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181.
N. I. Kiselev D. A. Velikanov S. B. Korchagina E. A. Petrakovskaya A. D. Vasil’ev L. A. Solov’ev D. A. Balaev O. A. Bayukov I. A. Denisov S. S. Tsegel’nik E. V. Eremin D. A. Znak K. A. Shaikhutdinov A. A. Shubin N. P. Shestakov N. V. Volkov S. K. Gordeev P. I. Belobrov 《Russian Journal of General Chemistry》2013,83(11):2173-2181
The electrical and magnetic properties of the nanodiamond composites comprising nanodiamond, pyrolytic carbon, and nanosized pores were studied. The composites are p-type semiconductors and their resistance decreases by 12 orders of magnitude as the pyrocarbon-to-diamond ratio γ increases from 0 to 80 wt %. Evidence for paramagnetic properties of the nanodiamond composites was obtained. The observed properties are explained by increased concentration of surface Tamm states. The paramagnetic properties are explained in terms of the electron spins localized on the nanodiamond surface in the composite. 相似文献
182.
183.
One-electron oxidation of bis(4-tert-butylphenyl)aminoxyl with antimony pentachloride and bromine leads to the formation of oxoammonium salts with anions SbCl 6 ? and Br 3 ? respectively. The salt with the Br 3 ? anion converted at heating into a mixture of bromodiphenylamines which formed also from the aminoxyl as a result of previously unknown reaction of three-electron reductive bromination. The mechanisms of these reactions were assumed. 相似文献
184.
V. I. Minkin A. D. Dubonosov V. A. Bren’ O. G. Nikolaeva A. V. Tsukanov O. N. Burov A. Yu. Fedyanina 《Russian Journal of Organic Chemistry》2013,49(3):374-378
Schiff bases were synthesized from 3-hydroxy-6-oxo-6H-benzo[c]chromene-4-carbaldehyde, 5-hydroxy-4,7-dimethyl-2-oxo-2H-chromene-6-carbaldehyde, 6,7-dihydroxy-4-methyl-2-oxo-2H-chromene-8-carbaldehyde, 5,7-dihydroxy-4-methyl-2-oxo-2H-chromene-6,8-dicarbaldehyde, and 5-hydroxy-4,7-dimethyl-2-oxo-2H-chromene-6,8-dicarbaldehyde and (15N)aniline or aminobenzo-15-crown-5 (2,3,5,6,8,9,11,12-octahydrobenzo[b][1,4,7,10,13]pentaoxacyclopentadecin-15-amine), and tautomeric equilibrium between the hydroxy enimino and keto enamino forms of the 4- and 8-iminomethyl derivatives in solution was revealed by 1H NMR and electronic spectroscopy. Addition of alkaline earth cations to their solutions in acetonitrile displaced the tautomeric equilibrium toward the hydroxy enimino structure due to complex formation with the crown ether fragment. 相似文献
185.
D. A. Vasilevskii V. G. Petushok G. V. Kalechits R. A. Zheldakova V. K. Ol’khovik 《Russian Journal of General Chemistry》2013,83(9):1698-1702
A series of novel double quaternary ammonium salts based on 5,5-dioxo-5H-dibenzo[b,d]thiophene has been prepared via quaternization of the corresponding 3,7-bis(chloromethyl)dibenzothiophene-5,5-diones with various N,N-dimethylalkylamines. Pronounced fungicidal activity of the C1-substituted quaternary ammonium salts has been observed. 相似文献
186.
I. N. Klochkova A. A. Anis’kov M. P. Shchekina S. V. Chuvaikina K. A. Andreev 《Russian Journal of Organic Chemistry》2013,49(9):1344-1347
Carbocyclization of unsymmetrical 1,5-diarylpenta-1,4-dien-3-ones with thiobarbituric acid afforded previously unknown 7,11-diaryl-3-thioxo-2,4-diazaspiro[5.5]undecane-1,5,9-triones with high regio- and stereoselectivity. The same spiro compounds were also synthesized by three-component condensation of thiobarbituric acid with the corresponding aromatic aldehydes and 4-arylbut-3-en-2-ones. 相似文献
187.
N. N. Makhmudiyarova K. I. Prokof’ev L. V. Mudarisova A. G. Ibragimov U. M. Dzhemilev 《Russian Journal of Organic Chemistry》2013,49(5):658-662
Efficient procedure was developed for 3-hetaryl-1,5,3-dithiazepanes and 3-hetaryl-1,5,3-dithiazocanes preparation from hetarylamines, N,N,N′,N′-tetramethylmethanediamine, and α,ω-alkanedithiols (ethane-1,2-dithiol, propane-1,3-dithiol), and also by the reaction of the latter with N,N-bis(methoxymethyl)hetarylamines in the presence of catalytic quantities of transition metals salts. 相似文献
188.
O. I. Kasian T. V. Luk’yanenko R. Amadelli A. B. Velichenko 《Russian Journal of Electrochemistry》2013,49(6):557-562
The electrochemical behavior of platinized Ebonex® was studied. The electrochemical and semiconductor properties of electrodes can be varied within wide limits by thermal treatment of Ebonex®/Pt, which selectively affects the electrocatalytic activity of anodes in the oxygen evolution reaction. The reduction peak of platinum oxides on the cyclic voltammetry (CV) curves can be used as a correlation parameter when evaluating the electrocatalytic activity of Ebonex®/Pt electrodes in the oxygen evolution reaction. 相似文献
189.
Yu. S. Dzyaz’ko L. N. Ponomareva Yu. M. Vol’fkovich V. E. Sosenkin V. N. Belyakov 《Russian Journal of Electrochemistry》2013,49(3):209-215
The organo-inorganic composites based on a strongly acid gel resin including zirconium hydro-phosphate nanoparticles and their aggregates were studied by impedance spectroscopy, electron microscopy, and standard contact porosimetry. The porous structure of the polymer was transformed under the action of the inorganic filler. The nanoparticles in the transport pores provided a three- to fivefold increase in the electric conductivity of the nanocomposites compared with the conductivity of the nonmodified ionite and a decrease in the percolation threshold. The nanocomposite ionites demonstrated stability against the accumulation of organic substances during electrodeionization to extract Na+ from low-concentrated solutions. 相似文献
190.
M. G. Bugaenko A. L. Rusanov E. G. Bulycheva S. A. Shevelev M. D. Dutov O. V. Serushkina A. V. Pisareva Yu. A. Dobrovol’skii 《Polymer Science Series B》2013,55(7-8):478-483
A new method for the synthesis of sulfonated polynaphthylimides has been developed on the basis of the postsulfonation of high-molecular-mass polynaphthylimides with a sulfuric acid-oleum mixture. Sulfonated polymers of this type have been obtained from the polycondensation products of 5-phenylthiophenylene-1,3-diamine with dianhydrides of 1,4,5,8-naphthalenetetracarboxylic acid and 4,4′-(1,4-phenylenedicarbonyl)-bis-naphthalene-1,8-dicarboxylic acid. It has been shown that hydrogen peroxide oxidation of sulfide bridge groups of these polymers in an acidic medium yields high-molecular-mass compounds that contain sulfonic bridge fragments and, therefore, have increased thermal stabilities and enhanced proton conductivities. 相似文献