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61.
Jacques Rouzaud MatthewD. Jones Robert Raja BrianF.G. Johnson John MeurigThomas MelindaJ. Duer 《Helvetica chimica acta》2003,86(5):1753-1759
A set of new, air‐stable, RhI‐based heterogeneous asymmetric hydrogenation catalysts have been synthesised, characterised, and tested. Individual members of this new family all exhibit good enantioselectivity. 相似文献
62.
Robert H. Crabtree 《Journal of organometallic chemistry》2004,689(24):4083-4091
The title topic is reviewed with emphasis on catalysis and on recent advances. Alkane σ complexes, Shilov chemistry and oxidative addition routes are covered. Attention is also given to σ bond metathesis, surface-bound organometallics and CH activation involving carbene complexes. Closely related reactions of non-alkane substrates such as the Murai reaction are also discussed. 相似文献
63.
64.
Cordula Grüttner Knut Müller Joachim Teller Fritz Westphal Allan Foreman Robert Ivkov 《Journal of magnetism and magnetic materials》2007
Bionized nanoferrite (BNF) particles with high specific power absorption rates were synthesized in the size range of 20–100 nm by high-pressure homogenization for targeted cancer therapy with alternating magnetic fields. Several strategies were used to conjugate antibodies to the BNF particles. These strategies were compared using an immunoassay to find optimal conditions to reach a high immunoreactivity of the final antibody–particle conjugate. 相似文献
65.
66.
Robert G. Payton 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2007,44(6):876-888
A cylindrically orthotropic elastic solid is excited by a point impulsive body force. The solid contains a semi-infinite stress
free crack. The resulting anti-plane wave motion problem has been solved in the form of a finite series representing the incident
and reflected pulses plus an integral representing the diffraction pulse. The series part of the solution has been previously
treated. In the present investigation the diffraction integral is integrated when λ (which measures the anisotropy of the
solid) is an odd integer number. The diffraction integral is also integrated when λ is half an odd integer, for the special
case in which the source lies in the plane of the crack and parallel to the crack edge. The displacement jump across the circular
diffraction wave front is given for unrestricted (positive) values of λ. 相似文献
67.
We give a number of characterizations of bodies of constant width in arbitrary dimension. As an application, we describe a way to construct a body of constant width in dimension n, one of its (n – 1)‐dimensional projection being given. We give a number of examples, like a four‐dimensional body of constant width whose 3D‐projection is the classical Meissner's body. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
68.
MDF materials are chemically bonded ceramic materials free of the macrodefects typical of hydraulic cement-based materials. MDF materials arising through reactions of sulfo-aluminate-ferrite belitic (SAFB) clinkers and/or Portland cements (PC) with two types of water-soluble polymer (hydroxy-propylmethyl cellulose {HPMC}, polyphosphate glass {poly-P}) are discussed. Mixes of low energy SAFB clinkers with Portland cement, HPMC and, especially poly-P comprise promising cross-linked compositions additional to the better known MDF materials formed from high alumina cement with polyvinylalcohol/acetate. The principles of co-ordination of P and C atoms (of the polymer) with Al and Fe atoms (originating from the cement) are highlighted from spectroscopic information on next-nearest-neighbour interactions, along with the effects of second co-ordination spheres. Polymers modify the interface through functional bonding/grafting of polymer chains onto the surfaces of cement grains. Both the cross-linked atomic structure and the interface coincide well with the model of functional polymers and represent a new type of atomic-level structure in polymer-modified cements. Interpretation is based on previous magnetic resonance and thermal analysis studies. The compactness of Al(Fe)-O-P cross-links reduces transport through the interfaces, increasing the interfacial interactions and resisting the unfavourable uptake of moisture and carbonation. 相似文献
69.
Andreas Fischer 《Mathematical Programming》1997,76(3):513-532
The paper deals with complementarity problems CP(F), where the underlying functionF is assumed to be locally Lipschitzian. Based on a special equivalent reformulation of CP(F) as a system of equationsφ(x)=0 or as the problem of minimizing the merit functionΘ=1/2∥Φ∥
2
2
, we extend results which hold for sufficiently smooth functionsF to the nonsmooth case.
In particular, ifF is monotone in a neighbourhood ofx, it is proved that 0 εδθ(x) is necessary and sufficient forx to be a solution of CP(F). Moreover, for monotone functionsF, a simple derivative-free algorithm that reducesΘ is shown to possess global convergence properties. Finally, the local behaviour of a generalized Newton method is analyzed.
To this end, the result by Mifflin that the composition of semismooth functions is again semismooth is extended top-order semismooth functions. Under a suitable regularity condition and ifF isp-order semismooth the generalized Newton method is shown to be locally well defined and superlinearly convergent with the
order of 1+p. 相似文献