theyarealsoimportantligands'forrecognizinginorganicandorganiccanons,anionsandneutralmolecules.Becauseofmulti-stepprocessandlowyields',thesynthesisofmacropolycycliccompoundsaresometimesverydifficu…     

Bioinspired polymer functionalized with a diiron carbonyl model complex and its assembly onto the surface of a gold electrode via “click” chemistry

A complex pendant with two ethynyl groups, [Fe₂(μ‐SCH₂CCH)₂(CO)₆] ( 2 ), as a model of the diiron subunit of [FeFe]‐hydrogenase was polymerized and the {Fe₂(CO)₆} core was successfully incorporated into the polymer matrix. The polymer was characterized by a variety of spectroscopic techniques, TGA, FTIR, SEM, TEM, and NMR. The resultant polymer was immobilized via “click” chemistry using its terminal C?CH bond onto the surface of a gold electrode, which was premodified with azidothiol by self‐assembled monolayer (SAM). The assembled electrode showed electrochemical responses. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2410–2417, 2010     

四种三唑化合物的合成及它们在盐酸介质中对碳钢缓蚀性能的研究

本文通过“点击化学”的方法合成了四种1,2,3-三唑化合物(3a, 3b, 4a和4b)，通过IR, ¹H NMR, ¹³C NMR 和 single crystal X-ray 晶体结构衍射分析对化合物进行了表征。通过交流阻抗和动电位扫描极化曲线研究四种化合物在1 mol/L HCl 中对碳钢的缓蚀性能。研究结果表明，四种化合物均可作为高效阳离子缓蚀剂，其中化合物4b的缓蚀效果最好，最高抑制效率可达97％。     

The Ionic Conductivity of Solid Electrolytes for Li4+xMxSi1–xO4‐yLi2O (M=Al,B) Systems

The Li_4+xM_xSi_4+xO₄‐yLi₂O (M=Al, B; x = 0 to 0.6, y = 0 to 0.5) ion conductors were prepared by the Sol‐Gel method and examined in detail. The powder and sintered samples were characterized by DTA‐TG, XRD, SEM, and AC impedance techniques. The experimental results show that the conductivity and sinterability in creased with the amount of excess lithium oxide in the silicate. The Li₂O phase acts as a flux to accelerate the sintering process and to obtain high conductivity of grain boundaries. The particle size of the sintered pellets is about 0.25 μm. The maximum conductivity at 200 °C is 5.40 × 10^?3s cm^?1 for Li_4.4Al_0.4 Si_0.6O₄‐0.3Li₂O.