Sensitive Voltammetric Determination of Captopril Using a Carbon Paste Electrode Modified with Nano-TiO2/Ferrocene Carboxylic Acid

A carbon paste electrode (CPE) modified with ferrocene carboxylic acid (FcCA) and TiO2 nanoparticles was constructed by incorporating TiO2 nanoparticles and ferrocene carboxylic acid into the carbon paste matrix.The electrochemical behavior of captopril (CAP) at the surface of the modified electrode was investigated using electroanalytical methods.The modified electrode showed excellent electrocatalytic activity for the oxidation of CAP in aqueous solutions at physiological pH values.Cyclic voltammetric curves showed that the oxidation of CAP at the surface of the modified electrode reduced its overpotential by more than 290 mV.The modified electrode was used for detecting captopril using cyclic voltammetry and square wave voltammetry techniques.A calibration curve in the range of 0.03 to 2400μmol/L was obtained that had a detection limit of 0.0096 μmol/L (3σ) under the optimized conditions.The modified electrode was successfully used for the determination of captopril in pharmaceutical and biological samples.     

Detection of cancer affected cell using Sagnac interferometer based photonic crystal fiber refractive index sensor

Optical and Quantum Electronics - A complex studies of optoelectronics, non-linear optical and laser stimulated piezoelectric features of chalcogenide powder-like chalcogenide crystals pure and...     

Charmonium decay widths in magnetized matter

The European Physical Journal A - In this paper, we investigated the spectroscopy of heavy tetraquarks through a relativistic diquark-antidiquark model. To this aim, the two-bosonic Klein-Gordon...     

A novel method for the synthesis of tetrahydrobenzo[a]-xanthen-11-one derivatives using cerium(III) chloride as a highly efficient catalyst

Cerium(III) chloride is found to be an highly efficient catalyst for the addition of aldehydes, β-naphthol and cyclic 1,3-dicarbonyl compounds/Meldrum's acid via a multicomponent reaction. The easy availability of starting materials, novel and eco-friendly procedure makes this strategy more useful for the preparation of tetrahydrobenzo[a]-xanthen-11-one, and benzo[f]chromen-3-one derivatives.     

Modulated Dust-Acoustic Wave Packets in an Opposite Polarity Dusty Plasma System

The nonlinear propagation of the dust-acoustic bright and dark envelope solitons in an opposite polarity dusty plasma(OPDP) system(composed of non-extensive q-distributed electrons, iso-thermal ions, and positively as well as negatively charged warm dust) has been theoretically investigated. The reductive perturbation method(which is valid for a small, but finite amplitude limit) is employed to derive the nonlinear Schr¨odinger equation. Two types of modes, namely, fast and slow dust-acoustic(DA) modes, have been observed. The conditions for the modulational instability(MI) and its growth rate in the unstable regime of the DA waves are significantly modified by the effects of non-extensive electrons, dust mass, and temperatures of different plasma species, etc. The implications of the obtained results from our current investigation in space and laboratory OPDP medium are briefly discussed.     

Monomial Ideals of Forest Type

As a generalization of the facet ideal of a forest, we define monomial ideal of forest type and show that monomial ideals of forest type are pretty clean. As a consequence, we show that if I is a monomial ideal of forest type in the polynomial ring S, then Stanley's decomposition conjecture holds for S/I. The other main result of this article shows that a clutter is totally balanced if and only if it has the free vertex property, and which is also equivalent to say that its edge ideal is a monomial ideal of forest type or is generated by an M sequence.     

Electrocatalytically active graphene-porphyrin MOF composite for oxygen reduction reaction

Pyridine-functionalized graphene (reduced graphene oxide) can be used as a building block in the assembly of metal organic framework (MOF). By reacting the pyridine-functionalized graphene with iron-porphyrin, a graphene-metalloporphyrin MOF with enhanced catalytic activity for oxygen reduction reactions (ORR) is synthesized. The structure and electrochemical property of the hybrid MOF are investigated as a function of the weight percentage of the functionalized graphene added to the iron-porphyrin framework. The results show that the addition of pyridine-functionalized graphene changes the crystallization process of iron-porphyrin in the MOF, increases its porosity, and enhances the electrochemical charge transfer rate of iron-porphyrin. The graphene-metalloporphyrin hybrid shows facile 4-electron ORR and can be used as a promising Pt-free cathode in alkaline Direct Methanol Fuel Cell.     

Electrochemical Monitoring of Photoelectrocatalytic Degradation of 3,4‐Dichlorophenol Using TiO2 Thin Film Modified Graphite Electrode

A novel electrode was prepared by forming TiO₂ thin films using a commercially available TiO₂ powder (Degussa P25) on graphite plates for water photoelectrocatalytic decontamination. In addition to, for the first time the photoelectrochemical degradation of 3,4‐dichlorophenol was investigated. The effects of applied potential, pH, and initial 3,4‐dichlorophenol concentration on the photoelectrocatalytic (PEC) degradation of 3,4‐dichlorophenol using ultraviolet (UV) illuminated TiO₂/graphite (TiO₂/C) thin film electrode was examined and discussed. Also, direct photolysis (DP), electrochemical oxidation (EC), photocatalytic (PC) and photoelectrocatalytic (PEC) degradation of 3,4‐dichlorophenol were compared. Results show that the best responses for PEC are obtained at applied potential 1.2 V versus reference electrode, pH 8.0 and initial 3,4‐dichlorophenol concentration 6.7 mg L^?1.     

Nickel/Poly(o‐aminophenol) Film Prepared in Presence of Sodium Dodecyl Sulfate: Application for Electrocatalytic Oxidation of Carbohydrates

Poly(o‐aminophenol) (POAP) was formed by successive cyclic voltammetry in monomer solution in the presence of sodium dodecyl sulfate (SDS) on the surface of a carbon paste electrode (CPE). Ni(II) ions were incorporated into the electrode by immersion of the polymeric modified electrode having amine groups in 0.1 M Ni(II) ion solution. Electrochemical study of this modified electrode shows a good redox behavior of the Ni(III)/Ni(II) couple. The electrocatalytic oxidations of glucose and other carbohydrates at the surface of the Ni/SDS‐POAP/CPE were studied in a 0.1 M NaOH solution. Compared to POAP/CPE, the SDS‐POAP/CPE significantly enhanced the catalytic efficiency of Ni ions for carbohydrates oxidation. Finally, using chronoamperometric method, the catalytic rate constants (k) for carbohydrates were calculated.