Langmuir-Blodgett self-assembly and electrochemical catalytic property of FePt magnetic nano-monolayer

Dispersed-well FePt nanoparticles with particle size ~5 nm have been prepared by hydrazine hydrate reduction of H₂PtCl₆·6H₂O and FeCl₂·4H₂O in ethanol–water system. By employing as-synthesized FePt nanoparticles, the monolayer can be formed by LB Technique. The structural, magnetic properties and electrochemical properties of FePt monolayer were respectively studied by XRD, TEM, VSM and CHI 820 electrochemical workstation. The as-synthesized particle has a chemically disordered fcc structure and can be transformed into chemically ordered fct structure after annealing treatment above 400°C. The coercivity of ordered fct FePt phase can be up to 2515Oe. CVs of 0.5 M H₂SO₄/0.5M CH₃OH on GCE modified with FePt nanoparticles monolayer films illustrate that the as-synthesized FePt is a kind of active electrochemical catalyst.     

Dispersion of nano-silicon carbide (SiC) powder in aqueous suspensions

The dispersion characteristics of nanosize silicon carbide (SiC) suspension were investigated in terms of surface charge, particle size, rheological measurement and adsorption study. Ammonium polycarboxylate has been used as dispersant to stabilize the suspension. It was found that the isoelectric point (iep) of SiC powder was pH_iep (4.9). The surface charge of powder changed significantly in presence of the ammonium polycarboxylate dispersant and iep shifted significantly towards lower acidic pH (3.6). The shift in iep has been quantified in terms of ΔG ⁰ _SP, the specific free energy of adsorption between the surface sites and the adsorbing polyelectrolyte (APC). The values of ΔG ⁰ _SP (−10.85 RT unit) estimated by the electro kinetic data compare well with those obtained from adsorption isotherms (−9.521 RT unit). The experimentally determined optimum concentration of dispersant required for maximizing the dispersion was found to be 2.4 mg/g of SiC (corresponding to an adsorbed amount of 1.10 mg/g), at pH 7.5. This is much below the full monolayer coverage (corresponding to adsorbed amount of 1.75 mg/g) of the particles surface by the dispersant. The surface charge quantity, rheological, pH, electro kinetic and adsorption isotherm results were used to explain and correlate the stability of the nanosize silicon carbide in aqueous media. At pH 7.5, where both SiC surface and APC are negatively charged, the adsorption of APC was low because of limited availability of favourable adsorption sites. In addition, the brush-like configuration of the adsorbed polymer prevented close approach of any additional dispersant; hence stabilization of the slurry happens at a comparatively lower concentration than the monolayer coverage.     

Initial-state parton shower kinematics for NLO event generators

We are developing a consistent method to combine tree-level event generators for hadron collision interactions with those including one additional QCD radiation from the initial-state partons, based on the limited leading-log (LLL) subtraction method, aiming at an application to NLO event generators. In this method, a boundary between non-radiative and radiative processes necessarily appears at the factorization scale (μ_F). The radiation effects are simulated using a parton shower (PS) in non-radiative processes. It is therefore crucial in our method to apply a PS which well reproduces the radiation activities evaluated from the matrix-element (ME) calculations for radiative processes. The PS activity depends on the applied kinematics model. In this paper we introduce two models for our simple initial-state leading-log PS: a model similar to the ’old’ PYTHIA-PS and a p_T-prefixed model motivated by ME calculations. PS simulations employing these models are tested using W-boson production at LHC as an example. Both simulations show a smooth matching to the LLL subtracted W+1 jet simulation in the p_T distribution of W bosons, and the summed p_T spectra are stable against a variation of μ_F, despite that the p_T-prefixed PS results in an apparently harder p_T spectrum.     

