全文获取类型
收费全文 | 88篇 |
免费 | 3篇 |
专业分类
化学 | 65篇 |
力学 | 2篇 |
数学 | 3篇 |
物理学 | 21篇 |
出版年
2020年 | 1篇 |
2016年 | 2篇 |
2015年 | 3篇 |
2013年 | 8篇 |
2012年 | 1篇 |
2011年 | 4篇 |
2010年 | 3篇 |
2009年 | 5篇 |
2008年 | 9篇 |
2007年 | 11篇 |
2006年 | 6篇 |
2005年 | 2篇 |
2004年 | 5篇 |
2003年 | 2篇 |
2002年 | 3篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1989年 | 1篇 |
1980年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1967年 | 1篇 |
1920年 | 1篇 |
1896年 | 1篇 |
1892年 | 1篇 |
1890年 | 1篇 |
排序方式: 共有91条查询结果,搜索用时 0 毫秒
31.
A variety of heterocyclic spiranes were prepared by cyclization of dinucleophiles with 1,1-bis(tosyloxymethyl)cyclopropane and -cyclobutane. 相似文献
32.
Muhammad A. Rashid Bettina Appel Vahuni Karapetyan Helmut Reinke Peter Langer 《Tetrahedron》2008,64(22):5416-5425
Functionalized 1-azaxanthones (5-oxo-5H-[1]-benzopyrano[2,3-b]pyridines) were prepared by TMSOTf-mediated condensation of 1,3-bis(trimethylsilyloxy)-1,3-butadienes with 3-cyanochromones and subsequent base-mediated domino ‘retro-Michael/nitrile-addition/heterocyclization’ reaction. 相似文献
33.
The cyclization of β-ketosulfone, β-ketonitrile and β-ketophosphonate dianions with 1,1-diacetylcyclopropane afforded 1-hydroxyspiro[5.2]cyclooct-4-en-3-ones, which were transformed, by reaction with tetrabutylammonium halides, into functionalized phenols containing a remote halide function. 相似文献
34.
The combination of spin-and charge based electronics in future devices requires the magnetic doping of group IV semiconductors, and the formation of ferromagnetic contacts. The doping of Mn with Si is one of the material systems which is discussed in this context. The present study focuses on the growth of Mn on a Si(100)(2x1) surface, and the evolution of the surface was observed as a function of Mn coverage with synchrotron-based photoelectron spectroscopy. The reaction of Mn with the Si(100) surface at room temperature leads the formation of silicide at the boundary between the Si substrate and the Mn-overlayer, presumably with MnSi stoichiometry. The residual sub-oxide reacts with the Mn and therefore incorporates a few percent of Mn-O-Si at the interface. The analysis of the sub-oxide composition indicates that the Si+1 component is the most reactive oxidation state. The overlayer is dominated by Mn, either as Mn-metal or as a Mn-rich silicide phase, and the metallic layer introduces a band bending in Si. As a consequence of our observations, including information from a recent STM study, the formation of ferromagnetic contacts which require ideally a flat and compositionally homogenous overlayer, cannot be achieved through room temperature deposition of Mn on the Si(100) (2x1) surface. The influence of residual oxides and surface defects on the growth process will be further investigated. 相似文献
35.
36.
R. H. Chittenden E. Bauer C. J. Lintner H. Ost P. Guichard L. Sostegni G. Düll Alb Munsche A. L. Winton Jr. O. Reinke H. Schreib J. Berger J. Krieger A. von Asboth C. Monheim F. Seyfert A. Leclerc Effront A. Baudry O. Saare W. E. Stone F. Mylius H. B. Stocks C. Meineke A. Girard F. W. Küster M. Dennstedt F. Voigtländer G. Ambühl W. Keller F. W. Dafert A. Meyer Em. Bourguelot und Stoltz 《Fresenius' Journal of Analytical Chemistry》1896,35(1):607-623
Ohne Zusammenfassung 相似文献
37.
O. Reinke 《Fresenius' Journal of Analytical Chemistry》1920,59(4):205-206
Ohne Zusammenfassung 相似文献
38.
Reinke D Stark H von Grünberg HH Schofield AB Maret G Gasser U 《Physical review letters》2007,98(3):038301
The elastic properties of fcc crystals consisting of charge stabilized colloidal particles are determined from real space imaging experiments using confocal microscopy. The normal modes and the force constants of the crystal are obtained from the fluctuations of the particles around their lattice sites using the equipartition theorem. We show that the Cauchy relation is not fulfilled and that only noncentral many-body forces can account for the elastic properties. 相似文献
39.
A Soibel SS Banerjee Y Myasoedov ML Rapparort E Zeldov S Ooi T Tamegai 《Pramana》2002,58(5-6):893-898
Using a novel differential magneto-optical imaging technique we investigate the phenomenon of vortex lattice melting in crystals
of Bi2Sr2CaCu2O8 (BSCCO). The images of melting reveal complex patterns in the formation and evolution of the vortex solid-liquid interface
with varying field (H)/temperature (T). We believe that the complex melting patterns are due to a random distribution of material disorder/inhomogeneities across
the sample, which create fluctuations in the local melting temperature or field value. To study the fluctuations in the local
melting temperature/field, we have constructed maps of the melting landscape T
m(H, r), viz., the melting temperature (T
m) at a given location (r) in the sample at a given field (H). A study of these melting landscapes reveals an unexpected feature: the melting landscape is not fixed, but changes rather
dramatically with varying field and temperature along the melting line. It is concluded that the changes in both the scale
and shape of the landscape result from the competing contributions of different types of quenched disorder which have opposite
effects on the local melting transition. 相似文献
40.
Michael Reinke John Mantzaras Rolf Schaeren Rolf Bombach Andreas Inauen Sabine Schenker 《Proceedings of the Combustion Institute》2005,30(2):2519-2527
The homogeneous ignition of CH4/air, CH4/O2/H2O/N2, and CH4/O2/CO2/N2 mixtures over platinum was investigated experimentally and numerically at pressures 4 bar p 16 bar, temperatures 1120 K T 1420 K, and fuel-to-oxygen equivalence ratios 0.30 0.40. Experiments have been performed in an optically accessible catalytic channel-flow reactor and included planar laser induced fluorescence (LIF) of the OH radical for the determination of homogeneous (gas-phase) ignition and one-dimensional Raman measurements of major species concentrations across the reactor boundary layer for the assessment of the heterogeneous (catalytic) processes preceding homogeneous ignition. Numerical predictions were carried out with a 2D elliptic CFD code that included elementary heterogeneous and homogeneous chemical reaction schemes and detailed transport. The employed heterogeneous reaction scheme accurately captured the catalytic methane conversion upstream of the gaseous combustion zone. Two well-known gas-phase reaction mechanisms were tested for their capacity to reproduce measured homogeneous ignition characteristics. There were substantial differences in the performance of the two schemes, which were ascribed to their ability to correctly capture the p–T– parameter range of the self-inhibited ignition behavior of methane. Comparisons between measured and predicted homogeneous ignition distances have led to the validation of a gaseous reaction scheme at 6 bar p 16 bar, a pressure range of particular interest to gas-turbine catalytically stabilized combustion (CST) applications. The presence of heterogeneously produced water chemically promoted the onset of homogeneous ignition. Experiments and predictions with CH4/O2/H2O/N2 mixtures containing 57% per volume H2O have shown that the validated gaseous scheme was able to capture the chemical impact of water in the induction zone. Experiments with CO2 addition (30% per volume) were in good agreement with the numerical simulations and have indicated that CO2 had only a minor chemical impact on homogeneous ignition. 相似文献