Flow birefringence of dilute solutions of polyethyleneoxide of high molecular weight at high rates

Summary Birefringence and orientation angle of solutions of Polyox WSR 301 in the concentration range of 50 to 1350 ppm have been measured up to 8000 s^–1. A few marked differences with ordinary flexible polymers have been evidenced: (i) a very low value of the extinction angle at high shear rate, which could be attributed to an unusually high molecular weight; (ii) the independence of this angle on the concentration, which is due to the variation of the flexibility with the concentration, as shown by the study of the concentration dependence of the segmental optical anisotropy; (iii) the concentration dependence of the elongation shows a plateau value forc 150 ppm, which may come from a concentration dependent and reversible association process, as shown from reduced viscosity measurements.

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Zusammenfassung Es wurden die Doppelbrechung und der Orientierungswinkel von Polyox-WSR 301-Lösungen im Konzentrationsbereich 50–1350 ppm bis zu Schergeschwindigkeiten von 8000 s^–1 gemessen. Dabei wurden einige ausgeprägte Unterschiede gegenüber normalen flexiblen Polymeren gefunden: (i) ein sehr niedriger Wert des Auslöschwinkels, was auf ein ungewöhnlich hohes Molekulargewicht schließen läßt: (ii) die Unabhängigkeit dieses Winkels von der Konzentration, was von einer Änderung der Flexibilität mit der Konzentration herrührt, wie sie durch die Untersuchung der Konzentrationsabhängigkeit der optischen Anisotropie der Segmente aufgezeigt wird; (iii) die Existenz eines Plateaus in der Konzentrationsabhängigkeit der Streckung beic 150 ppm, welches auf einen konzentrationsabhängigen reversiblen Assoziationsvorgang hindeutet, der auch durch Messung der reduzierten Viskosität nahegelegt wird.

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With 5 figures     

Critical time for shock formation in radiative magnetogasdynamics

For the general case of magnetogasdynamics coupled to the radiation field, a differential scheme which is capable of dealing with variable optical depths, leads to a hyperbolic system of equations. To this system the standard techniques for evaluating the critical time of weak discontinuities is applied. In this paper the critical time for radiative magnetoacoustic waves propagating into a constant state is analyzed. Plane waves, spherical waves and cylindrical waves are studied.     

The measurement of the material parameters of viscoelastic fluids using a rotating sphere and a rheogoniometer

Summary In this work, measurement of the flow field around a rotating sphere has been used to obtain the material parameters of a second-order Rivlin-Ericksen fluid. Experiments were carried out with a Laser-Doppler anemometer to obtain the velocity distribution and usingGiesekus' analysis, the material parameters for the second-order fluid were obtained.

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Zusammenfassung In dieser Untersuchung wird die Ausmessung des Strömungsfeldes um eine rotierende Kugel dazu verwendet, um die Stoffparameter einer Rivlin-Ericksen-Flüssigkeit zweiter Ordnung zu erhalten. Die Experimente zur Bestimmung der Geschwindigkeitsverteilung werden mit einem Laser-Doppler-Anemometer durchgeführt, und zur Auswertung der Parameter der Flüssigkeit zweiter Ordnung wird eine Analyse vonGiesekus benutzt.

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Notations A ₁,A₂ Rivlin-Ericksen tensor - A ² Parameter used in eq. [12] - a Radius of the sphere - B Parameter used in eq. [12] - I Unit tensor - m ₀(₁ – ₂)/a², parameter used by ref. (8) - N ₁,N₂ First and second normal stress difference - p Isotropic pressure - Radial distance from the centre of the rotating body - S ₁,S₂ Stress tensor - v _r,v,v Velocity components in a spherical coordinate system - ₀,₁,₂ Material parameters used in eq. [2] - Shear rate - _a Apparent voscosity - ₀ Zero-shear viscosity - Angle measured from the axis of rotation - Fluid density - Stream function - Shear stress - Angular velocity With 3 figures     

Rising vortex ring in a viscous fluid

Most theoretical results for thermals, whose motion is determined by the complex interaction between dynamics and buoyancy, have been obtained numerically [1–4]. The analytic solutions for a convection element have been limited to consideration of the self-similar regime [5]. At the same time, the preself-similar stage of development of a vortex ring of dynamic origin has been described analytically [6]. This approach is now extended to a rising vortex ring. In this case a modification of the traditional formulation of the problem makes it possible to obtain an analytic solution of the problem of a weak thermal in the form of unsteady temperature, vorticity and stream function fields that tend in the limit to the self-similar regime. The rate of ascent of the convective vortex ring is found. A solution is obtained for the two-dimensional analog of the problem.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 3, pp. 42–48, May–June, 1989.     

Acoustic scattering and radiation problems, and the null-field method

The best known methods for solving the scattering and radiation problems of acoustics are integral-equation methods. However, it is also known that the simplest of these methods yield equations which are not uniquely solvable at certain discrete sets of frequencies (the irregular frequencies). In this paper, we shall analyse an alternative method (the null-field method, or T-matrix method). We prove that the infinite system of null-field equations always has precisely one solution, i.e. the unphysical irregular frequencies do not occur with this method. Moreover, we also prove that the solution of the original boundary-value problem can always be determined (at any point exterior to the scatterer) from the solution of the null-field equations. We prove these results in two dimensions, for two radiation problems (the exterior Neumann problem and the exterior Dirichlet problem) and two scattering problems (scattering by a sound-hard body and scattering by a sound-soft body); similar results can be proved in three dimensions. We also prove some subsidiary results, concerning the solvability of certain boundary integral equations and the completeness of certain sets of radiating wave-functions, and give a discussion of related numerical techniques.     

Non-equilibrium relativistic M.H.D. with finite electrical conductivity

A system of balance laws for relativistic m.h.d, with finite eIectrical conductivity, heat flux and viscosity is proposed, starting from the properties of the systems of conservation laws compatible with a supplementary balance law (entropy balance). Adopting a two-fluid scheme the plasma is treated as a mixture of a neutral fluid and a charged fluid. Following the approach ofextended thermodynamics heat flux, viscous stress and electric current density are considered as new field variables contributing to non equilibrium entropy density and flux.     

Numerical modeling of carbon monoxide neutralization by metered water injection into a high-temperature mixture of combustion products

A closed mathematical model of the flow of a two-phase mixture consisting of evaporating water droplets and a chemically reacting multicomponent gas is described. The effect of the real droplet heating and evaporationkinetics on the gas-phase chemical reactions in a mixture of combustion products is studied within the framework of this model.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No.6, pp. 96–106, November–December, 1993.     

Allowance for the unsteadiness of the flow in determining the critical cavitation number for marine propellers

A method of estimating the critical cavitation number for marine propeller blades is proposed. This method is based on the reduction of the three-dimensional unsteady problem to the three-dimensional steady problem and a series of two-dimensional unsteady problems.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No.1, pp. 78–85, January–February, 1993.The authors are grateful to S. V. Kaprantsev for assisting with the experiments.     

On the problem of eversion for incompressible elastic materials

The paper contains a discussion on when eversion of cylindrical tubes and spherical shells is possible. The analysis shows that eversion of a cylindrical tube of every isotropic incompressible elastic material with no applied forces is possible assuming only the E-inequalities. This is not always true for spherical shells. Conditions are given as to when this is possible and when it is not possible.