全文获取类型
收费全文 | 9325篇 |
免费 | 1462篇 |
国内免费 | 890篇 |
专业分类
化学 | 6591篇 |
晶体学 | 93篇 |
力学 | 494篇 |
综合类 | 47篇 |
数学 | 1031篇 |
物理学 | 3421篇 |
出版年
2024年 | 32篇 |
2023年 | 165篇 |
2022年 | 315篇 |
2021年 | 323篇 |
2020年 | 346篇 |
2019年 | 336篇 |
2018年 | 299篇 |
2017年 | 272篇 |
2016年 | 399篇 |
2015年 | 427篇 |
2014年 | 503篇 |
2013年 | 697篇 |
2012年 | 825篇 |
2011年 | 802篇 |
2010年 | 567篇 |
2009年 | 535篇 |
2008年 | 606篇 |
2007年 | 500篇 |
2006年 | 510篇 |
2005年 | 412篇 |
2004年 | 372篇 |
2003年 | 275篇 |
2002年 | 284篇 |
2001年 | 212篇 |
2000年 | 147篇 |
1999年 | 167篇 |
1998年 | 150篇 |
1997年 | 164篇 |
1996年 | 157篇 |
1995年 | 116篇 |
1994年 | 120篇 |
1993年 | 95篇 |
1992年 | 60篇 |
1991年 | 53篇 |
1990年 | 59篇 |
1989年 | 43篇 |
1988年 | 28篇 |
1987年 | 22篇 |
1986年 | 35篇 |
1985年 | 29篇 |
1984年 | 23篇 |
1983年 | 20篇 |
1982年 | 11篇 |
1981年 | 13篇 |
1980年 | 16篇 |
1979年 | 10篇 |
1978年 | 22篇 |
1977年 | 10篇 |
1976年 | 13篇 |
1974年 | 12篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
71.
Network science has been widely applied in theoretical and empirical studies of global value chain (GVC), and many related articles have emerged, forming many more mature and complete analytical frameworks. Among them, the GVC accounting method based on complex network theory is different from the mainstream economics in both research angle and content. In this paper, we build up global industrial value chain network (GIVCN) models based on World Input–Output Database, introduce the theoretical framework of Social Capital, and define the network-based indicators with economic meanings. Second, we follow the econometric framework to analyze the hypothesis and test whether it is true. Finally, we study how the three types of capital constituted by these indicators interact with each other, and discuss their impact on the social capital (economic development level, i.e., GDP). The results prove that the structural capital (industrial status) has a positive impact on the social capital; the relational capital (industrial correlation) has a positive impact on both social capital and structural capital; the cognitive capital (industrial structure) has a small impact on the social capital, structural capital, and relational capital. 相似文献
72.
测量了50–250 keV H+和1.0–3.0 MeV Ar11+ 轰击Si表面过程中辐射的X射线. 结果表明, 在Ar11+入射的情况下, 引起了Si的L壳层上3, 4个电子的多电离.计算了Si的K壳层X射线产生截面, 并将两体碰撞近似(BEA), 平面波恩近似, ECPSSR理论计算与实验值进行了对比. ECPSSR理论与质子产生的截面数据能够很好地符合; 而考虑多电离后, BEA理论与Ar11+的实验结果符合较好.
关键词:
X射线
高电荷态重离子
多电离 相似文献
73.
本文考察了Fe-Fe50 wt.%Si扩散偶在1200℃ 无磁场以及稳恒磁场下扩散层生长规律. 利用真空浇注强制冷却技术制备Fe-Fe50 wt.%Si扩散偶, 将制备的扩散偶进行1200℃不同磁感应强度下的热处理. 对获得热处理后试样进行SEM与EDS线扫描分析, 结果表明, 无论无磁场还是稳恒磁场下Fe-Fe50 wt.%Si扩散偶均生成两个扩散层, 即FeSi相层和Fe-Si固溶体层, 并且发现0.8 T下的两个扩散层宽度均小于0 T磁场下试样. 按照抛物线规律, 计算了扩散偶中间扩散层的互扩散系数, 发现0.8 T磁场下FeSi相层和Fe-Si固溶体层的互扩散系数较无磁场下 分别降低了26.7%与34.1%. 通过对磁吉布斯自由能的计算, 发现0.8 T磁场对扩散激活能Q的影响不足以影响扩散过程. 但扩散过程中原子振动频率ν会受到磁场的影响, 进而影响扩散常数D0, 磁场对原子振动频率的影响可以用拉莫尔旋进理论进行解释.
