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11.
I. Bellucci und B. Ricca 《Fresenius' Journal of Analytical Chemistry》1925,67(7-8):314
Ohne Zusammenfassung 相似文献
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In this paper we consider the Bounded Length Median Path Problem which can be defined as the problem of locating a path-shaped facility that departures from a given origin and arrives at a given destination in a network. The length of the path is assumed to be bounded by a given maximum length. At each vertex of the network (customer-point) the demand for the service is given and the cost to reach the closest service-point is computed. The objective is to minimize the sum of these costs over all the customer-points in the network. 相似文献
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Alessandra Ricca Jean M. J. Tronchet Jacques Weber 《Journal of computer-aided molecular design》1992,6(6):541-552
Summary The cytotoxic activities of a series of sugar derivatives bearing electrophilic groups (1-cyanovinyl, 4-cyanochromen-2-yl and 3-nitrochromen-2-yl) have been correlated with their electrophilic properties. To this end, an electrophilic index was defined as an isovalue surface where the interaction energy with an incoming model nucelophile (H–) was equal to a predefined value. This index, calculated from extended Hückel wave functions, allows one to quantify the electrophilic character of the substrates and to describe its spatial localization within the molecular volume (at Michael acceptor sites or on other parts of the molecules). Only sugars for which Michael acceptor reactivity was predicted were retained, and they were subdivided into two groups: those showing antiviral activity against a retrovirus and those devoid of such activity. Under these conditions, good correlations between cytotoxic activity and electrophilic reactivity-positive for the first group, negative for the second-were found. In addition, the ratio electrophilicity/sum of the absolute value of the dipole plus its projection along the principal axis of inertia, Z, of the molecule allows one to predict to which of these groups a sugar derivative belongs. 相似文献
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An internally consistent set of carbon-13 assignments for ajmaline (1) and three diastereomers isoajmaline (2), sandwicine (3) and isosandwicine (4), are presented. 相似文献
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The well-known Kramers-Krönig relations, pertaining to linear processes, can be generalized to non-linear ones. For simplicity, only the quadratic non-linearity is considered in some detail here. 相似文献
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The wave function resulting from an accurate Hartree-Fock computation has been used to describe the electron momentum distribution in beryllium metal. Appreciable discrepancies are found with respect to a simple model that amounts to filling with plane waves the first plus second Brillouin zone. In comparing the calculated with the experimental directional Compton profiles, very close agreement is found in particular with a recent set of accurate -ray profiles. The differential Compton profiles are also semiquantitatively reproduced, better on average than with all previous calculations. Concerning the Fourier transforms of the Compton profiles, all the features of the experimental curves are accurately reproduced, in particular the position of the zero passages, which is a powerful test of the adequacy of a theoretical model to account for the metallic nature of the solid. The possible influence of the correlation correction is discussed, and it is shown that such a correction would substantially improve the overall agreement with the experiment. 相似文献
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