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991.
This paper presents a model for improving utilization in IEEE 802.11e wireless LAN via a Markov decision process (MDP) approach. A Markov chain tracking the utilized transmission window for two separate access mechanisms is devised. Subsequently, the action space and the rewards of the MDP are judiciously selected with the aim of improving overall utilization without explicit blocking. The proposed MDP model for 802.11e reveals that proportional allocation of access opportunities improve overall utilization compared to completely randomized access. Simulation results go on to show that a policy that limits HCCA access as a function of channel load improves utilization by an average 8 %. The optimization framework proposed in this paper is promising as a practical decision support tool for resource planning in 802.11e. 相似文献
992.
Salim F. Haddad Roger D. Willett Brendan Twamley 《Journal of chemical crystallography》2010,40(11):902-908
Abstract
An analysis is made of the supramolecular interactions in the two polymorphic structures of 3,5-dibromo-2,6-diaminopyridinium bromide, with particular emphasis on the roles of hydrogen and halogen bonding. Because of the extensive hydrogen bonding capabilities, hydrogen bonding interactions dominate in both phases. This causes a competition between C–Br···Br–C and C–Br···Br− halogen bonding interactions, with the former dominating in the orthorhombic Pbca phase and the latter in the monoclinic P21/c phase. For Pbca phase a = 5.5197(11) ?, b = 15.040(3) ?, c = 23.2555(5) ?, and for P21/c phase a = 8.1143(19) ?, b = 14.226(3) ?, c = 8.9005(18) ?, β = 113.18(2)°. 相似文献993.
Reactions of cuprous chloride with the phosphorus–nitrogen cage ligand 2,4,6,8,9,10-hexamethyl-2,4,6,8,9,10-hexaaza-1,3,5,7-tetraphosphaadamantane, P4(NCH3)6, in acetonitrile form distinct solids depending on the ligand-to-metal ratio. Three structurally characterized compounds include: a solvated 3-D network of formula [P4(NCH3)6]2(CuCl)3(CH3CN)2; a “ladder-type” polymer {[μ2-P4(NCH3)6]2(CuCl)2}∞; and a monomeric complex [P4(NCH3)6]2CuCl. Thermal decomposition of the solvated network results in formation of two more materials [P4(NCH3)6]2(CuCl)3, and [P4(NCH3)6](CuCl)2 that are not isolated from solution reactions. The variety of products isolated based solely on ligand-to-metal ratio suggest that this system participates in solution equilibria common to many phosphorus(III) ligands and multiple solubility equilibria. 相似文献
994.
The lichen species Xanthoparmelia chlorochroa is toxic when consumed by domestic sheep, cattle, and Rocky Mountain elk. Clinical signs exhibited by poisoned animals include red urine, ataxia, and muscular weakness that rapidly progresses to recumbency. Elk are unable to recover once becoming recumbent; however, most affected cattle can recover if offered suitable feed shortly following the onset of signs. At present, the pathogenesis and specific toxin(s) are unknown. As part of an effort to elucidate the proximate toxin, a method using ultra-performance LC coupled to MS/MS with negative-ion electrospray ionization has been developed to compare salazinic, norstictic, and usnic acid concentrations in X. chlorochroa collected from locales associated with lichen poisonings. Compounds were extracted from lichen samples with acetone and sonication. The stationary phase was a Waters Acquity UPLCTM BEH Ca18 (50 x 2.1 mm; 1.7 microm particle size) column. The mobile phase consisted of an acetonitrile-water gradient. The precision of the method was confirmed by an SD below 0.4% (n=9) for triplicate samples. LOD values were 200, 100, and 50 ng/mL for salazinic, norstictic, and usnic acids, respectively. 相似文献
995.
Hans Andersson Magnus Gustafsson Dr. Dan Boström Dr. Roger Olsson Prof. Fredrik Almqvist Prof. 《Angewandte Chemie (International ed. in English)》2009,48(18):3288-3291
Reactivity N? Own : Pyridine N‐oxides can be used for the complete regio‐ and stereoselective synthesis of trans‐substituted piperidines. The sequential addition of Grignard reagents and aldehydes or ketones to pyridine N‐oxides yields a complete regio‐ and stereoselective trans 2,3‐addition reaction in high yields, and the substituted 2,3‐dihydropyridine N‐oxide can be reduced to form 2,3‐trans‐substituted piperidines (see scheme).
996.
We consider normalizers of an infinite index irreducible inclusion N⊆M of II1 factors. Unlike the finite index setting, an inclusion uNu∗⊆N can be strict, forcing us to also investigate the semigroup of one-sided normalizers. We relate these one-sided normalizers of N in M to projections in the basic construction and show that every trace one projection in the relative commutant N′∩〈M,eN〉 is of the form u∗eNu for some unitary u∈M with uNu∗⊆N generalizing the finite index situation considered by Pimsner and Popa. We use this to show that each normalizer of a tensor product of irreducible subfactors is a tensor product of normalizers modulo a unitary. We also examine normalizers of infinite index irreducible subfactors arising from subgroup-group inclusions H⊆G. Here the one-sided normalizers arise from appropriate group elements modulo a unitary from L(H). We are also able to identify the finite trace L(H)-bimodules in ?2(G) as double cosets which are also finite unions of left cosets. 相似文献
997.
The interaction between capillary fluid films and micro-structural rough surfaces is one of the main challenges in studying self-cleaning mechanisms. The surface behavior of the deformable fluid film is governed by the Young-Laplace equation, which is highly non-linear. Therefore, a numerical solution is introduced using the finite element method, based on a continuum mechanical formulation. Surface and line contact at the fluid-structure interface are modeled by enforcing a contact constraint, and a contact angle, respectively. The numerical solution is validated against the analytical solution of a test case. (© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
998.
High-resolution infrared laser spectroscopy has been used to obtain rotationally resolved spectra of HCN-Zn(n) (n = 1-4) complexes formed in helium nanodroplets. In the present study the droplets passed through a metal oven, where the zinc vapor pressure was adjusted until one or more atoms were captured by the droplets. A second pickup cell was then used to dope the droplets with a single HCN molecule. Rotationally resolved infrared spectra are obtained for all of these complexes, providing valuable information concerning their structures. Stark spectra are reported and used to determine the corresponding permanent electric dipole moments. Ab initio calculations are also reported for these complexes for comparison with the experimental results. 相似文献
999.
The structures, C-H stretching frequencies, and dipole moments of HCN-Cun (n = 1-3) clusters are determined through high-resolution infrared spectroscopy. The complexes are formed and probed within superfluid helium droplets, whereby the helium droplet beam is passed over a resistively heated crucible containing copper shot and then through a gas HCN pickup cell. All complexes are found to be bound to the nitrogen end of the HCN molecule and on the "atop site" of the copper cluster. Through the experimental C-H vibrational shifts of HCN-Cun and ab initio calculations, it was found that the HCN-metal interaction changes from a strong van der Waals bond in n = 1 to a partially covalent bond in HCN-Cu3. Comparisons with existing infrared data on copper surfaces show that the HCN-Cun bond must begin to weaken at very large copper cluster sizes, eventually returning to a van der Waals bond in the bulk copper surface case. 相似文献
1000.