关键词:
Fe-Fe50wt.%Si扩散偶
稳恒磁场
FeSi相
Fe-Si固溶体 相似文献
74.
Rafael Dias do Espírito Santo Rosineide Costa Simas Alviclér Magalhães Vanessa Gonçalves dos Santos Thais Regiani Ana Cristina Isler Natiza Graziele Martins Marcos Nogueira Eberlin Eduardo René Pérez González 《Journal of Physical Organic Chemistry》2013,26(4):315-321
Molecules containing the guanidinic nuclei possess several pharmacological applications, and knowing the preferred isomers of a potential drug is important to understand the way it operates pharmacologically. Benzoylguanidines were synthesized in satisfactory to good yields and characterized by NMR, Electrospray Ionization Mass Spectrometry (ESI‐MS) and Fourrier Transform InfraRed Spectroscopy techniques (FTIR). E/Z isomerism of the guanidines was studied and confirmed by NMR analysis in solution (1H‐13C Heteronuclear Single Quantum Coherence (HSQC) and Heteronuclear Multiple‐Bond Correlation (HMBC), 1H‐15N HMBC, 1H‐1H Correlation Spectroscopy (COSY) and Nuclear Overhauser Effect Spectroscopy (NOESY) experiments) at low temperatures. Compounds with p‐Cl and p‐Br aniline moiety exist mainly as Z isomer with a small proportion of E isomer, whereas compounds with p‐NO2 moiety showed a decrease in proportion of isomer Z. The results are important for the application of these molecules as enzymatic inhibitors. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
75.
A. Khorsand Zak W.H.abd. Majid H.Z. Wang Ramin Yousefi A. Moradi Golsheikh Z.F. Ren 《Ultrasonics sonochemistry》2013,20(1):395-400
This work is about fabrication of ZnO nanostructures (ZnO-NS) via a simple sonochemical method. The chemicals used for the synthesis of various shaped ZnO are Zn salt, sodium hydroxide and ammonia solution without other structure directing agent or surfactant needed. This method is feasible and green, as it does not require high temperature and/or highly toxic chemicals. The shape of the ZnO-NS can be tuned by adjusting the ultrasound energy dissipated via varying the ultrasonication time from 5 to 60 min. It was found that uniform ZnO nanorods with diameter around 50 nm were formed after 15 min of ultrasonication while flowerlike ZnO-NS was formed after 30 min. This method produces high quality ZnO-NS with controllable shapes, uniformity, and purity. 相似文献
76.
Modulus–porosity relationships are critical for engineered bone tissue scaffold materials such as hydroxyapatite (HA), where porosity is essential to biological function. Resonant ultrasound spectroscopy (RUS) measurements revealed that the Young's modulus, E, and shear modulus, G, of both alumina and HA decrease monotonically with increasing volume fraction porosity, P, for 0.06 < P < 0.39 (alumina) and 0.05 < P < 0.51 (HA). Although the elastic moduli of porous materials have been measured by a number of different ultrasonic resonance techniques (of which the RUS technique is one example) and over the last decade the elastic moduli of many solids have been measured by the RUS technique, this study is the first systematic RUS study of porous materials. Comparison of E versus P data for alumina (which has been studied extensively) with literature data from several measurement techniques indicates the RUS technique is effective for modulus–porosity measurements. Another key result is that although the HA specimens included in this study have a unimodal pore size distribution, the details of the decrease in E and G with increasing P agree well with literature data for HA with both unimodal and bimodal pore size distributions. In addition, Poisson's ratio exhibits a local minimum in the porosity range of 0.2 < P < 0.25 for both HA and alumina, which may be related to the pore morphology evolution during sintering. 相似文献
77.
