Acetylene weak bands at 2.5 μm from intracavity Cr:ZnSe laser absorption observed with time-resolved Fourier transform spectroscopy

The spectral dynamics of a mid-infrared multimode Cr(2+):ZnSe laser located in a vacuum sealed chamber containing acetylene at low pressure is analyzed by a stepping-mode high-resolution time-resolved Fourier transform interferometer. Doppler-limited absorption spectra of C(2)H(2) in natural isotopic abundance are recorded around 4000 cm(-1) with kilometric absorption path lengths and sensitivities better than 3 10(-8) cm(-1). Two cold bands are newly identified and assigned to the ν(1)+ν(4) (1) and ν(3)+ν(5) (1) transitions of (12)C(13)CH(2). The ν(1)+ν(5) (1) band of (12)C(2)HD and fourteen (12)C(2)H(2) bands are observed, among which for the first time ν(2)+2ν(4) (2)+ν(5) (-1).     

On the genericity of chaos

Let M be a compact manifold with dimM?2. We prove that some iteration of the generic homeomorphism on M is semiconjugated to the shift map and has infinite topological entropy (Theorem 1.1).     

Estimates of covering numbers of convex sets with slowly decaying orthogonal subsets

Covering numbers of precompact symmetric convex subsets of Hilbert spaces are investigated. Lower bounds are derived for sets containing orthogonal subsets with norms of their elements converging to zero sufficiently slowly. When these sets are convex hulls of sets with power-type covering numbers, the bounds are tight. The arguments exploit properties of generalized Hadamard matrices. The results are illustrated by examples from machine learning, neurocomputing, and nonlinear approximation.     

Nonvanishing cohomology and classes of Gorenstein rings

We give counterexamples to the following conjecture of Auslander: given a finitely generated module M over an Artin algebra Λ, there exists a positive integer n_M such that for all finitely generated Λ-modules N, if Ext_Λⁱ(M,N)=0 for all i?0, then Ext_Λⁱ(M,N)=0 for all i?n_M. Some of our examples moreover yield homologically defined classes of commutative local rings strictly between the class of local complete intersections and the class of local Gorenstein rings.     

Latex particles bearing hydrophilic grafted hairs with controlled chain length and functionality synthesized by reversible addition–fragmentation chain transfer

A method is described for synthesizing latex particles with anchored hairs by the grafting of hydrophilic chains, synthesized by reversible addition–fragmentation chain transfer, onto functionalized latex particles. These have the potential to bind biologically active species. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1188–1195, 2003     

Random Walks And The Colored Jones Function

It can be conjectured that the colored Jones function of a knot can be computed in terms of counting paths on the graph of a planar projection of a knot. On the combinatorial level, the colored Jones function can be replaced by its weight system. We give two curious formulas for the weight system of a colored Jones function: one in terms of the permanent of a matrix associated to a chord diagram, and another in terms of counting paths of intersecting chords. Electronic supplementary material to this article is available at and is accessible to authorized users. * S. G. was partially supported by an NSF and by an Israel-US BSF grant. † M. L. was partly supported by GAUK 158 grant and by the Project LN00A056 of the Czech Ministry of Education.     

Shape Optimization for Semi-Linear Elliptic Equations Based on an Embedding Domain Method

We study a class of shape optimization problems for semi-linear elliptic equations with Dirichlet boundary conditions in smooth domains in ℝ². A part of the boundary of the domain is variable as the graph of a smooth function. The problem is equivalently reformulated on a fixed domain. Continuity of the solution to the state equation with respect to domain variations is shown. This is used to obtain differentiability in the general case, and moreover a useful formula for the gradient of the cost functional in the case where the principal part of the differential operator is the Laplacian. Online publication 23 January 2004.     

Spectral enhancement of Polish vowels to improve their identification by hearing impaired listeners

Abnormalities in the cochlear function usually cause broadening of the auditory filters which reduces the speech intelligibility. An attempt to apply a spectral enhancement algorithm has been undertaken to improve the identification of Polish vowels by subjects with cochlear-based hearing-impairment. The identification scores of natural (unprocessed) vowels and spectrally enhanced (processed) vowels has been measured for hearing-impaired subjects. It has been found that spectral enhancement improves vowel scores by about 10% for those subjects, however, a wide variation in individual performance among subjects has been observed. The overall vowels identification scores obtained were 85% for natural vowels and 96% for spectrally enhanced vowels.