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181.
We investigate superconducting pair correlations in the attractive Hubbard model on a finite square lattice. Our aim is to understand the pronounced size dependence which they display in the weak and intermediate coupling regimes. These size effects originate from the electronic shell structure of finite systems and severely complicate a reliable extrapolation of numerical simulation data from small systems to the thermodynamic limit. To analyze the size effects in detail, we use the BCS approximation, as well as a particle number conserving modification of it and compare the results with those of quantum Monte Carlo simulations. As an application, we explore the possibility of reducing the shell effects in simulation data by changing the shape of the system and the imposed boundary conditions and by making use of the size dependence of corresponding BCS data. 相似文献
182.
The n-dimensional cube Qn is the graph whose vertices are the subsets of {1,…n}, with two vertices adjacent if and only if their symmetric difference is a singleton. Clearly Qn has diameter and radious n. Write M = n2n-1 = e(Qn) for the size of Qn. Let Q = (Qt)oM be a random Qn-process. Thus Qt is a spanning subgraph of Qn of size t, and Qt is obtained from Qt–1 by the random addition of an edge of Qn not in Qt–1, Let t(k) = τ(Q;δ?k) be the hitting time of the property of having minimal degree at least k. We show that the diameter dt = diam (Qt) of Qt in almost every Q? behaves as follows: dt starts infinite and is first finite at time t(1), it equals n + 1 for t(1) ? t(2) and dt, = n for t ? t(2). We also show that the radius of Qt, is first finite for t = t(1), when it assumes the value n. These results are deduced from detailed theorems concerning the diameter and radius of the almost surely unique largest component of Qt, for t = Ω(M). © 1994 John Wiley & Sons, Inc. 相似文献
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184.
It is an important challenge to analyze a three-dimensional thermal flow field in engineering, science, and agriculture. For such an analysis, it is essential to measure physical quantities such as temperature and velocity over the entire thermal flow field. This paper presents a measurement system based on color image processing for temperature and velocity vector distributions in a three-dimensional thermal flow field. Flow visualization is accomplished by the use of thermo-sensitive liquid crystal tracers. An algorithm for the color-to-temperature transformation using a multi-layer feed-forward neural network is applied to three-dimensional natural convection in a rotating cylindrical cell. Two-dimensional temperature distributions in a slit plane are obtained by using the algorithm. A three-dimensional temperature distribution is consequently constructed by interpolating the two-dimensional distributions using the B-spline function. In addition, the Spatio-Temporal correlation method is applied to the natural convection to obtain a three-dimensional velocity vector distribution. 相似文献
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187.
Images of the surface ordering of 4-n-octyl-4'-cyanobiphenyl, a room temperature smectic liquid crystal deposited upon graphite, have been obtained by scanning tunnelling microscopy. The microscope was operated in air using the constant-current mode. Under certain tunnelling conditions it has been possible to resolve both the aliphatic and aromatic parts of the molecule, and to observe individual benzene rings. Two previously unreported conformations have been observed: an overlapping bilayer structure with spacing 3.7 nm, and a monolayer structure with spacing 2.4 nm. The latter structure may represent the first visual evidence for a surface polar ordered structure. 相似文献
188.
The mechanism of ozone formation has been studied using 16O and 18O2. High-resolution microwave spectroscopy was used to measure the amounts of the isotopomeric ozone species formed. The study is hampered by the very rapid exchange process between the reactants, that tends to scramble the isotopes and hence give a 2:1 statistical ratio between the two possible isotopomers. We have found a strategy to come around this difficulty and conclude that the mechanism is a simple end-on-addition. 相似文献
189.
G. M. Luke L. P. Le B. J. Sternlieb Y. J. Uemura J. H. Brewer R. Kadono R. F. Kiefl S. R. Kreitzman T. M. Riseman C. L. Seaman Y. Dalichaouch M. B. Maple J. D. Garrett 《Hyperfine Interactions》1991,64(1-4):517-522
We have performed both zero field and high transverse field measurements at dilution refrigerator temperatures on a number of heavy electron systems, examining the superconducting and magnetic properties of these interesting materials. Among the materials studied to date are UBe13, URu2Si2 and U6Fe. The magnetic field penetration depth in the superconducting state of UBe13 is greater than 10000 Å, as no increase in the transverse field relaxation rate is observed belowT c . A sharp increase in the precession frequency is seen, starting atT c . This frequency shift shows little temperature dependence at low temperature; we found no clear evidence for unconventional superconductivity in this material. Zero field measurements in URu2Si2 show the weak antiferromagnetic transition at 17.5 K. Finally, we we found no clear evidence for unconventional superconductivity in this material. Zero field measurements in URu2Si2 show the weak antiferromagnetic transition at 17.5 K. Finally, we have observed relaxation in high transverse field due to the formation of a flux lattice in U6Fe, a material where the electron effective mass is rather lighter than in other heavy fermion systems. The relaxation exhibits a sharp onset atT c=3.9 K, and is flat at low temperatures as expected for a conventional superconductor. 相似文献
190.
Rate constants have been measured by pulse radiolysis for the reactions of the carbonate radical, CO3·?, with a number of organic and inorganic reactants as a function of temperature, generally over the range 5 to 80°C. The reactants include the substitution-inert cyano complexes of FeII, MoIV, and WIV, the simple inorganic anions SO32?, ClO2?, NO2?, I?, and SCN?, several phenolates, ascorbate, tryptophan, cysteine, cystine, methionine, triethylamine, and allyl alcohol. The measured rate constants ranged from less than 105 to 3 × 109 M?1 s?1, the activation energies ranged from ?11.4 to 18.8 kJ mol?1, and the pre-exponential factors ranged from log A = 6.4 to 10.7. The activation energies for the metal complexes and inorganic anions generally decrease with increasing driving force for the reaction, as expected for an outer sphere electron transfer. For highly exothermic reactions, however, the activation energy appears to increase, probably reflecting the temperature dependence of diffusion. For many of the organic reactants, the activation energies were low and independent of driving force, suggesting that the oxidation is via an inner sphere mechanism. 相似文献