全文获取类型
收费全文 | 114篇 |
免费 | 5篇 |
专业分类
化学 | 75篇 |
力学 | 5篇 |
数学 | 8篇 |
物理学 | 31篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 2篇 |
2018年 | 3篇 |
2017年 | 1篇 |
2016年 | 10篇 |
2015年 | 4篇 |
2014年 | 8篇 |
2013年 | 6篇 |
2012年 | 13篇 |
2011年 | 14篇 |
2010年 | 4篇 |
2009年 | 7篇 |
2008年 | 6篇 |
2007年 | 5篇 |
2006年 | 4篇 |
2005年 | 4篇 |
2004年 | 1篇 |
2003年 | 1篇 |
2002年 | 1篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有119条查询结果,搜索用时 328 毫秒
21.
The entanglement of a two-level atom and its radiation field near the edge of a photonic band gap is studied by using the quantum entropy. Unlike the free space case, there is a steady-state entanglement between the atom and its spontaneous emission field even when the atomic transition frequency lies outside the band gap. Moreover, the degree of entanglement, which is due to the formation of atom–photon bound dressed state, depends on the detuning of the atomic transition frequency from the photonic band edge and can be controlled by a controllable photonic band gap crystal. 相似文献
22.
Carla Gasbarri Maurizio Ronci Antonio Aceto Roshan Vasani Gianluca Iezzi Tullio Florio Federica Barbieri Guido Angelini Luca Scotti 《Molecules (Basel, Switzerland)》2021,26(17)
The aim of this work was to deeply investigate the structure and properties of electrochemically synthesized silver nanoparticles (AgNPs) through high-resolution techniques such as transmission electron microscopy (TEM), scanning electron microscopy (SEM), Zeta Potential measurements, and matrix-assisted laser desorption/ionization time of flight mass spectrometry (MALDI-TOF-MS). Strong brightness, tendency to generate nanoclusters containing an odd number of atoms, and absence of the free silver ions in solution were observed. The research also highlighted that the chemical and physical properties of the AgNPs seemed to be related to their peculiar oxidative state as suggested by X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction (XRPD) analyses. Finally, the MTT assay tested the low cytotoxicity of the investigated AgNPs. 相似文献
23.
Optoelectronic Properties,Elastic Moduli and Thermoelectricity of SrAlGa: An Ab Initio Study 下载免费PDF全文
Roshan Ali G. Murtaza Y. Takagiwa R. Khenata Haleem Uddin H. Ullah S. A. Khan 《中国物理快报》2014,(4):134-138
Half-Heusler compounds are an impressive class of materials with a huge potential for different applications such as in future energy, especially in the fields of thermoelectrics and solar cells. We present ab fnitio total energy calculations within the modified Becke-Johnson generalized gradient approximation (mBJ-GGA) to obtain the physical properties of SrAlGa compounds. The structural, elastic, acoustic, electronic, chemical bonding, optical, and thermoelectric properties are calculated and compared with the available calculation data. The SrAlGa is found to be a small-band-gap (0.125-0.175 eV) material, suitable for thermoelectric applications with a relatively high Seebeck coefficient. Also, SrAIGa has the potential in the optoelectronic applications due to high optical conductivity and reflectivity in the infrared and visible region of electromagnetic spectra. 相似文献
24.
25.
Raju B Ramesh M Borkar RM Padiya R Banerjee SK Srinivas R 《Biomedical chromatography : BMC》2012,26(11):1341-1347
A highly sensitive, selective and rapid liquid chromatography–electrospray ionization mass spectrometry (LC‐MS) method has been developed and validated for simultaneous determination of moxifloxacin (MFX) and ketorolac (KTC) in rat plasma. Gemifloxacin (GFX) was used as an internal standard (IS). A simple protein precipitation method was used for the extraction of analytes from rat plasma. Effective chromatographic separation of MFX, KTC and GFX was achieved on a Kromasil C18 column (100 × 4.6 mm, 5 µm) using a mobile phase consisting of acetonitrile–10 mm ammonium acetate (pH 2.5)–0.1% formic acid (50:25:25) in an isocratic elution, followed by detection with positive ion electrospray ionization mass spectrometry using target ions of [M + H]+ at m/z 402 for MFX, m/z 256 for KTC and m/z 390 for GFX in selective ion recording mode. The method was validated over the calibration range of 5–100 ng/mL for MFX and 10–6000 ng/mL for KTC. The method demonstrated good performances in terms of intra‐ and inter‐day precision (0.97–5.33%) and accuracy (93.91–101.58%) for both MFX and KTC, including lower and upper limits of quantification. The recoveries from spiked control samples were >75% for MFX and >79% for KTC. The matrix effect was found to be negligible and the stability data were within acceptable limits. Further, the method was also successfully applied to a single‐dose pharmacokinetic study in rats. This method can be extended to measure plasma concentrations of both drugs in human to understand drug interaction and adverse effects. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
26.
