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81.
The cyclization of dilithiated nitriles with epibromohydrin afforded 2-cyano-1-(hydroxymethyl)cyclopropanes. 2-Cyanomethylidene-(4-hydroxymethyl)thiazolidines were prepared by one-pot cyclization of dilithiated nitriles with isothiocyanates and epibromohydrin. 相似文献
82.
83.
Bivash R Behera Subinit Roy P Basu M K Sharan S Jena M Satpathy SK Datta L Satpathy ML Chatterjee 《Pramana》1999,53(3):563-566
Time of flight and energy of fission fragments were measured using pulsed beam. Fission fragment mass and energy integrated
angular distributions were extracted. Fission fragment anisotropy was explained in the framework of saddle point model. 相似文献
84.
4,5-Diaryl-1,2,3-benzenetricarboxylates were prepared by cycloaddition of 4-hydroxycyclo-2-penten-1-one-2-carboxylates with dimethyl acetylenedicarboxylate. 相似文献
85.
The applicability of the chromatomembrane method for the removal of dissolved oxygen from solvents used in voltammetric measurements was investigated. The chromatomembrane cell combined with a flow-through system allows an online deaeration of solutions. These experiments employed a mercury film electrode as working electrode and differential pulse anodic stripping voltammetry as the measuring method. Different eluents with adequate supporting electrolyte (without analyte) were measured to determine the background current, whether any contribution of oxygen is detectable. Voltammograms of eluents deaerated with the chromatomembrane method are compared to those of eluents purged with nitrogen for several minutes immediately before the measurement. No differences in the background currents can be observed when defined flow rates of eluent and nitrogen are maintained. Determinations of cadmium and lead even indicate the high efficiency of this method. 相似文献
86.
87.
A.?Jafarpour E.?Chow C.M.?Reinke J.?Huang A.?AdibiEmail author A.?Grot L.W.?Mirkarimi G.?Girolami R.K.?Lee Y.?Xu 《Applied physics. B, Lasers and optics》2004,79(4):409-414
For the first time, we experimentally demonstrate ultra-low-loss guiding in bi-periodic photonic crystal waveguides over a large bandwidth of more than 60 nm. In such bi-periodic waveguides, we achieve a propagation loss very similar to that of a dielectric ridge waveguide, which indicates that the dominant loss mechanism in these bi-periodic waveguides is due to fabrication imperfections. PACS 42.70.Qs; 42.79.Gn 相似文献
88.
Stefan Büttner Ibrar Hussain Mathias Lubbe Helmut Reinke Peter Langer 《Tetrahedron》2009,65(10):2124-603
A variety of functionalized 5-aryl-3-(trifluoromethyl)phenols were prepared by the first TiCl4-mediated [3+3] cyclocondensation of 1,3-bis(trimethylsilyloxy)-1,3-butadienes with 3-aryl-3-trimethylsilyloxy-1-trifluoromethyl-2-en-1-ones. 相似文献
89.
Rice JE Hughes JW Diamond PH Kosuga Y Podpaly YA Reinke ML Greenwald MJ Gürcan ÖD Hahm TS Hubbard AE Marmar ES McDevitt CJ Whyte DG 《Physical review letters》2011,106(21):215001
Intrinsic rotation has been observed in I-mode plasmas from the C-Mod tokamak, and is found to be similar to that in H mode, both in its edge origin and in the scaling with global pressure. Since both plasmas have similar edge ?T, but completely different edge ?n, it may be concluded that the drive of the intrinsic rotation is the edge ?T rather than ?P. Evidence suggests that the connection between gradients and rotation is the residual stress, and a scaling for the rotation from conversion of free energy to macroscopic flow is calculated. 相似文献
90.
Iran Otero Karen Methling Holger Feist Manfred Michalik José Quincoces Helmut Reinke 《Journal of carbohydrate chemistry》2013,32(8-9):809-829
Treatment of 1,2‐dideoxy‐4,5:6,7‐di‐O‐isopropylidene‐D‐xylo‐hept‐1‐yn‐3‐uloses 4a,b with hydrazine hydrate and amidines yielded the 3‐(1,2:3,4‐di‐O‐isopropylidene‐D‐xylo‐1,2,3,4‐tetrahydroxy‐butyl)‐5‐phenyl‐1H(2H)‐pyrazole 5 and the substituted 4‐(1,2:3,4‐di‐O‐isopropylidene‐D‐xylo‐1,2,3,4‐tetrahydroxy‐butyl)pyrimidines 7a–f, respectively. Reaction of 4a,b with 2‐amino‐benzimidazol afforded the 2‐(1,2:3,4‐di‐O‐isopropylidene‐D‐xylo‐1,2,3,4‐tetrahydroxy‐butyl)benzo[4,5]imidazo[1,2‐a]pyrimidines 9a,b. Compound 4a and 5‐amino‐pyrazole‐4‐carbonic acid derivatives yielded the 5‐(1,2:3,4‐di‐O‐isopropylidene‐D‐xylo‐1,2,3,4‐tetrahydroxy‐butyl)pyrazolo[1,5‐a]pyrimidines 11a–d. Deprotection of pyrazole 5, pyrimidine 7a, and pyrazolo[1,5‐a]pyrimidine 11b yielded the acyclo‐C‐nucleosides 6, 8, and 12, respectively. 相似文献