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101.
Indigo is one of the oldest dyes manufactured chemically and is mostly used in textile, food, and pharmaceutical industries.
However, owing to the environmental hazards posed by the chemical production, the present scenario in the field stipulates
a biosynthesis alternative for indigo production. The present study describes an indigenously isolated naphthalene-degrading
strain Pseudomonas sp. HOB1 producing a blue pigment when indole was added in the growth medium. This blue pigment was analyzed by high-pressure
thin-layer chromatography and other spectroscopic techniques which revealed it to be the indigo dye. Pseudomonas sp. HOB1 showed ability to produce 246 mg indigo liter−1 of the medium. The K
m for the enzyme naphthalene dioxygenase which is involved in indigo formation is 0.3 mM, and V
max was as high as 50 nmol min−1 mg dry biomass−1. The bacterial indigo dye was further successfully applied for dyeing cotton fabrics. The high indigo productivity of Pseudomonas sp. HOB1 using naphthalene as growth substrate and its applicability on cotton fabrics, therefore, stems the probability
of using this culture for commercial indigo production. 相似文献
102.
Polyaniline nanotube (PANI-NT) based films have been fabricated onto indium-tin-oxide (ITO) coated glass plates via electrophoretic technique. These PANI-NT/ITO electrodes have been utilized for covalent immobilization of cholesterol oxidase (ChOx) using glutaraldehyde (Glu) as cross-linker. Structural, morphological and electrochemical characterization of PANI-NT/ITO electrode and ChOx/Glu/PANI-NT/ITO bioelectrode have been done using FT-IR spectroscopy, SEM, electrochemical impedance spectroscopy and cyclic voltammetry techniques. Response studies of the ChOx/Glu/PANI-NT/ITO bioelectrode have been carried out using both linear sweep voltammetry and UV-Visible spectrophotometry. The results of the biosensing studies reveal that this bioelectrode can be used to detect cholesterol in wide detection range of 25-500 mg/dL with high sensitivity of 3.36 mA mg(-1) dL and fast response time of 30 s at pH 7.4. This bioelectrode exhibits very low value of Michaelis-Menten constant of 1.18 mM indicating enhanced interactions between cholesterol and ChOx immobilized onto this nanostructured PANI matrix. 相似文献
103.
Y.N. Rao D. Banerjee A. Datta S.K. Das R. Guin A. Saha 《Radiation Physics and Chemistry》2010,79(12):1240-1246
Aqueous dispersions of highly stable, redispersible silver nanoparticles (Ag NPs) were synthesized using gamma radiolysis with gum acacia as a protecting agent. The formation of nanosized silver was confirmed by its characteristic surface plasmon absorption peak at around 405 nm in UV–vis spectra. The size of the silver nanoparticles can be tuned by controlling the radiation dose, ratio of gum acacia to silver ions and also the ionic strength of the medium. Dynamic light scattering (DLS) measurement of the as-synthesized nanoparticles indicated the size less than 3 nm at higher dose of radiation and this also corroborated the size measurement from the width of the corresponding X-ray diffraction (XRD) peak. The face centered cubic (fcc) crystallinity of the nanoparticles was evident from XRD and high resolution transmission electron microscopic (HRTEM) measurements. Fourier transform infra-red (FTIR) spectroscopic data indicate a bonding of Ag NPs with COO? group of acacia through bridging bidentate linkage. 相似文献
104.
We quantify the one-shot entanglement cost of an arbitrary bipartite state, that is, the minimum number of singlets needed by two distant parties to create a single copy of the state up to a finite accuracy, by using local operations and classical communication only. This analysis, in contrast to the traditional one, pertains to scenarios of practical relevance, in which resources are finite and transformations can be achieved only approximately. Moreover, it unveils a fundamental relation between two well-known entanglement measures, namely, the Schmidt number and the entanglement of formation. Using this relation, we are able to recover the usual expression of the entanglement cost as a special case. 相似文献
105.
