Thin Films and Interfaces of Electroactive Organic Materials: The Surface Science Approach

 We highlight the importance of interfacial properties in determining the performance of devices based on electroactive organic materials. Investigations of the interfaces of benzene with Al(111) and In₂O₃ are presented as a model of interface properties for devices based on complex aromatic molecules. At both interfaces the binding is shown to be electrostatic, with the resulting interface dipole determining the band alignment. It is also argued that chemical modification of substrates can be used to tailor both electronic and structural properties.     

The peptide (Z)‐Pro–Leuol

The structure of the synthetic protected dipeptide (Z)‐Pro–Leuol [systematic name: benzyl 2‐(1‐hydroxy­methyl‐3‐methyl­butyl­amino­carbonyl)­pyrrolidine‐1‐carboxyl­ate], C₁₉H₂₈N₂O₄, was determined by X‐ray crystallography. The peptide adopts a novel backbone conformation compared with other longer oligopeptides containing Pro–Leuol.     

A New Kinetic Model for Water Sorption Isotherms of Cellulosic Materials

Summary: Some natural fibres like flax, hemp and others show excellent mechanical properties which make them a promising choice for the reinforcement of polymers. For natural fibre reinforced composites, hydrophilicity is a problem with respect to dimensional changes, fibre to matrix adhesion and long term stability. The interaction of differently prepared and modified fibres with water vapour has been investigated by dynamic vapour sorption. It has been found that the sorption and desorption kinetics of cellulosic fibres can be excellently fitted by assuming two parallel, independent first order processes. This empirical model, defined here as the “Parallel Exponential Kinetics” model (PEK-model), reveals two distinct mechanisms with slow and fast exchange of water vapour respectively, related to different sorption sites. The specific sorption mechanisms are represented by individual sorption-desorption isotherms as components of the total isotherms. The results suggest a relation to the differing types of amorphous regions in the fibres and/or to the different states of “bound” or “free” water, discussed for hydrophilic materials. The PEK-model proved to be consistently applicable for sorption and desorption over the whole humidity range, and also for all tested cellulose fibres. It is especially useful for a clearer distinction of different fibre types or modifications and can be successfully used for an extended fibre characterization.     

Efficient transient noise analysis in circuit simulation

Stochastic differential algebraic equations (SDAEs) arise as a mathematical model for electrical network equations that are influenced by additional sources of Gaussian white noise. We discuss adaptive linear multi-step methods for their numerical integration, in particular stochastic analogues of the trapezoidal rule and the two-step backward differentiation formula, and we obtain conditions that ensure mean-square convergence of this methods. For the case of small noise we present a strategy for controlling the step-size in the numerical integration. It is based on estimating the mean-square local errors and leads to step-size sequences that are identical for all computed paths. Test results illustrate the performance of the presented methods. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Zur Realstruktur bearbeiteter Silizium-Einkristallscheiben

The production of semiconductor devices is based on single crystal silicon wafers worked by abrasive cutting, lapping and polishing. Relations between the structure of the silicon surface and the generation of dislocation are analyzed by electronmicroscopical imaging of the surface after the respective steps of mechanical treatment and by TEM after annealing.     

On the Epistemological Status of Cosmology Anthropic Principle,Cosmological Numbers,and the Subject of Cosmology

It is shown that cosmology destroys the fundamental on which it lies as a natural-scientific discipline if it introduces subjectivistic principles as one of them is the so-called Anthropic Principle that superseds the Copernican turn of sciences. Likewise conceptions are proved as conceptions that contradict the physical cosmology which conceive that the “World harmony” or the physical-uniform grasping of the world can be derived from numbers or relations of numbers. This is due to the fact that these conceptions liquadate the advantage of physics to get via measurements statements about reality.