全文获取类型
收费全文 | 658篇 |
免费 | 6篇 |
专业分类
化学 | 492篇 |
晶体学 | 12篇 |
力学 | 26篇 |
数学 | 38篇 |
物理学 | 96篇 |
出版年
2021年 | 7篇 |
2018年 | 7篇 |
2016年 | 7篇 |
2013年 | 29篇 |
2012年 | 25篇 |
2011年 | 25篇 |
2010年 | 13篇 |
2009年 | 13篇 |
2008年 | 25篇 |
2007年 | 33篇 |
2006年 | 20篇 |
2005年 | 19篇 |
2004年 | 18篇 |
2003年 | 18篇 |
2002年 | 28篇 |
2001年 | 11篇 |
2000年 | 16篇 |
1999年 | 9篇 |
1998年 | 8篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 10篇 |
1993年 | 11篇 |
1992年 | 20篇 |
1991年 | 12篇 |
1990年 | 8篇 |
1988年 | 12篇 |
1987年 | 6篇 |
1986年 | 8篇 |
1985年 | 8篇 |
1984年 | 10篇 |
1983年 | 8篇 |
1982年 | 7篇 |
1981年 | 7篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 7篇 |
1977年 | 6篇 |
1976年 | 10篇 |
1975年 | 9篇 |
1974年 | 12篇 |
1973年 | 8篇 |
1972年 | 10篇 |
1971年 | 12篇 |
1970年 | 6篇 |
1969年 | 5篇 |
1960年 | 5篇 |
1958年 | 9篇 |
1954年 | 5篇 |
排序方式: 共有664条查询结果,搜索用时 15 毫秒
31.
A Metal–Organic Framework with Cooperative Phosphines That Permit Post‐Synthetic Installation of Open Metal Sites 下载免费PDF全文
Samuel G. Dunning Gianne Nandra Adam D. Conn Wenrui Chai R. Eric Sikma Ji Sun Lee Pranaw Kunal Joseph E. Reynolds III Jong‐San Chang Alexander Steiner Graeme Henkelman Simon M. Humphrey 《Angewandte Chemie (International ed. in English)》2018,57(30):9295-9299
PCM‐101 is a phosphine coordination material comprised of tris(p‐carboxylato)triphenylphosphine and secondary pillaring groups coordinated to [M3(OH)]5+ nodes (M=Co, Ni). PCM‐101 has a unique topology in which R3P: sites are arranged directly trans to one another, with a P???P separation distance dictated by the pillars. Post‐synthetic coordination of soft metals to the P: sites proceeds at room temperature to provide X‐ray quality crystals that permit full structural resolution. Addition of AuCl groups forces a large distortion of the parent framework. In contrast, CuBr undergoes insertion directly between the trans‐P sites to form dimers that mimic solution‐phase complexes, but that are geometrically strained due to steric pressure exerted by the MOF scaffold. The metalated materials are active in heterogeneous hydroaddition catalysis under mild conditions, yielding different major products compared to their molecular counterparts. 相似文献
32.
33.
The axial resolution of optical coherence tomography images is primarily dependent on the bandwidth of the illumination source. Continuum generation is one way to generate the single-mode, high-bandwidth light needed for point illumination. We present an inexpensive and easy-to-implement augmentation to a Ti:sapphire laser that widens the bandwidth from 20 to over 200 nm with commerically available ultrahigh-numerical-aperture fiber. This technique can provide a readily available broad-bandwidth source for researchers and a practical enhancement to a fiber-optic optical coherence tomography system. 相似文献
34.
35.
36.
37.
Wear KA Laib A Stuber AP Reynolds JC 《The Journal of the Acoustical Society of America》2005,117(5):3319-3324
Biot's theory for elastic propagation in porous media has previously been shown to be useful for modeling the dependence of phase velocity on porosity in bovine cancellous bone in vitro. In the present study, Biot's theory is applied to measurements of porosity-dependent phase velocity in 53 human calcanea in vitro. Porosity was measured using microcomputed tomography for some samples (n = 23) and estimated based on bone mineral densitometry for the remaining samples (n = 30). The phase velocity at 500 kHz was measured in a water tank using a through-transmission technique. Biot's theory performed well for the prediction of the dependence of sound speed on porosity. The trend was quasilinear, but both the theory and experiment show similar slight curvature. The root mean square error (RMSE) of predicted versus measured sound speed was 15.8 m/s. 相似文献
38.
Reynolds AM 《Journal of colloid and interface science》2004,275(1):328-335
The statistical properties of fluid velocities along particle trajectories in turbulent flows have a conditional dependency upon particle velocity. It is shown that the formulation of Lagrangian stochastic (LS) models for particle trajectories in terms of the well-mixed condition for these conditional velocity statistics is exactly analogous to the formulation of second-order LS models for fluid-particle trajectories. The particle aerodynamic response time is shown to be incorporated at second order, which together with the Lagrangian timescale introduced at first order, defines the Stokes number. Reynolds-number effects can be incorporated at third order. The corresponding Fokker-Planck equation is shown to be identical to that advocated by Pozorski and Minier [Phys. Rev. E 59 (1999) 855], who included the fluid velocities "seen" by a particle in the probability density function (pdf) formalism of Reeks and co-workers as a means of circumventing the closure problem (prescribing a closure for the particle flux induced by the fluid) associated with that approach. It is demonstrated that the neglect of Stokes-number effects accounts, in part, for the tendency of first-order LS models to underpredict particle deposition velocities in the diffusion-impaction regime. 相似文献
39.
Reynolds AM 《Physical review letters》2003,91(8):084503
The Lagrangian stochastic model of Reynolds [Phys. Fluids 15, L1-4 (2003)]] for the accelerations of fluid particles in turbulence is shown to predict precisely the observed Reynolds-number dependency of the distribution of Lagrangian accelerations and the exponents characterizing the observed extended self-similarity scaling of the Lagrangian velocity structure functions. Departures from superstatistics of the log-normal kind are accounted for and their impact upon model predictions is quantified. 相似文献
40.
Several novel glycofuranoses disaccharides related to mycobacterial cell wall polysaccharides were synthesized regio- and stereoselectively using 2,3,5-tri-O-benzoyl-alpha-D-arabinofuranosyl trichloroacetimidate as a glycosyl donor. 相似文献