气体自发瑞利-布里渊散射的理论分析及压强反演

气体压力是描述体系状态的重要参数,许多物理、化学性质都与压力有关.传统侵入式的压力测量方法会对气体状态产生干扰,影响测量精度,因此需要一种无扰式的测量方法.本实验测量了压强为2,4和6 atm(1 atm=1.01325×10~5 Pa)下加入气溶胶的N2在90?散射方向的自发瑞利-布里渊散射光谱,利用卷积后的Tenti S6模型对测量光谱进行直接拟合,拟合得到的压强值总体误差小于6.0%,求和归一化的均方根误差总体小于6.5%;利用理想的Tenti S6模型对经维纳滤波器反卷积处理后的测量光谱进行拟合,拟合得到的压强值误差总体小于5.0%,求和归一化的均方根误差总体小于6.0%.通过对两种方法的详细对比,发现压强低于2 atm时,对测量光谱进行反卷积处理在一定程度上可以消除仪器函数的影响,提高测量光谱的准确性,其光谱拟合效果和压强反演精度要优于卷积光谱.而在压强高于2 atm的情况下,卷积光谱的拟合效果和压强反演精度要优于反卷积光谱.     

First principles study on the magnetocrystalline anisotropy of Fe--Ga magnetostrictive alloys

This paper investigates the electronic structure and magnetocrystalline anisotropy of Fe--Ga magnetostrictive material by means of the full potential-linearized augmented plane-wave method within the generalized gradient approximation. The 3d-orbit splitting of Fe atoms in D0₃, B2-like and L1₂ crystalline structures of Fe--Ga is calculated with consideration of the crystal field as well as the spin--orbit coupling effect. Because of the frozen orbital angular momenta of the 3d-orbit for Fe atoms in Fe--Ga magnetostrictive alloys and the spin--orbit coupling, the distribution of the electron cloud is not isotropic, which leads to the anisotropy of exchange interaction between the different atoms. A method on estimating the magnetocrystalline anisotropy of Fe--Ga alloys by means of calculating orbit-projected density of states for Fe atoms is performed. The anisotropic distribution of the electron cloud of Fe atoms in these three crystalline structures of Fe--Ga is studied based on the above method showing the highest magnetic anisotropy for B2-like structure. This qualitative method comes closer to physical reality with a vivid physical view, which can evaluate the anisotropy of electron cloud for 3d transition atoms directly. The calculated results are in good agreement with both the previous theoretical computation and the tested value on the magnetic anisotropy constant, which confirms that the electron cloud anisotropy of Fe atoms could well characterize the magnetocrystalline anisotropy of Fe--Ga magnetostrictive material.     

MoO3的水热法制备、表征及储锂性能

以钼酸钠和水杨酸钠为原料,通过水热法合成了MoO3.借助X射线衍射(XRD)、扫描电子显微镜(SEM)等对材料的结构和形貌进行表征,采用电化学工作站和充放电仪对电池的电化学性能进行测试.研究结果表明:在180 ℃下水热反应12 h制备得到六方相MoO3(h-MoO3)纳米块相较于在180 ℃下水热反应24 h制备得到正交相MoO3(α-MoO3)纳米片的电化学性能更佳.当h-MoO3 作为锂离子电池负极电极材料时,其首次放电比容量为2068.1 mAh/g.在电流密度为50 mA/g下循环50次后,其放电比容量仍然高达946.4 mAh/g,这归因于h-MoO3较小的电化学转移阻抗.     

Pull-in instability of a typical electrostatic MEMS resonator and its control by delayed feedback

Pull-in instability of the electrostatic microstructures is a common undesirable phenomenon which implies the loss of reliability of micro-electromechanical systems. Therefore, it is necessary to understand its mechanism and then reduce the phenomenon. In this work, pull-in instability of a typical electrostatic MEMS resonator is discussed in detail. Delayed position feedback and delayed velocity feedback are introduced to suppress pull-in instability, respectively. The thresholds of AC voltage for pull-in instability in the initial system and the controlled systems are obtained analytically by the Melnikov method. The theoretical predictions are in good agreement with the numerical results. It follows that pull-in instability of the MEMS resonator can be ascribed to the homoclinic bifurcation inducing by the AC and DC load. Furthermore, it is found that the controllers are both good strategies to reduce pull-in instability when their gains are positive. The delayed position feedback controller can work well only when the delay is very short and AC voltage is low, while the delayed velocity feedback will be effective under a much higher AC voltage and a wider delay range.     

