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131.
M. Adamus N. M. Agababyan I. V. Ajinenko Yu. A. Belokopytov H. Bia?kowska H. B?ttcher P. V. Chliapnikov F. Crijns A. De Roeck E. A. De Wolf K. Dziunikowska A. M. F. Endler W. Friebel H. Graessler P. van Hal J. K. Karamyan D. Kisielewska W. Kittel A. I. Kurnosenko B. B. Levchenko F. Meijers M. Merk A. B. Micha?owska V. I. Nikolaenko L. C. S. Oliveira K. Olkiewicz V. M. Ronjin A. M. Rybin H. M. T. Saarikko Y. T. M. Saarikko W. Schmitz L. Scholten N. A. Sotnikova J. Stepaniak O. G. Tchikilev L. A. Tikhonova V. A. Uvarov F. Verbeure R. Wischnewski EHS/NA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1988,37(2):215-229
The charged particle multiplicity distribution has been studied for non-single-diffractive π+ p andpp collisions at \(\sqrt s = 22\) GeV, for full phase space as well as for intervals in rapidity, azimuthal angle and transverse momentum. In general, the multiplicity distribution is well described by a negative binomial. From comparison of the distribution for negative or positive particles to that of all charged particles, cascading is favoured as an interpretation over stimulated emission. Interesting consequences follow from a comparison of our results to those at collider energies and toe + e ? data at comparable energy. Furthermore, evidence is given that the multiplicity distribution is not exactly of negative binomial type in every (connected or disconnected) phase space region. 相似文献
132.
Sahadev R. K. Sharma S. K. Sindhwani 《Monatshefte für Chemie / Chemical Monthly》1992,123(10):883-889
Summary The chelation behaviour of some trivalent lanthanide and yttrium metal ion with biologically active 2-hydroxy-1-naphthaldehyde thiosemicarbazone (HNATS) has been investigated by potentiomotric measurements at 20±0.5°C in 75% (v/v) dioxane-water medium at various ionic strengths of sodium perchlorate. The method of Bjerrum and Calvin, as modified by Irving and Rossotti has been used to find out the values of
(average number of ligand bound per metal ion) andpL (free ligand exponent). The formation constants of metal chelates have been computed on a PC-XT computer, using a program patterned after that of Sullivan et al. to give
n
values using weighted least squares method. TheS
min
values (S
min
=2) have been calculated. The order of formation constants of chelates was found to be: La3+3+3+3+3+3+3+3+3+3+. The formation constants of the chelates formed have been correlated to size and ionization potentials of the metal ions.
Potentiometrische Untersuchungen der Komplexierungsgleichgewichte zwischen einigen trivalenten Metallionen und biologisch aktivem 2-Hydroxy-1-naphthaldehyd-thiosemicarbazon (HNATS)
Zusammenfassung Es wurde das Chelierungsverhalten einiger trivalenter Lanthanidenionen mit biologisch aktivem 2-Hydroxy-1-naphthaldehyd-thiosemicarbazon (HNATS) mittels potentiometrischer Messungen bei 20±0.5°C in 75% (v/v) Dioxan-Wasser bei verschiedener Ionenstärke an Natriumperchlorat untersucht. Die Methode nach Bjerrum und Calvin in der Modifikation nach Irving und Rossotti wurde zur Ermittlung der Werte (mittlere Anzahl an Liganden pro Metallion) undpL (Exponent an freiem Liganden) verwendet. Die Komplexbildungskonstanten wurden in Anlehnung an Sullivan et al. an einem PC-XT Computer errechnet. DieS min-Werte (S min=2) wurden ebenfalls bestimmt. Die Reihung der Chelatbildungskonstanten war: La3+相似文献3+ 3+ 3+ 3+ 3+ 3+ 3+ 3+ 3+. Die Bildungskonstanten sind mit der Größe und dem Ionisierungspotential der Metallionen zu korrelieren.
133.
R. Bacaud M. Besson D. Brodzki P. Bussière H. Charcosset G. Diega-Mariadassou M. Oberson B. K. Sharma 《Hyperfine Interactions》1989,46(1-4):583-589
Mössbauer Spectroscopy, X-Ray Diffraction and Electron Microscopy were applied to the study of solid residues of coal hydroliquefaction, for which tin-based catalysts were used. In the general case hydroliquefaction runs were performed in the presence of added sulphur and of finely dispersed SnO2 as a catalyst precursor. The only observed tin species were SnO2 and SnS, the former with percentages higher than expected from XRD, due to its large f factor, the latter as a symmetric doublet, which suggests that any asymmetry should be ascribed to small particle sizes rather than to structure. When the S content was only that of coal and the catalyst precursor β-Sn, FeSn2 occurred together with Sn sulfides and oxides, while no β-Sn was detected. The main catalytic role is ascribed to SnS. 相似文献
134.
V. V. Aivazyan I. V. Ajinenko Yu. A. Belokopytov P. C. Bosetti H. B?ttcher F. Botterweck P. V. Chliapnikov F. Crijns A. De Roeck E. A. De Wolf Th. Driever K. Dziunikowska A. Eskreys W. Friebel Z. C. Garutchava V. G. Gavrjusev H. Graessler P. van Hal T. Haupt W. Kittel S. S. Megrabyan F. Meijers A. B. Micha?owska V. I. Nikolaenko L. C. S. Oliveira K. Olkiewicz L. P. Petrovikh E. Riipinen V. M. Ronjin A. M. Rybin H. M. T. Saarikko W. Schmitz L. Scholten R. Schulte O. G. Tchikilev L. A. Tikhonova A. G. Tomaradze V. A. Uvarov F. Verbeure R. Wischnewski A. Wróblewski S. A. Zotkin NA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1989,42(4):533-542
Forward-backward multiplicity correlations in σ+,K + p andpp collisions at 250 GeV/c ( \(\sqrt s \) =22 GeV) are given for all charges and for the different charge combinations. The correlations are found to be caused predominantly by centrally produced particles. It is demonstrated that this result is an agreement with observations at the ISR and the CERNp \(\bar p\) -Collider. The results are compared to expectations from LUND, DPM and FRITIOF Monte Carlo models and a geometrical picture relating correlations in hadron-hadron collisions toe + e ? data in terms of impact parameters is tested. 相似文献
135.
