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61.
Proteomic analysis of the Arabidopsis thaliana cell wall   总被引:1,自引:0,他引:1  
With the completion of the Arabidopsis genome, many hypothetical proteins have been predicted without any information on their expression, subcellular localisation and function. We have performed proteomic analysis of proteins sequentially extracted from enriched Arabidopsis cell wall fractions and separated by two-dimensional gel electrophoresis (2-DE). The proteins were identified by peptide mass fingerprinting using matrix-assisted laser desorption/ionisation-time of flight (MALDI-TOF) mass spectrometry and genomic database searches. This is part of a targeted exercise to establish the entire Arabidopsis secretome database. We report evidence for new proteins of unknown function whose existence had been predicted from genomic sequences and, furthermore, localise them to the cell wall. In addition, we observed an unexpected presence in the cell wall preparations of proteins whose known biochemical activity has never been associated with this compartment hitherto. We discuss the implications of these findings and present results suggesting a possible involvement of cell wall kinases in plant responses to pathogen attack.  相似文献   
62.
Rydberg transitions for the interhalogen ICI, are reported in the wavelength region 160-130 nm.  相似文献   
63.
We have prepared two new C3-symmetric, substituted-triazatruxene molecules using a facile one-pot trimerisation of 5-carboxyindole and 6-bromoindole in acetic acid using Br2, giving 2a and 3a, respectively. These were subsequently modified by the addition of six alkyl chains to the N- and carboxyl-positions of 2a giving 2b and three alkyl chains to the N-positions of 3a giving 3b. The new molecules were characterised using cyclic voltammetry, UV/vis and emission spectroscopy, DFT calculations and in the case of 3b, field-effect transistor measurements showing gate-modulated source-drain current. These represent a straightforward route to large polyaromatic molecules with easily-modified side groups and are suitable as building blocks for synthesis of functional molecules for materials.  相似文献   
64.
Perfluoroalkytin compounds R(4−n)Sn(Rf)n (R = Me, Et, Bu, Rf = C4F9, n = 1; R = Bu, Rf = C4F9, n = 2, 3; R = Bu, Rf = C6F13, n = 1) have been synthesized, characterized by 1H, 13C, 19F and 119Sn NMR, and evaluated as precursors for the atmospheric pressure chemical vapour deposition of fluorine‐doped SnO2 thin films. All precursors were sufficiently volatile in the range 84–136 °C and glass substrate temperatures of ca 550 °C to yield high‐quality films with ca 0.79–2.02% fluorine incorporation, save for Bu3SnC6F13, which incorporated <0.05% fluorine. Films were characterized by X‐ray diffraction, scanning electron microscopy, thickness, haze, emissivity, and sheet resistance. The fastest growth rates and highest quality films were obtained from Et3SnC4F9. An electron diffraction study of Me3SnC4F9 revealed four conformations, of which only the two of lowest abundance showed close F Sn contacts that could plausibly be associated with halogen transfer to tin, and in each case it was fluorine attached to either the γ‐ or δ‐carbon atoms of the Rf chain. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
65.
Theoretical and experimental values have been determined for the pressure broadening of the ν1 + ν3 band of acetylene by hydrogen and deuterium at 195 K, and experimental values of the pressure shifts have been determined. Theoretical values have been calculated on the basis of a recent potential energy surface using the close coupling scheme. We discuss the detailed contribution of the various rotational angular momenta of the perturbing gas and the ortho and para contribution to the total pressure broadening cross-sections. We give routes to circumvent the computational cost of such calculations. Experimental values have been measured using a tunable diode laser spectrometer assuming a Voigt line shape. These pressure broadening parameters are compared with measurements performed recently at room temperature and with present measurements performed at 195 K in the ν1 + ν3 band of acetylene. A satisfactory agreement is obtained with the present results and available ones at 295 K.  相似文献   
66.
Band gaps and defect modes in periodically structured waveguides   总被引:2,自引:0,他引:2  
This work examines a simple one-dimensional acoustic band gap system made from a diameter-modulated waveguide. Experimental and theoretical results are presented on perfectly periodic waveguide arrays showing the presence of band gaps--frequency intervals in which the transmission of sound is forbidden. The introduction of defects in the perfect periodicity leads to narrow frequency transmission bands--defect states--within the forbidden band gaps. The circular cross-section waveguide system is straightforward to simulate theoretically and experimental results demonstrate good agreement with theory. The experimental transmission of the periodic waveguide arrays is measured using an impulse response technique.  相似文献   
67.
A new example of magnetic nonequivalence of chemically equivalent atoms is identified from the proton and carbon resonance spectra of 9,10-di(9,9-dioctylfluorenyl)anthracene with the aid of its conformation in the crystalline state. Molecular modeling suggests that it has a similar conformation in solution.  相似文献   
68.
Extracts of the marine sponge Caminus sphaeroconia showed potent activity in a screen for bacterial type III secretion inhibitors. Bioassay guided fractionation of the extract led to the isolation of the novel antimicrobial glycolipid caminoside A (1). The structure of caminoside A was elucidated by analysis of spectroscopic data and chemical degradation.[structure: see text]  相似文献   
69.
To learn more about the out-of-plane deformation of polymer lamellae during drawing, we have measured the resistance to shear along various planes in uniaxially oriented polyethylene and polypropylene. Fissures parallel to the orientation axis in oriented materials always cause too small an experimental value for the resistance of crystal glide parallel to the chain axes, but a rough estimate for the resistance to crystal glide is obtained using the elastic anisotropy. Also, the results suggest that kinking can be easier than glide when glide is inhibited by tie molecules.  相似文献   
70.
Appropriate selection of subjects is a critical element in assuring a valid evaluation of the clinical usefulness of a laboratory test. Careful definition of the clinical question to be answered by the test clearly points to the target population from which a representative sample must be obtained.  相似文献   
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