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61.
The Mössbauer spectrum of ferrous zirconium double sulphate FeZrO(SO4)2·8H2O shows a quadrupole split doublet at room temperature. The results are discussed in terms of high-spin Fe(II) in distorted octahedral symmetry.  相似文献   
62.
The reactions of bis(cyclopentadienyl)titanium(IV)/zirconium(IV) dichloride with a new class of organometallic thiosemicarbazones (LH), derived by condensing acetylferrocene with substituted thiosemicarbazides, have been studied and two types of bimetallic products, viz. [Cp2M(L)Cl] (M = Ti or Zr) and [CpZr(L)3], have been isolated. On the basis of various physicochemical and spectral studies, five- and seven-coordinate structures have been assigned to these derivatives, respectively. Attempts have been made to establish a correlation between biological activity and the structures of the products.  相似文献   
63.
Summary The kinetics of iridium(III)-catalysed oxidation of 1,2-ethanediol and 1,4-butanediol by N-bromoacetamide (NBA) in HClO4 in the presence of [Hg(OAc)2] as a scavenger for Br have been investigated. The reactions are zero-order with respect to both diols, and first-order in NBA at low NBA concentrations, tending to zero order at high concentrations. The order in IrIII decreases from unity to zero at high iridium(III) concentrations. A positive effect on the oxidation rate is observed for [H+] and [HgII] whereas a negative effect is observed for acetamide and [Cl]. Ionic strength does not influence the oxidation rate. (H2OBr)+ is postulated as the oxidizing species. A mechanism consistent with the observed kinetic data is proposed.  相似文献   
64.
Summary The coagulation concentration for a titania sol decreases if the concentration of a mixture of electrolytes and papain decreases. If the concentration of papain is increased then lesser amount of electrolytes is needed to coagulate the sol. If glycine is added as an additional substance then the value decreases more rapidly. There is no significant change in the pH and the electrical conductance of the sol by the addition of papain or electrolytes. There is a little change, when glycine is added as an additional substance. These observations are explained due to the formation of negative papain ions in a low pH region. The possibility of the adsorption or the release of the counter ions is ruled out.The authors wish to thank Dr.R. C. Mehrotra, Professor and the Head of the Chemistry Department for providing all the facilities for this work. We are also thankful to the Ministry of Education, Government of India, for the award of a research scholarship to one of us (V.K.S.).  相似文献   
65.
The new water-soluble photosensitizer 5,10,15,20-tetrakis[3,4-bis(carboxymethyleneoxy)phenyl]chlorin (T3,4BCPC) has been prepared, characterized and labeled with 99mTc radionuclide. The radiotracer was evaluated for tissue distribution in Wistar rats. Accumulation of administrated activities in the liver, kidney, bladder and large intestine at 4 h post-injection indicated that the labeled ligand was largely eliminated through the renal and partly through the hepatobiliary system. In vivo biodistribution studies of the labeled compound were carried out in rodent and murine tumor models in comparison with other tumor-seeking radiopharmaceuticals such as 99mTc(V)-dimercaptosuccinic acid (DMSA), 201thallous chloride (TlCl) and 99mTc-citrate using a gamma camera computer system. In N-nitrosomethylurea (NMU)-induced rat mammary tumors, the labeled ligand showed a five-fold tumor to muscle (T/M) ratio compared to 99mTc(V)-DMSA (3-fold) and 201TlCl (3-fold). In the case of C(3)H/J virus-induced spontaneous mammary tumors, the differences were not marked. However, in the transplanted rat C(6)-glioma, the T/M ratio of the labeled compound was appreciably higher (four-fold) than that noted with 99mTc(V)-DMSA (two-fold), 201TlCl (three-fold) and 99mTc-citrate (more than three-fold). These findings suggest that the radiolabeled T3,4BCPC may have potential for the detection of cancer. In order to ascertain the efficacy of the compound for photodynamic therapy applications, a preclinical PDT study was carried out in fibrosarcoma-bearing mice after injecting 5.0 mg/kg body weight of the T3,4BCPC. A laser dose of 20 mW for 60 s resulted in 80% destruction of tumors. These data suggest that this molecule could be useful for PDT of cancer. The labeled agent could also be useful in monitoring the progression/regression of tumors before, during, and after chemotherapy, radiation therapy or PDT.  相似文献   
66.