Singular Perturbation of Reduced Wave Equation and Scattering from an Embedded Obstacle

We consider time-harmonic wave scattering from an inhomogeneous isotropic medium supported in a bounded domain ${\Omega \subset \mathbb{R}^N}$ (N ≥?2). In a subregion ${D \Subset \Omega}$ , the medium is supposed to be lossy and have a large mass density. We study the asymptotic development of the wave field as the mass density ρ → +?∞ and show that the wave field inside D will decay exponentially while the wave filed outside the medium will converge to the one corresponding to a sound-hard obstacle ${D \Subset \Omega}$ buried in the medium supported in ${\Omega \backslash \overline{D}}$ . Moreover, the normal velocity of the wave field on ? D from outside D is shown to be vanishing as ρ → +?∞. We derive very accurate estimates for the wave field inside and outside D and on ? D in terms of ρ, and show that the asymptotic estimates are sharp. The implication of the obtained results is given for an inverse scattering problem of reconstructing a complex scatterer.     

一种基于多种群对立平行进化策略的DE算法

针对微分进化算法应用于换热网络优化时易陷入局部区域和收敛精度不高的缺点,建立一种多种群对立的平行进化策略的微分进化算法.首先建立原始种群的对立种群;在此基础上,通过原始种群与对立种群的变异操作进行信息共享产生新的试验个体;最后运用多轮对立的思想保持多种群平行进化,使种群在保留当前求解信息的同时又能在求解域内进行更大范围搜索.对换热网络的经典算例计算表明,本文提出的多种群对立平行进化微分进化算法能够有效增强种群多样性,扩大算法的全局搜索能力,跳出局部极值陷阱,得到较好的优化结果.     

A parallel two-level finite element method for the Navier-Stokes equations

Based on domain decomposition, a parallel two-level finite element method for the stationary Navier-Stokes equations is proposed and analyzed. The basic idea of the method is first to solve the Navier-Stokes equations on a coarse grid, then to solve the resulted residual equations in parallel on a fine grid. This method has low communication complexity. It can be implemented easily. By local a priori error estimate for finite element discretizations, error bounds of the approximate solution are derived. Numerical results are also given to illustrate the high efficiency of the method.     

回流法合成硫化锑纳米棒及其光催化性能研究

以三氯化锑(SbCl₃)、硫粉(S)和硼氢化钠(NaBH₄)为原料, 1,2-丙二醇(C₃H₈O₂)作溶剂, 用回流法成功合成了Sb₂S₃纳米棒. 用XRD, EDS, SEM, TEM, HRTEM, SAED以及UV-Vis等手段对所制备产品的晶型、成分、形貌和光学特性进行了表征|以太阳光为光源、亚甲基蓝为目标降解物评价了Sb₂S₃纳米棒的光催化活性. 结果表明, 经186 ℃回流15 h可得到直径约为78～180 nm、长度达2～5 μm的正交晶系的Sb₂S₃单晶纳米棒. 经计算, 其晶胞参数a＝1.124 nm, b＝1.138 nm, c＝0.384 nm. UV-Vis分析表明, Sb₂S₃纳米棒为半导体材料, 其带隙能量为1.52 eV. 光催化性能测试表明, 所制备的Sb₂S₃纳米棒在太阳光下对亚甲基蓝具有较高的光催化降解率, 经20 min降解, 亚甲基蓝的降解率达84.31%, 表现出明显的可见光活性. 加入的PVP对控制Sb₂S₃的形貌有重要的作用. 另外, 还讨论了Sb₂S₃ 纳米棒可能的形成机理.     

低损耗193 nm增透膜

计算了适用于193nm增透膜设计与制备的基底与薄膜材料的光学常数,并在此基础上对193nm增透膜进行了设计、制备与性能分析.发现基底材料的吸收损耗对增透膜元件的影响很大,超过一定值时,增透膜元件的设计透过率将达不到理想水平.对单面增透膜的设计与制备结果表明,当吸收损耗降低到一定程度,散射损耗成为不可忽略的因素.采用热舟蒸发方法实现了性能良好的193 nm减反射膜,剩余反射率在0.2%以下. 关键词： 193nm 增透膜 光学损耗 剩余反射率     

In0.53 Ga0.47As/In0.52Al0.48As量子阱中双子带占据的二维电子气的输运特性

研究了不同沟道厚度的In0.53 Ga0.47As/In0.52Al0.48As量子阱中双子带占据的二维电子气的输运特性.在考虑了两个子带电子之间的磁致子带间散射效应后,通过分析Shubnikov-de Haas振荡一阶微分的快速傅里叶变换结果,获得了每个子带电子的浓度、输运散射时间、量子散射时间以及子带之间的散射时间.结果表明,对于所研究的样品,第一子带电子受到的小角散射更强,这与第一子带电子受到了更强的电离杂质散射有关.