Alain Tressaud Jean Louis Soubeyroux Jean Michel Dance René Sabatier Paul Hagenmuller Barbara M. Wanklyn 《Solid State Communications》1981,37(6):479-484
The nature of the magnetic interactions in the chain compound Rb2FeF5 has been investigated using neutron diffraction and magnetic measurements under high applied fields. Rb2FeF5 orders antiferromagnetically at TN = 8.0 ± 0.5 K; the magnetic structure is of the AZ + GX mode and the moment of the Fe3+ ion extrapoled to 0K is 3.5 ± 0.2 μB, this low value being due to zero-point spin reduction. Within a chain the Fe3+ ions are antiferromagnetically coupled with an exchange constant of J/k = ?8.8 K. A spin-flop behavior has been observed and interpreted on the basis of the molecular field theory. The critical field was found to be HC = 65 kOe at 1.7 K. 相似文献
78.
Summary We consider a one-dimensional linear wave equation with a small mean zero dissipative field and with the boundary condition imposed by the so-called Goursat problem. In order to observe the effect of the randomness on the solution we perform a space-time rescaling and we rewrite the problem in a diffusion approximation form for two parameter processes. We prove that the solution converges in distribution toward the solution of a two-parameter stochastic differential equation which we identify. The diffusion approximation results for oneparameter processes are well known and well understood. In fact, the solution of the one-parameter analog of the problem we consider here is immediate. Unfortunately, the situation is much more complicated for two-parameter processes and we believe that our result is the first one of its kind.Partially supported by ONR N00014-91-J-1010 相似文献
79.
Lenglart不等式与特殊半鞅的收敛集 总被引:2,自引:1,他引:2
本文讨论局部鞅和特殊半鞅的收敛集。我们给出Lenglart不等式的一个推广形式,利用这一不等式对一些定理给出了简单证明,对一些结果作了改进和推广。 相似文献
80.
QiuHong Wang Abdusalam Abdukerim Wei Chen Xun Chen YunHua Chen XiangYi Cui YingJie Fan DeQing Fang ChangBo Fu LiSheng Geng Karl Giboni Franco Giuliani LinHui Gu XuYuan Guo Ke Han ChangDa He Di Huang Yan Huang YanLin Huang Zhou Huang Peng Ji XiangDong Ji YongLin Ju YiHui Lai Kun Liang HuaXuan Liu JiangLai Liu WenBo Ma YuGang Ma YaJun Mao Yue Meng Parinya Namwongsa KaiXiang Ni JinHua Ning XuYang Ning XiangXiang Ren ChangSong Shang Lin Si AnDi Tan AnQing Wang HongWei Wang Meng Wang SiGuang Wang XiuLi Wang Zhou Wang MengMeng Wu ShiYong Wu JingKai Xia MengJiao Xiao PengWei Xie BinBin Yan JiJun Yang Yong Yang ChunXu Yu Jumin Yuan Dan Zhang HongGuang Zhang Tao Zhang Li Zhao QiBin Zheng JiFang Zhou Ning Zhou XiaoPeng Zhou 《中国科学:物理学 力学 天文学(英文版)》2020,(3):54-63
In dark matter direct detection experiments,neutron is a serious source of background,which can mimic the dark matter-nucleus scattering signals.In this paper,we present an improved evaluation of the neutron background in the PandaX-II dark matter experiment by a novel approach.Instead of fully relying on the Monte Carlo simulation,the overall neutron background is determined from the neutron-induced high energy signals in the data.In addition,the probability of producing a dark-matter-like background per neutron is evaluated with a complete Monte Carlo generator,where the correlated emission of neutron(s)andγ(s)in the(α,n)reactions and spontaneous fissions is taken into consideration.With this method,the neutron backgrounds in the Run 9(26-ton-day)and Run 10(28-ton-day)data sets of PandaX-II are estimated to be(0.66±0.24)and(0.47±0.25)events,respectively. 相似文献