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181.
    
The solvent extraction of cobalt(II), nickel(II) and copper(II) using 2,4-pent-dione (Hacac) and 4-phenyl-2, 4-but-dione (Hbzac) is carried out by varying the reagent concentration and pH of the aqueous phase. Each of these metals is quantitatively separated (≈ 98%) from their binary mixtures with monovalent (Ag), divalent (Mn, Zn, Cd, Hg, Mg, Sn, Pb) and trivalent (Cr, Fe) metals. The extraction constants are calculated from the metal distribution data using linear regression analysis. The extracted species is MA2 in each case. A most significant result is separation of copper(II) from iron(III) which otherwise interferes when extracted from the acidic medium.  相似文献   
182.
Chaos in duopoly pricing   总被引:5,自引:0,他引:5  
The dynamics of two competing firms in a market is studied in terms of Cournot's duopoly theory. Assuming iso-elastic demand and constant unit production costs the iterative mapping
for the outputs of the two firms ensues. The two constants are the unit production costs. The fixed point, the Cournot equilibrium, has earlier been assumed to be the only interesting feature of this model. It is, however, shown that the model can produce persistent motion, periodic or chaotic.  相似文献   
183.
In an attempt to develop a low‐k interlayer dielectric, adamantane‐diphenyldiethynyl moiety containing oligomer is prepared. Oligomerization of 1,3,5,7‐tetrakis[3/4‐ethynylphenyl]adamantane ( 4 ) is accomplished by a Glaser–Hay oxidative coupling with 1,3,5‐triethynylbenzene and phenylacetylene end‐capping agent. The CHCl3 soluble oligomer is then thermally treated by step‐curing at 200, 300, 380, and 450 °C for 30 min at each temperature under nitrogen flow to render a shiny void‐free black polymer. TGA analysis indicates that the polymer is stable under nitrogen up to 500 °C with a marginal decomposition up to 800 °C. Solid‐state 13C NMR, Raman scattering, and FTIR are used to characterize the structure of the polymer. The polymer consists of amorphous carbon networks with the adamantane moieties and nanosized graphitic regions (clusters), which are generated from the thermal crosslinking of the diphenyldiethynyl units. It shows a remarkably low linear coefficient of thermal expansion (~25 ppm/°C), presumably due to the presence of the disordered graphitic structure. Its high density (~1.21 g/cm3), refractive index (~1.80 at 632 nm), and Young's modulus (~17.0 GPa) are also consistent with the interpretation. This study reveals important details about the effect of microscopic structure on the macroscopic properties of the highly crosslinked polymer. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6909–6925, 2006  相似文献   
184.
185.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 55, No. 5, pp. 881–884, November, 1991.  相似文献   
186.
We survey recent progress achieved in understanding the impact of inelastic processes on coherent backscattering of light from cold atoms that are saturated by a powerful laser field.  相似文献   
187.
188.
Manganites of the LA1−x Ca x MnO3 family show a variety of new and poorly understood electronic, magnetic and structural effects. Here we outline a new approach recently proposed by us, where we argue that due to strong Jahn-Teller (JT) coupling with phonons the twofold degeneratee g states at the Mn sites dynamically reorganize themselves into localised, JT polaronsl with exponentially small inter-site hopping, and band-like, nonpolaronic statesb, leading to anew 2-band model for manganites which includes strong Coulomb and Hund’s couplings. We also discuss some results from a dynamical mean-field theory treatment of the model which explains quantitatively a wide variety of experimental results, including insulator-metal transitions and CMR, in terms of the influence of physical conditions on the relative energies and occupation of thel andb states. We argue that this microscopic coexistence of the two types of electronic states, and their relative occupation and spatial correlation is the key to manganite physics. Dedicated to Professor C N R Rao on his 70th birthday  相似文献   
189.
We study the problem of evaluation of the probability of ruin of an insurance company for infinitely many steps in the case where the company can invest its capital to bank deposits at any time. As a distribution of the amounts of claims to the insurance company, we use the gamma-distribution with the parameters n and α. __________ Translated from Ukrains’kyi Matematychnyi Zhurnal, Vol. 59, No. 4, pp. 447–457, April, 2007.  相似文献   
190.
Composition and rheological characteristics of aqueous solutions of acrylic acid/urea copolymers were studied, including the composition dependences of the equivalent conductivity and viscosity.  相似文献   
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