An efficient and direct procedure for the synthesis of amidoalkyl-2-naphthol derivatives has been described. The process employs a three-component cyclocondensation reaction in one-pot using β-naphthol, aromatic aldehyde and acetamide or benzamide in the presence of silica chloride accelerated by ultrasound giving the product in excellent yield in very short duration. 相似文献
106.
D. Madhavi LathaV.G.K.M. Pisipati C. Rama Chandra PrabhuP.V. Datta Prasad 《Journal of Molecular Liquids》2011,164(3):187-190
The thermodynamic parameters like Moelwyn-Hughes parameter (C1), reduced molar volume (V~), isochoric temperature coefficient of internal pressure (X), Huggin's parameter (F), Gruneisen parameter (Γp), isothermal microscopic Gruneisen parameter, Sharma parameter (So), fraction free volume (f) and (A?) a dimensionless thermal parameter, etc and the Beyer's nonlinearity parameter (B/A) were deduced employing the thermal expansion coefficient derived from density data for the homologues series of compounds terephthalyidene-bis-p-n-alkyl anilines, TBnA with n = 5 to 10,12,14,16 and 18. Further, it is found that the variation of molecular radius, Mr increases with the increase of alkyl chain number, with a core radius of 4.78 Å and the increment for methylene unit is 0.086 Å . The results were discussed with the body of the data available. 相似文献
107.
D. Madhavi LathaV.G.K.M. Pisipati J. Lalitha KumariP.V. Datta Prasad 《Journal of Molecular Liquids》2011,163(1):14-19
Different thermodynamic parameters are estimated from volume expansion coefficient, α for a number of N-(p-n-alkoxybenzylidene)-p-n-butyloxyanilines, nO.O4 compounds in isotropic phase (at TIN + 5 °C) and in liquid crystalline phases. The variation of different thermodynamic parameters with the alkoxy chain length in nO.O4 series and their variation with the temperature in individual liquid crystal compounds are discussed. The parameters like available volume (Va), inter molecular free length (Lf) and molecular radius (Mr) are also computed from density, and refractive index for these nO.O4 compounds and the nature of molecular free length and molecular radius are analyzed and discussed. 相似文献
108.
Effect of various abiotic (methyl jasmonate, salicylic acid) and biotic (yeast extract, Aspergillus niger) elicitors on furanocoumarin production and in situ product removal was studied using shoot cultures of Ruta graveolens L. Elicitation by yeast extract (1% w/v) on day 15 was most effective. It led to 7.8-fold higher furanocoumarin production that was attained 24 h after elicitation
and 43% of the product was released into the medium. Changes in the relative concentration of furanocoumarins produced depend
on the elicitor used. Molar ratio of bergapten increased to 93% in response to yeast extract. With the perspective of developing
a commercially feasible process, an approach for preserving viability of biomass and its reuse needs to be developed. For
this, medium renewal strategy was investigated. Removal of the spent medium 48 h after elicitation allowed in situ product
removal and proved effective in revival of cultures, allowing reuse of biomass. A week after medium renewal, the revived biomass
was re-elicited and a second furanocoumarin production peak was obtained. A perfusion-based bioprocess optimization approach,
employing elicitation coupled with medium renewal with subsequent re-elicitation, as a new strategy for improved furanocoumarin
production, has been suggested. 相似文献
109.
110.
R. Renuka S. Rajasekaran Ganga Radhakrishnan 《Applied biochemistry and biotechnology》2001,96(1-3):83-92
Among the possible new materials for microelectronics, quinones have a number of significant advantages. Similarly, polymers
with quinone functionality possess biodegradability. Because natural polymers are promising candidates for functional materials
for the future, we have initiated studies on the polymers of natural products. In the present study, a natural quinone (a
plant substance) extracted from Embelier libes distributed in the Kerala state of India was electrochemically polymerized and its properties were investigated. The redox
activity, electrical conductivity, and biodegradability are discussed. 相似文献