Recognizing the potential of combinatorial chemistry to accelerate drug discovery and development, most pharmaceutical and related industries are seriously looking toward combinatorial synthesis of compounds in order to facilitate the identification of 'lead' molecules. In particular, solid phase synthesis is the core technology for combinatorial chemistry and is widely used for generating libraries of structurally related compounds. Since many drugs contain the nitrogen heterocyclic component and since heterocycles possess a high order of structural diversity, a precise overview of recent progress in the combinatorial synthesis of nitrogen heterocycles using solid phase methodology would be useful. Since the progress in solid phase synthesis of organic molecules has been reviewed regularly from 1992 to 1998, only the development of solid phase combinatorial synthetic approaches of small nitrogen heterocycles since 1999 will be reviewed here. This review describes the solid phase synthesis of azepanes, benzodiazepines, benzimidazoles, benzothiazepines, cinnolines, indolizines, beta lactams, oxazepins, oxazoles including benzisooxazoles, hydantoins, piperidines, pyrimidines, pyrazolones, quinolones, trizolopyridazines and thiazoles.  相似文献   
67.
Summary Electroosmosis of acetone, water and their binary mixtures through thorium oxide (ThO2) plug membrane has been studied and the data analysed using non-equilibrium thermodynamics. The phenomenological coefficients,L 11 andL 12 have been found to vary nonlinearly with composition. Excess phenomenological coefficients have therefore been evaluated and the results explained in terms of the membrane permeant and permeant-permeant interactions. The results on the measurement of electrophoretic velocity of ThO2 particles dispersed in acetone-water mixtures also lead to the conclusion that the components of the mixture interact appreciably.
Zusammenfassung Die Elektroosmose von Aceton, Wasser and deren binären Gemische durch eine ThO2-Pflock-Membran wurde untersucht; die Daten wurden mit Hilfe der Nichtgleich-gewichts-Thermodynamik analysiert. Die phänomenologischen KoeffizientenL 11 undL 12 ändern sich hiernach nichtlinear mit der Zusammensetzung. Es wurden daher Exzess-L 11-und -L 12-Werte berechnet; die Ergebnisse wurden auf Grund der Membran-Permeant- und Permeant-Permeant-Wechselwirkungen diskutiert. Aus der Messung der elektrophoretischen Geschwindigkeit von ThO2-Teilchen, die in Aceton-Wasser-Gemischen dispergiert sind, folgt, daß eine merkliche Wechselwirkung zwischen den Komponenten der Mischung vorliegt.


With 8 figures and 1 table  相似文献   
68.
Summary A relatively simple procedure for the isolation and determination of the prostaglandins present in human seminal fluid is described. It involves preliminary chromatographic purification of these compounds from the major non-prostaglandin impurities followed by their total elution in one solvent (one-step elution). The prostaglandins thus obtained were almost free from other lipids and were further resolved into prostaglandin-groups and individual prostaglandins by repeated thin-layer chromatography. Data are also presented for prostaglandin contents of fresh semen samples from five individuals and results compared with those from the stored samples.
Einfaches Verfahren zur chromatographischen Isolierung und Bestimmung von Prostaglandinen aus menschlichem Sperma
Zusammenfassung Das Verfahren umfaßt eine chromatographische Abtrennung der Verbindungen von den hauptsächlichsten Verunreinigungen und die Gesamtelution mit einem Lösungsmittel. Die von anderen Lipiden fast völlig freien Prostaglandine werden durch wiederholte Dünnschicht-Chromatographie in Gruppen und Einzelverbindungen getrennt. Werte werden angegeben über die Prostaglandingehalte von frischem im Vergleich zu gelagertem Sperma.
  相似文献   
69.
Development of simple and reliable protocols for the synthesis of organically soluble catalytically active metal nanoparticles is an important aspect of research in nanomaterials. We demonstrate herein the formation of Pd nanoparticles by reduction of aqueous Pd(NO(3))(2) by photoexcited Keggin ions (phosphotungstate anions). This results in the formation of Pd nanoparticles capped with with Keggin ions that render the particles negatively charged. The Keggin ion capped Pd nanoparticles may then be phase transferred into nonpolar organic solvents such as toluene by electrostatic complexation with cationic surfactants such as octadecylamine at the liquid-liquid interface. This results in a new class of catalyst wherein both the Pd core and Keggin ion shell may be used in a range of catalytic reactions leading to a truly multifunctional catalyst dispersible in organic solvents.  相似文献   
70.
67Ga is produced by the66Zn(d,n) reaction at 9 MeV bombarding energy. Deuterons of about 30 A obtained from the T-11 Tandem accelerator are used to bombard targets of natural Zinc prepared by electroplating onto thick copper disks. Radiochemical separation of gallium is performed by using a cation exchange column. The optimum conditions for an efficient separation are given in detail.  相似文献   
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