27.
Sadeghinia P. Roshan A. S. Goudarzi P. K. Nikkhoo M. 《Journal of Applied Mechanics and Technical Physics》2022,63(2):231-239
Journal of Applied Mechanics and Technical Physics - This study is aimed at designing, optimizing, and validating a posterior lumbar interbody cage (PLIF) model based on the 3D printing method,... 相似文献
28.
A simple procedure has been used for preparation of modified glassy carbon electrode with carbon nanotubes and copper complex. Copper complex [Cu(bpy)2]Br2 was immobilized onto glassy carbon (GC) electrode modified with silicomolybdate, α-SiMo12O404− and single walled carbon nanotubes (SWCNTs). Copper complex and silicomolybdate irreversibly and strongly adsorbed onto GC electrode modified with CNTs. Electrostatic interactions between polyoxometalates (POMs) anions and Cu-complex, cations mentioned as an effective method for fabrication of three-dimensional structures. The modified electrode shows three reversible redox couples for polyoxometalate and one redox couple for Cu-complex at wide range of pH values. The electrochemical behavior, stability and electron transfer kinetics of the adsorbed redox couples were investigated using cyclic voltammetry. Due to electrostatic interaction, copper complex immobilized onto GC/CNTs/α-SiMo12O404− electrode shows more stable voltammetric response compared to GC/CNTs/Cu-complex modified electrode. In comparison to GC/CNTs/Cu-complex the GC/CNTs/α-SiMo12O404− modified electrodes shows excellent electrocatalytic activity toward reduction H2O2 and BrO3− at more reduced overpotential. The catalytic rate constants for catalytic reduction hydrogen peroxide and bromate were 4.5(±0.2) × 103 M−1 s−1 and 3.0(±0.10) × 103 M−1 s−1, respectively. The hydrodynamic amperommetry technique at 0.08 V was used for detection of nanomolar concentration of hydrogen peroxide and bromate. Detection limit, sensitivity and linear concentration range proposed sensor for bromate and hydrogen peroxide detection were 1.1 nM and 6.7 nA nM−1, 10 nM-20 μM, 1 nM, 5.5 nA nM−1 and 10 nM-18 μM, respectively. 相似文献
29.
Kim SH Perera R Hager LP Dawson JH Hoffman BM 《Journal of the American Chemical Society》2006,128(17):5598-5599
The classical heme-monooxygenase active intermediate, compound I (Cpd-I), incorporates a heme which is oxidized by two equivalents above the resting ferric state, one equivalent associated with a ferryl center, [Fe=O]2+ (FeS = 1), and the other with an active-site radical (RS = 1/2). Theoretical calculations on models of a Cpd-I with a thiolato axial ligand have presented divergent views about its electronic structure. In one picture, the radical is on the porphyrin; in the other, it is on the sulfur. In this report, ENDOR spectroscopy answers the question, does Cpd-I of the enzyme chloroperoxidase contain a porphyrin pi-cation radical or an iron-bound cysteinyl radical: the radical is predominantly on the porphyrin, with spin density on sulfur having an upper bound, rhoS = rhoSmax approximately 0.23. We further suggest that the same answer applies to Cpd-I of cytochromes P450. 相似文献
30.
We consider scalar–tensor theory for describing varying speed of light in a spatially flat FRW space–time. We find some exact solutions in the metric and Palatini formalisms. Also we examine the dynamics of this theory by dynamical system method assuming a ΛCDM background and we find some exact solutions by considering the character of critical points of the theory in both formalisms. We show that for any attractor the form of non-minimal coupling coefficient is quadratic in terms of the scalar field Ψ. Also we show that only attractors of the de Sitter era satisfy the horizon criteria. 相似文献