Allan H. S?rensen 《Few-Body Systems》1989,6(3):N38-N38
Few-Body Systems — News Section
New books 相似文献136.
Bortoletto D Goldberg M Horwitz N Mestayer MD Moneti GC Sharma V Shipsey IP Skwarnicki T Csorna SE Letson T Brock IC Ferguson T Artuso M Bebek C Berkelman K Blucher E Byrd J Cassel DG Cheu E Coffman DM Crawford G DeSalvo R DeWire JW Drell PS Ehrlich R Galik RS Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Kandaswamy J Kowalewski R Kreinick DL Kubota Y Lewis JD Mistry NB Mueller J Namjoshi R Nandi S Nordberg E O'Grady C Peterson D Pisharody M Riley D Sapper M Silverman A Stone S Worden H 《Physical review letters》1989,62(21):2436-2439
137.
Alam MS Katayama N Kim IJ Li WC Lou XC Sun CR Bortoletto D Goldberg M Horwitz N Mestayer MD Moneti GC Sharma V Shipsey IP Skwarnicki T Csorna SE Letson T Brock IC Ferguson T Artuso M Bebek C Berkelman K Blucher E Byrd J Cassel DG Cheu E Coffman DM Crawford G DeSalvo R DeWire JW Drell PS Ehrlich R Galik RS Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Kandaswamy J Kowalewski R Kreinick DL Kubota Y Lewis JD Mistry NB Mueller J Namjoshi R Nandi S Nordberg E O'Grady C Peterson D Pisharody M 《Physical review D: Particles and fields》1989,40(11):3790
138.
A rapid, selective, sensitive and simple fluorescence method was developed for the direct determination of celecoxib in capsules. The capsules were emptied, pulverized and dissolved in either ethanol or acetonitrile, sonicated and filtered. Direct fluorescence emission was measured at 355±5 nm (exciting at 272 nm). The method was fully validated and the recoveries were excellent, even in presence of excipients. 相似文献
139.
Zeta potential studies show that the ATO nanoparticle surface is positively charged in pH range from 2 to 5 without oxalic acid. The addition of oxalic acid brings a charge reversal on the surface of ATO particle in a wide pH range. The interaction of oxalic acid with surface of ATO nanoparticle was studied by FTIR and indicates that the most probable mechanism is the formation of Sn-O-C bonds via the condensation reaction between the oxalic acid and surface hydroxyl groups. TEM, X-ray diffraction and UV-Vis-Near IR spectra were used to characterize the nanocrystalline ATO sol and thin gel film. 相似文献
140.
Kameo S Nakai K Kurokawa N Kanehisa T Naganuma A Satoh H 《Analytical and bioanalytical chemistry》2005,381(8):1514-1519
Mercury vapor is effectively absorbed via inhalation and easily passes through the blood–brain barrier; therefore, mercury poisoning with primarily central nervous system symptoms occurs. Metallothionein (MT) is a cysteine-rich metal-binding protein and plays a protective role in heavy-metal poisoning and it is associated with the metabolism of trace elements. Two MT isoforms, MT-I and MT-II, are expressed coordinately in all mammalian tissues, whereas MT-III is a brain-specific member of the MT family. MT-III binds zinc and copper physiologically and is seemed to have important neurophysiological and neuromodulatory functions. The MT functions and metal components of MTs in the brain after mercury vapor exposure are of much interest; however, until now they have not been fully examined. In this study, the influences of the lack of MT-I and MT-II on mercury accumulation in the brain and the changes of zinc and copper concentrations and metal components of MTs were examined after mercury vapor exposure by using MT-I, II null mice and 129/Sv (wild-type) mice as experimental animals. MT-I, II null mice and wild-type mice were exposed to mercury vapor or an air stream for 2 h and were killed 24 h later. The brain was dissected into the cerebral cortex, the cerebellum, and the hippocampus. The concentrations of mercury in each brain section were determined by cold vapor atomic absorption spectrometry. The concentrations of mercury, copper, and zinc in each brain section were determined by inductively coupled plasma mass spectrometry (ICP-MS). The mercury accumulated in brains after mercury vapor exposure for MT-I, II null mice and wild-type mice. The mercury levels of MT-I, II null mice in each brain section were significantly higher than those of wild-type mice after mercury vapor exposure. A significant change of zinc concentrations with the following mercury vapor exposure for MT-I, II null mice was observed only in the cerebellum analyzed by two-way analysis of variance. As for zinc, the copper concentrations only changed significantly in the cerebellum. Metal components of metal-binding proteins of soluble fractions in the brain sections were analyzed by size-exclusion high-performance liquid chromatography (HPLC) connected with ICP-MS. From the results of HPLC/ICP-MS analyses, it was concluded that the mercury components of MT-III and high molecular weight metal-binding proteins in the cerebellum of MT-I, II null mice were much higher than those of wild-type mice. It was suggested that MT-III is associated with the storage of mercury in conditions lacking MT-I, and MT-II. It was also suggested that the physiological role of MT-III and some kind of high molecular weight proteins might be impaired by exposure to mercury vapor and lack of MT-I and MT-II. 相似文献