Diffusion and transport phenomena in a collisional magnetoplasma having both streaming and temperature anisotropy: Collisional kinetics

Boltzmann-transport equation is analytically solved for two-component magnetoplasma using Chapman-Enskog analysis to include collisional diffusion transport having anisotropies in both streaming velocity and temperature components. The modified collisional integrals are analytically solved with flux integrals and perturbed kinetic equation to arrive at drift diffusion velocity and resulting transport coefficients which are markedly affected by both streaming and temperature anisotropy. The early isotropic results are recovered in the limit V ₀ = 0 and T _‖ = T _⊥ which reduce to eqs (11.30) and (11.31) of [1] and eqs (2.7) and (2.13) of [2]. The electrical resistivity (η_⊥) diminishes sharply in fusion temperature limit kT _⊥ = 1 keV. The shape of the curves for both electrical resistivity and thermal conductivity is rectangular hyperbolic. However, for low thermal ratio (T _‖/T _⊥ < 1), the curves are raised up and for high thermal ratio (T _‖/T _⊥ > 1), they are lowered down the isotropic case (T _‖/T _⊥ > 1), showing comparatively diminished magnitudes of the quantities.      

Adiabatic Theorems for Quantum Resonances

We study the adiabatic time evolution of quantum resonances over time scales which are small compared to the lifetime of the resonances. We consider three typical examples of resonances: The first one is that of shape resonances corresponding, for example, to the state of a quantum-mechanical particle in a potential well whose shape changes over time scales small compared to the escape time of the particle from the well. Our approach to studying the adiabatic evolution of shape resonances is based on a precise form of the time-energy uncertainty relation and the usual adiabatic theorem in quantum mechanics. The second example concerns resonances that appear as isolated complex eigenvalues of spectrally deformed Hamiltonians, such as those encountered in the N-body Stark effect. Our approach to study such resonances is based on the Balslev-Combes theory of dilatation-analytic Hamiltonians and an adiabatic theorem for nonnormal generators of time evolution. Our third example concerns resonances arising from eigenvalues embedded in the continuous spectrum when a perturbation is turned on, such as those encountered when a small system is coupled to an infinitely extended, dispersive medium. Our approach to this class of examples is based on an extension of adiabatic theorems without a spectral gap condition. We finally comment on resonance crossings, which can be studied using the last approach.     

Single photon and nonlocality

In a paper by Home and Agarwal [1], it is claimed that quantum nonlocality can be revealed in a simple interferometry experiment using only single particles. A critical analysis of the concept of hidden variable used by the authors of [1] shows that the reasoning is not correct.      

Hartree-Fock variational bounds for ground state energy of chargeless fermions with finite magnetic moment in the presence of a hard core potential: A stable ferromagnetic state

We use different determinantal Hartree-Fock (HF) wave functions to calculate true variational upper bounds for the ground state energy of N spin-half fermions in volume V ₀, with mass m, electric charge zero, and magnetic moment μ, interacting through magnetic dipole-dipole interaction. We find that at high densities when the average interparticle distance r ₀ becomes small compared to the magnetic length r _m ≡ 2mμ²/ħ², a ferromagnetic state with spheroidal occupation function n _↑(), involving quadrupolar deformation, gives a lower upper bound compared to the variational energy for the uniform paramagnetic state or for the state with dipolar deformation. This system is unstable towards infinite density collapse, but we show explicitly that a suitable short-range repulsive (hard core) interaction of strength U ₀ and range a can stop this collapse. The existence of a stable equilibrium high density ferromagnetic state with spheroidal occupation function is possible as long as the ratio of coupling constants Γ_cm ≡ (U ₀ a ³/μ²) is not very small compared to 1.      

Evaluation of nanoparticle emission for TiO<Subscript>2</Subscript> nanopowder coating materials

In this study, nanoparticle emission of TiO₂ nanopowder coated on different substrates including wood, polymer, and tile, was evaluated in a simulation box and measured with a Scanning Mobility Particle Sizer (SMPS) for the first time. The coating process for the substrate followed the instructions given by the supply company. In the simulation box, UV light, a fan, and a rubber knife were used to simulate the sun light, wind, and human contacting conditions. Among the three selected substrates, tile coated with TiO₂ nanopowder was found to have the highest particle emission (22 #/cm³ at 55 nm) due to nanopowder separation during the simulation process. The UV light was shown to increase the release of particle below 200 nm from TiO₂ nanopowder coating materials. The results show that, under the conditions of UV lamps, a fan and scraping motion, particle number concentration or average emission rate decreases significantly after 60 and 90 min for TiO₂/polymer and TiO₂/wood, respectively. However, the emission rate continued to increase after 2 h of testing for TiO₂/tile. It is suggested that nanoparticle emission evaluation is necessary for products with nanopowder coating.