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排序方式: 共有407条查询结果,搜索用时 15 毫秒
71.
Reiko Saito Akifumi Fujita Ayako Ichimura Koji Ishizu 《Journal of polymer science. Part A, Polymer chemistry》2000,38(11):2091-2097
Novel structural microspheres of the Janus type, with microphase‐separated polystyrene (PS) and poly(tert‐butyl methacrylate) (PBMA) shells and crosslinked poly(2‐vinyl pyridine) (PVP) cores, were synthesized with the crosslinking of PVP spherical domains in poly(styrene‐block‐2‐vinyl pyridine‐block‐tert‐butyl methacrylate) ABC triblock terpolymer film with PS/PBMA lamellae–PVP spherical structures. For the formation of lamellae‐sphere structures, toluene, which was a selective solvent for the ABC triblock terpolymer, was used. With the crosslinking of PVP spheres in the microphase‐separated film with 1,4‐diiodobutane gas, the microphase structure of the terpolymer was fixed, and microspheres composed of microphase‐separated PS and PBMA shells and P2VP cores were obtained. The size distribution of the purified microspheres was narrow. The characteristics of the microspheres and their aggregation behaviors in selective solvents were investigated by transmission electron microscopy and light scattering methods. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 2091–2097, 2000 相似文献
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Bu HB Götz G Reinold E Vogt A Azumi R Segura JL Bäuerle P 《Chemical communications (Cambridge, England)》2012,48(21):2677-2679
A PEDOT-based conductive copolymer soluble in organic solvents was synthesized electrochemically using dihexyl-EDOT and azidomethyl-EDOT as monomers and was successfully post-functionalized by "click"-cycloaddition reaction with a functionalized terminal alkyne under mild heterogeneous conditions. 相似文献
75.
76.
Reiko Heckel Hartmut Ehrig Uwe Wolter Andrea Corradini 《Applied Categorical Structures》2001,9(1):83-110
The classical algebraic approach to graph transformation is a mathematical theory based on categorical techniques with several interesting applications in computer science. In this paper, a new semantics of graph transformation systems (in the algebraic, double-pushout (DPO) approach) is proposed in order to make them suitable for the specification of concurrent and reactive systems. Classically, a graph transformation system comes with a fixed behavioral interpretation. Firstly, all transformation steps are intended to be completely specified by the rules of the system, that is, there is an implicit frame condition: it is assumed that there is a complete control about the evolution of the system. Hence, the interaction between the system and its (possibly unknown) environment, which is essential in a reactive system, cannot be modeled explicitly. Secondly, each sequence of transformation steps represents a legal computation of the system, and this makes it difficult to model systems with control. The first issue is addressed by providing graph transformation rules with a loose semantics, allowing for unspecified effects which are interpreted as activities of the environment. This is formalized by the notion of double-pullback transitions, which replace (and generalize) the well-known double-pushout diagrams by allowing for spontaneous changes in the context of a rule application. Two characterizations of double-pullback transitions are provided: the first one describes them in terms of extended direct DPO derivations, and the second one as incomplete views of parallel or amalgamated derivations. The issue of constraining the behavior of a system to transformation sequences satisfying certain properties is addressed instead by introducing a general notion of logic of behavioral constraints, which includes instances like start graphs, application and consistency conditions, and temporal logic constraints. The loose semantics of a system with restricted behavior is defined as a category of coalgebras over a suitable functor. Such category has a final object which includes all finite and infinite transition sequences satisfying the constraints. 相似文献
77.
Reiko Saito Yoshiki Okuno Hiroaki Kobayashi 《Journal of polymer science. Part A, Polymer chemistry》2001,39(20):3539-3546
A novel template monomer with multiple methacryloyl groups was synthesized with β‐cyclodextrin by the acetylation of primary hydroxyl groups and the esterification of secondary hydroxyl groups with methacrylic acid anhydride. The average number of methacryloyl groups in the monomer was 11. The radical polymerization of the monomer was carried out with the following initiators: α,α′‐azobisisobutylonitrile, H2O2? Fe2+ redox initiator, p‐xylyl‐N,N‐dimethyldithiocarbamate (XDC), and α‐bromo‐p‐xylyl‐N,N‐dimethyldithiocarbamate (BXDC). When the concentration of the monomer was less than 4.12 × 10?3 M, polymerization was limited inside the molecule, and gelation of the system was hindered. For controlled radical photopolymerization with XDC and BXDC, the methacryloyl groups of the monomer were homogeneously polymerized, and poly(methacrylic acid) with a narrow molecular weight distribution was obtained by the hydrolysis of the polymerized products. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 3539–3546, 2001 相似文献
78.
Nobuo Ishizawa Reiko Yamashita Shuji Oishi James R. Hester Shunji Kishimoto 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(9):1006-1009
The triclinic superstructure of a small crystal of LiCa2Nb3O10, lithium dicalcium triniobium decaoxide, has been investigated by synchrotron X‐ray diffraction. The unit cell is an almost rectangular parallelepiped, although there is a 0.245° offset from orthogonality for β. The structure essentially belongs to a homologous series of Li[Nan?3Ca2NbnO3n+1] with n = 3, where the moiety in square brackets has a perovskite‐type slab structure. The superstructure has a doubled unit‐cell volume with respect to the tetragonal aristotype. The NbO6 octahedra are rotated about axes parallel to [110] by approximately 10°. Adjacent slabs are connected by Li atoms and are geometrically related by 42 pseudosymmetry lying parallel to c . There are twice as many sites as Li atoms, providing a variation of population at these Li sites. 相似文献
79.
Nobuo Yamada Dr. Hiroki Noguchi Yoshifumi Orimoto Dr. Yutaka Kuwahara Prof. Dr. Makoto Takafuji Shaheen Pathan Dr. Reiko Oda Almara Mahammadali Rahimli Prof. Dr. Mahammadali Ahmed Ramazanov Prof. Dr. Hirotaka Ihara 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(43):10141-10148
In this work, a new class of totally organic fluorescent nanogel particles and their exceptionally specific behaviors based on their unique structures are introduced, which draws a sharp line from conventional fluorophore-doped and fluorophore-branched-type particles. The nanogel particles, the diameter of which could be controlled by adjusting reaction conditions, such as the solvent system, were spontaneously fabricated with a spherical shape by direct polymerization of non-heterocyclic aromatic compounds, such as 2,6-dihydroxyanthracene, 2,6-dihydroxynaphthalene, and 9,9-bis(4-hydroxyphenyl)fluorene with triazinane as the cross-linker. A fluorophoric moiety formed from a polymer main chain was realized in the particle, and consequently, the resultant content of the fluorophoric moiety was around 70–80 wt % per particle. The uniqueness and versatility of the particles can be emphasized by their good compatibility with various solvents due to their amphiphilic and ampholytic swelling properties, but also by their remarkable fluorescent solvatochromism in the dispersion state. Furthermore, these behaviors were preserved even in their polymer composite system. This study also demonstrates that various fluorescent polymer films can be fabricated with emission color control due to memorization of the solvatochromism phenomenon of the dispersed fluorescent nanoparticles. 相似文献
80.
Yanada R Obika S Inokuma T Yanada K Yamashita M Ohta S Takemoto Y 《The Journal of organic chemistry》2005,70(17):6972-6975
We have developed efficient catalytic methods for the stereoselective and diversity synthesis of various (E)-, (Z)-, and disubstituted 3-alkylideneoxindoles and 3-alkylidenebenzofuran-2-ones via palladium-catalyzed Heck/Suzuki-Miyaura, Heck/Heck, and Heck/carbonylation/Suzuki-Miyaura domino reactions. 相似文献