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81.
Ammar R Baringer P Coppage D Davis R Kelly M Kwak N Lam H Ro S Kubota Y Lattery M Nelson JK Perticone D Poling R Schrenk S Wang R Alam MS Kim IJ Nemati B Romero V Sun CR Wang P Zoeller MM Crawford G Fulton R Gan KK Kagan H Kass R Lee J Malchow R Morrow F Sung MK Whitmore J Wilson P Butler F Fu X Kalbfleisch G Lambrecht M Skubic P Snow J Bortoletto D Brown DN Dominick J McIlwain RL Miller DH Modesitt M Shibata EI Schaffner SF Shipsey IP Battle M Ernst J Kroha H Roberts S Sparks K Thorndike EH 《Physical review D: Particles and fields》1992,45(11):3976-3985
82.
Henderson S Kinoshita K Pipkin F Procario M Saulnier M Wilson R Wolinski J Xiao D Ammar R Baringer P Coppage D Davis R Haas P Kelly M Kwak N Lam H Ro S Kubota Y Nelson JK Perticone D Poling R Schrenk S Crawford G Fulton R Jensen T Johnson DR Kagan H Kass R Malchow R Morrow F Whitmore J Wilson P Bortoletto D Brown D Dominick J McIlwain RL Miller DH Modesitt M Schaffner SF Shibata EI Shipsey IP Battle M Kroha H Sparks K Thorndike EH Wang C Alam MS Kim IJ Li WC Nemati B Romero V Sun CR Wang P 《Physical review D: Particles and fields》1992,45(7):2212-2231
83.
Alexander J Artuso M Bebek C Berkelman K Browder T Cassel DG Cheu E Coffman DM Crawford G DeWire JW Drell PS Ehrlich R Galik RS Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Kandaswamy J Katayama N Kreinick DL Lewis JD Ludwig GS Mistry NB Mueller J Nandi S Nordberg E O'Grady C Peterson D Pisharody M Riley D Sapper M Selen M Silverman A Stone S Worden H Worris M Sadoff AJ Avery P Besson D Garren L Yelton J Bowcock T Kinoshita K Pipkin FM Procario M Wilson R Wolinski J Xiao D Zhu Y 《Physical review letters》1990,65(13):1531-1534
84.
Jin-Seong ParkChang-Eun Yeom Soo Hyuk ChoiYong Shik Ahn Sunggu Ro Young Ho Jeon Dong-Kyu Shin B.Moon Kim 《Tetrahedron letters》2003,44(8):1611-1614
An orthogonally protected β,γ′-diamino acid 6 possessing conformationally-constrained ring system was synthesized as a novel cyclic amino acid analogue. This synthesis involves as key steps chemoselective enzymatic hydrolysis of cis-piperidine-3,5-dicarboxylic ester derivative followed by efficient kinetic resolution of the partially resolved half-acid to afford the C1-symmetric piperidine-3,5-dicarboxylic acid monoester in high enantiomeric excess (>98% ee). The optically active half-acid was transformed to the cyclic amino acid via Curtius-type rearrangement. 相似文献
85.
Sixteen methyl glucopyranosyl glucopyranoside disaccharides (methyl beta-d-Glcp(p-Br-Bz)-(1-->x)-beta/alpha-d-Glcp) containing beta-glycosidic linkages (1-->2, 1-->3, 1-->4, and 1-->6) were synthesized and analyzed by means of CD and NMR spectroscopy in three different solvents. For each of these four types of disaccharides, a correlation was observed between the hydroxymethyl rotational populations around the C5-C6 bond of the glucopyranosyl residue II with the substituents and the anomeric configuration of the methoxyl group in residue I, as well as with the solvent. Nonbonded interactions, the stereoelectronic exo-anomeric effect, and hydrogen bonding were found to be responsible for the observed rotameric differences. Whereas the rotational populations of the (1-->6)-linked disaccharides are mainly dependent on the exo-anomeric effect, the (1-->2)-bonded disaccharides are strongly dependent on the anomeric configuration at C1, and the (1-->3)- and (1-->4)-linked disaccharides are mainly dependent on the substituents and the solvent. The population of the gt rotamer decreases as nonbonded interactions increase but increases as the exo-anomeric effect becomes greater, as well as in the presence of intramolecular hydrogen bonding to the endocyclic oxygen O5'. Comparison of the hydroxymethyl rotational preferences between our model disaccharides revealed a dependence on the glycosidic linkage type. Thus the population of the gg and gt rotamers decreases/increases from (1-->2)- (beta series), to (1-->6)-, to (1-->2)- (alpha series), to (1-->4)-, and to (1-->3)-bonded disaccharides respectively, while the tg rotamer population remains almost constant (around 20%), except for the (1-->3)- and (1-->4)-linked disaccharides with the intramolecular hydrogen bonding to O5', where this population decreases to 10%. 相似文献
86.
