全文获取类型
收费全文 | 537篇 |
免费 | 7篇 |
国内免费 | 4篇 |
专业分类
化学 | 272篇 |
晶体学 | 6篇 |
力学 | 30篇 |
数学 | 60篇 |
物理学 | 180篇 |
出版年
2022年 | 5篇 |
2021年 | 6篇 |
2020年 | 7篇 |
2017年 | 5篇 |
2016年 | 6篇 |
2015年 | 8篇 |
2014年 | 7篇 |
2013年 | 24篇 |
2012年 | 16篇 |
2011年 | 16篇 |
2010年 | 7篇 |
2009年 | 12篇 |
2008年 | 22篇 |
2007年 | 20篇 |
2006年 | 25篇 |
2005年 | 24篇 |
2004年 | 5篇 |
2003年 | 13篇 |
2002年 | 21篇 |
2001年 | 10篇 |
2000年 | 8篇 |
1999年 | 7篇 |
1998年 | 9篇 |
1997年 | 9篇 |
1996年 | 18篇 |
1995年 | 9篇 |
1994年 | 7篇 |
1993年 | 18篇 |
1992年 | 9篇 |
1991年 | 13篇 |
1990年 | 8篇 |
1989年 | 13篇 |
1988年 | 6篇 |
1987年 | 10篇 |
1986年 | 10篇 |
1985年 | 10篇 |
1984年 | 4篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1979年 | 8篇 |
1978年 | 5篇 |
1977年 | 8篇 |
1976年 | 8篇 |
1975年 | 8篇 |
1974年 | 9篇 |
1973年 | 4篇 |
1968年 | 6篇 |
1966年 | 9篇 |
1959年 | 4篇 |
排序方式: 共有548条查询结果,搜索用时 15 毫秒
41.
Enzymes can be used in nonpolar reaction media to modify waterinsoluble substrates. A variety of pretreatments, applied to
the enzyme prior to introduction to the nonpolar media, can improve enzyme activity. However, the various pretreatments have
not been studied using directly comparable conditions, nor have they been applied simultaneously to test for interactive effects.
This work evaluates pretreatment of lipase with various classes of additives. The pretreated lipase is used to catalyze esterification
between citronellol and acetic acid in a medium of n-hexane. The effectiveness of a particular pretreatment is presented in terms of relative performance (RP), which is equal
to the number of times faster the pretreated lipase catalyzes the reaction relative to untreated lipase. The individual and
interactive effects of the pretreatment factors were studied and compared. Buffer salts had a much stronger performance-enhancing
effect than nonbuffer salts; pretreatment with 90% (w/w) sodium phosphate yielded lipase with an RP of approx 64. A strong
interaction was found between the treatments with sodium phosphate and pH adjustment. These treatments may mitigate the inhibitory
effect of acetic acid. Activating effects of phase interfaces and active-site protectants are shown to be complementary to
other treatments, demonstrating that they likely act by distinct mechanisms. 相似文献
42.
43.
44.
We study the filling length function for a finite presentation of a group , and interpret this function as an optimal bound on the length of the boundary loop as a van Kampen diagram is collapsed to the basepoint using a combinatorial notion of a null-homotopy. We prove that filling length is well behaved under change of presentation of . We look at 'AD-pairs' (f,g) for a finite presentation
: that is, an isoperimetric function f and an isodiametric function g that can be realised simultaneously. We prove that the filling length admits a bound of the form [g+1][log (f+1)+1] whenever (f,g) is an AD-pair for
. Further we show that (up to multiplicative constants) if
is an isoperimetric function (
) for a finite presentation then (
) is an AD-pair. Also we prove that for all finite presentations filling length is bounded by an exponential of an isodiametric function.Partially supported by NSF grant DMS-9800158Supported by EPSRC Award No. 98001683 and Corpus Christi College, Oxford. 相似文献
45.
Bornheim A Lipeles E Pappas SP Shapiro A Sun WM Weinstein AJ Masek G Paar HP Mahapatra R Morrison RJ Briere RA Chen GP Ferguson T Tatishvili G Vogel H Adam NE Alexander JP Bebek C Berkelman K Blanc F Boisvert V Cassel DG Drell PS Duboscq JE Ecklund KM Ehrlich R Gibbons L Gittelman B Gray SW Hartill DL Heltsley BK Hsu L Jones CD Kandaswamy J Kreinick DL Magerkurth A Mahlke-Krüger H Meyer TO Mistry NB Nordberg E Palmer M Patterson JR Peterson D Pivarski J Riley D Sadoff AJ Schwarthoff H 《Physical review letters》2002,88(23):231803
We report a new measurement of the Cabibbo-Kobayashi-Maskawa parameter Vub made with a sample of 9.7 x 10(6) BB- events collected with the CLEO II detector. Using heavy quark theory, we combine the observed yield of leptons from semileptonic B decay in the end-point momentum interval 2.2-2.6 GeV/c with recent CLEO II data on B-->X(s)gamma to find Vub = (4.08+/-0.34+/-0.44+/-0.16+/-0.24)x10(-3), where the first two uncertainties are experimental and the last two are from theory. 相似文献
46.
A wavefunction used in an earlier calculation of the nuclear shielding of the hydrogen molecule has been tested by comparing the calculated magnetic susceptibility against that of Kolos and Wolniewicz. Good agreement is obtained. The procedure of Herman and Short for averaging over the nuclear motion has also been tested by comparing the predicted susceptibilities of H2, Hd and D2 with those obtained from averages of the Rydberg-Klein-Rees potential curves by Jain and Sahni. Again, good agreement is found.For the first time calculated values have been obtained for the susceptibilities of the isoropomers of hydrogen which contain tritium. It is predicted that accurate susceptibility measurements should not only be able to distinguish between all the various isotopomers but should also detect the temperature dependence of the susceptibility of any one isotopomer. 相似文献
47.
48.
Free convection from a horizontal line source of heat 总被引:1,自引:0,他引:1
Norman Riley 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1974,25(6):817-828
Summary In this paper a study is made of finite Grashof number effects upon the flow, in an unbounded domain, in the buoyant plume which forms over a horizontal line source of heat. The consequences of introducing a plane boundary into the domain are also assessed for two particular configurations.
Zusammenfassung In dieser Arbeit wird der Effekt der endlichen Grashof-Zahl auf die Strömung untersucht, in einem unbegrenzten Medium mit natürlicher Konvektion, die durch eine horizontale linienförmige Quelle erzeugt wird. Die Folgen einer ebenen Begrenzungsfläche werden für zwei besondere Konfigurationen untersucht.相似文献
49.
An apparatus and a procedure are described for the preconcentration of nanogram amounts of trace elements. Co-precipitation and pressure filtration confine the precipitate to a 1.27 mm diameter spot on a filter membrane. Trace elements in the 10-100 ng range are collected reproducibly and detected with high sensitivity by X-ray fluorescence, by use of a milliprobe instrument. Advantages of the technique for quantitative applications are discussed. 相似文献
50.