This paper describes the procedures of isolating strontium and yttrium from seawater that enable the determination of 89,90Sr. In one procedure, strontium is directly isolated from seawater on the column filled with Sr resin by binding of strontium to the resin from 3 M HNO3 in a seawater, and successive elution with HNO3. In others, strontium is precipitated from seawater with (NH4)2CO3, followed by isolation on a Sr column or an anion exchange column. It is shown that strontium precipitation is optimal with concentration of 0.3 M (NH4)2CO3 at pH = 11. In these conditions, 100% Y, 78% Sr, 80% Ca and 50% Mg are precipitated. Strontium is bound on to Sr column from 5 to 8 M HNO3, separated from other elements by elution with 3 M HNO3 and 0.05 M HNO3. Strontium and yttrium are bound on to anion exchange column from alcoholic solutions of nitric acid. The optimum mixture of alcohols for sample binding is a mixture of ethanol and methanol with the volume ratio 1:3. Strontium and yttrium are separated from Mg, Ca, K, and other elements by elution with 0.25 M HNO3 in the mixture of ethanol and methanol. After the separation, yttrium and strontium are eluted from the column with water or methanol.In the procedure of direct isolation from 1 l of the sample, the average recovery of 50% was obtained. In the remaining two procedures, the strontium recovery was about 60% for the Sr column and 65% for anion exchange column. Recovery of yttrium is about 70% for the anion exchange column. It turned out that the procedure with the Sr resin (direct isolation and isolation after precipitation) is simpler and faster in the phase of the isolation on the column in comparison with the procedure with the anion exchanger. The procedure with the anion exchanger, however, enables the simultaneous isolation of yttrium and strontium and rapid determination of 89,90Sr. These procedures were tested by determination of 89,90Sr on liquid scintillation counter and Cherenkov counting in 5 M HNO3. Obtained results showed that activity of 50 mBq l−1 of 89,90Sr and higher can be simultaneously determined. 相似文献
87.
The ligand of Numb protein-X (LNX) family, also known as the PDZRN family, is composed of four discrete RING-type E3 ubiquitin ligases (LNX1, LNX2, LNX3, and LNX4), and LNX5 which may not act as an E3 ubiquitin ligase owing to the lack of the RING domain. As the name implies, LNX1 and LNX2 were initially studied for exerting E3 ubiquitin ligase activity on their substrate Numb protein, whose stability was negatively regulated by LNX1 and LNX2 via the ubiquitin-proteasome pathway. LNX proteins may have versatile molecular, cellular, and developmental functions, considering the fact that besides these proteins, none of the E3 ubiquitin ligases have multiple PDZ (PSD95, DLGA, ZO-1) domains, which are regarded as important protein-interacting modules. Thus far, various proteins have been isolated as LNX-interacting proteins. Evidence from studies performed over the last two decades have suggested that members of the LNX family play various pathophysiological roles primarily by modulating the function of substrate proteins involved in several different intracellular or intercellular signaling cascades. As the binding partners of RING-type E3s, a large number of substrates of LNX proteins undergo degradation through ubiquitin-proteasome system (UPS) dependent or lysosomal pathways, potentially altering key signaling pathways. In this review, we highlight recent and relevant findings on the molecular and cellular functions of the members of the LNX family and discuss the role of the erroneous regulation of these proteins in disease progression. 相似文献
88.
L. Hock B. Helferich K. Neumann F. Peters H. Schmidt W. Lauppe B. Roßmann 《Colloid and polymer science》1951,123(1):54-56
Ohne Zusammenfassung 相似文献
89.
E. Mergel G. Schönwaβer H. Hübel D. Roβbach P. G. Thirolf M. Chromik D. Gassmann D. Habs P. Reiter 《Acta Physica Hungarica A》2001,13(1-3):199-202
Transitions between nuclear states with a large deformation difference may have large transition probabilities for E0 decay. Such an E0 decay has been found in the decay of the superdeformed 238U fission isomer back into the normal-deformed states [1]. However, a search for the E0 back-decay in 236U showed no result [2]. A setup has been developed to search for conversion electrons in this decay. 相似文献
90.
Abul Kasem Mohammad Mydul Islam Hyo‐Sub Lee Jin‐Ho Ro Danbi Kim Hyeyoung Kwon 《Journal of separation science》2019,42(14):2379-2389
A multi‐residue method has been developed and validated to determine 46 pesticides in spinach using liquid chromatography tandem mass spectrometry. The method is based on modified quick, easy, cheap, effective, rugged, and safe sample preparation, where high‐surface‐area graphitized carbon black was used first as sorbent material in the dispersive solid‐phase extraction. The method was compared with the quick, easy, cheap, effective, rugged, and safe method. The morphology, surface area, pore size, and pore volume of the sorbent was determined. The results obtained show that the sorbent consists of high surface area (233 m2/g) and large pore volume (1.5 cm3/g). The calibration curve correlation coefficient (R2) of the method was at least 0.99. The average recoveries ranged from 74 to 116%, and limits of detection and quantification from 0.0001 to 0.002 mg/kg and from 0.0002 to 0.005 mg/kg, respectively. Using the method, the pesticides exhibited low matrix effect (< 20%), except for nicosulfuron (29.86%), methomyl (26.77%), and flufenoxuron (24.65%). The method showed better potential to remove pigments than the quick, easy, cheap, effective, rugged, and safe method. It is demonstrated that the proposed method could be useful alternative for sample preparation of spinach and other matrices in future. 相似文献